ISSN:
0009-2940
Keywords:
Borane adduct
;
Organoboron compound, reducing agent
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Organoboron Compounds, II1,2) - Preparation, Structure, and Reactions of Lithium [Cyano(triphenylphosphoranylidene)-methyl]trihydroborate(-1)(Cyanomethylene)triphenylphosphorane (5) adds borane (from 2) with formation of phosphorane-borane 6, which cannot be rearranged. 6 reacts with butyllithium to afford a crystalline lithium compound 9, which contains four tetrahydrofuran molecules. The X-ray structure analysis of 9 is reported, 9 is acting as a reducing agent towards halogeno and carbonyl compounds.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19911240129
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