ISSN:
0941-1216
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Metal Complex Catalysts with Phosphonic Ester Phosphine Ligands. I. Carbonylation of Methanol by Phosphonic Ester Phosphine Rhodium ComplexesThe treatment of technically available 2-(chloroethyl)phosphonic acid dimethylester (1) with diphenylphosphine and potassium-tert.-butylate affords 2-(diphenylphosphino)ethylphosphonic acid dimethylester (2a) in a simple way. 2a can be used as a hemilabil complex ligand (by phosphine and phosphoryl group.) Rhodium complexes of the type (MeO)2P(O)CH2CH2P(Ph)2RhL3 (3) were obtained from 2a and exhibit excellent catalytic properties in the liquid-phase carbonylation of methanol to acetic acid. Studies on other chelat-ligands did not confirm the exceptional increase of the activity by bisphosphinemonoxyd-ligands and the inhibition of the title reaction by bisphosphine-ligands already published.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/prac.19933350406
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