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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 67 (1990), S. 4998-5000 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: An investigation of the metallurgy of a pseudobinary section of the ternary-phase diagram has been performed by means of differential thermal analysis, x-ray diffraction, and metallography. Microstructural observations and lattice parameter variations have been interpreted in terms of the existence of a solid solubility range for the Laves phase. Thermal analysis has established the details of the phase relationships in the region of the Laves phase and on the basis of the results a modified phase diagram is proposed.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2015-12-10
    Description: The electronic structure of [6,6]-phenyl C 61 butyric acid methyl ester (PCBM), poly(3-hexylthiophene) (P3HT), and P3HT/PCBM blends is studied using soft X-ray emission and absorption spectroscopy and density functional theory calculations. We find that annealing reduces the HOMO-LUMO gap of P3HT and P3HT/PCBM blends, whereas annealing has little effect on the HOMO-LUMO gap of PCBM. We propose a model connecting torsional disorder in a P3HT polymer to the HOMO-LUMO gap, which suggests that annealing helps to decrease the torsional disorder in the P3HT polymers. Our model is used to predict the characteristic length scales of the flat P3TH polymer segments in P3HT and P3HT/PCBM blends before and after annealing. Our approach may prove useful in characterizing organic photovoltaic devices in situ or even in operando .
    Print ISSN: 0021-9606
    Electronic ISSN: 1089-7690
    Topics: Chemistry and Pharmacology , Physics
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