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  • 2000-2004  (94)
  • 1990-1994  (90)
  • 1920-1924
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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 116 (1994), S. 777-778 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 93 (1990), S. 3207-3214 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Overtone vibration–laser double resonance studies of DF(v=1–3) energy transfer yield self-relaxation rate constants for v=1, 2 and 3 of k1=(0.37±0.06)×10−12 cm3 mol−1 s−1, k2=(22.0±2.0)×10−12 cm3 mol−1 s−1, and k3=(17.0±1.8)×10−12 cm3 mol−1 s−1, respectively. The approach also directly measures the relative importance of vibration-to-vibration (V–V) and vibration-to-translation-and-rotation (V–T,R) energy transfer. The fraction of DF(v) molecules relaxing by V–V energy transfer is 1.1±0.1 and 0.72±0.10 for v=2 and v=3, respectively. Essentially all of the vibrational energy transfer in v=2 occurs via the V–V mechanism. The slower relaxation of DF(v=3) compared to DF(v=2), in contrast to simple scaling law predictions, reflects the decreasing influence of the V–V mechanism, even though it is still the primary relaxation pathway for DF(v=3). Comparison with HF self-relaxation qualitatively indicates that V–R energy transfer is important in V–T,R relaxation of DF(v=1).
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 116 (2002), S. 8384-8395 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We re-examine the ionization-detected ultraviolet absorption spectrum of the 3pπ 2Π←X 2A′ transition in HCO and DCO using a high-power visible laser to enhance the observation of first-photon resonant features. This technique, which we term here, assisted REMPI, significantly improves the signal-to-noise ratio of the spectrum, making many weak vibronic sub-bands visible for the first time. A comprehensive fit to the structure evident in a progression of bending levels from (000) to (040) refines the assignment of Song and Cool [X. M. Song and T. A. Cool, J. Chem. Phys. 96, 8664 (1992)] to yield a set of rotational constants that vary with K in relation to v2, together with a higher-order contribution to the Renner–Teller splitting in HCO, which is mirrored in DCO for all levels but (040). The (040) band falls at a frequency that is commensurate with that of CD stretch, and Fermi resonance between 3pπ 2Π(1000)Π and the higher-energy (040) K=1(Π) component gives rise to an added splitting that increases the energy of this (040) component and causes an apparent increase in the Renner parameter. © 2002 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 109 (1922), S. 43-44 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] MR. W. ROBERTSON'S letter in NATURE of January 5 is very timely. May I invite him and those his letter has interested or impressed to put into practice, in Middlesbrough or any other town, the “most practical suggestion of immediate value” he describes, with one important addition. Some of us ...
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Ground water 28 (1990), S. 0 
    ISSN: 1745-6584
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: Mixing of fluids at fracture intersections was examined using both a series of plexiglass models and a two-dimensional, finite-element, discrete fracture model. The physical laboratory models included 12 models having two continuous, fully intersecting fractures with different intersection angles and apertures, a single model consisting of a single continuous fracture offsetting a second fracture, and a fracture system model consisting of parallel fractures in two intersecting sets. The plexiglass model results indicated essentially no mixing occurred in the fully intersecting fracture models when the apertures were equal. Mixing was found to be dependent only upon the relative size of the inlet and outlet fractures even with multiple intersections.For transport of a conservative solute in a discontinuous, random, discrete fracture system, the numerical model used the mixing algorithm for fracture intersections, developed from the physical model study. At each four-way intersection, a novel approach was used to uncouple and recouple the nodal points to ensure the proper assignment of concentrations to each fracture element. Using the laboratory-determined mixing algorithm, the numerical model demonstrated that more longitudinal and less lateral dispersion takes place than when complete mixing at fracture intersections is assumed. In addition, more longitudinal transport takes place in discontinuous than in continuous fracture systems. These findings indicate that contaminants migrating through fractured media, where the fracture walls are not in contact, will not be dispersed and diluted to the extent that previous numerical models have predicted; hence, the contaminant will be discharged to the biosphere in much greater concentration than expected.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1520-6904
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1520-6904
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    [s.l.] : Macmillian Magazines Ltd.
    Nature 425 (2003), S. 65-69 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] The Late Devonian genus Ichthyostega was for many decades the earliest known tetrapod, and the sole representative of a transitional form between a fish and a land vertebrate. However, despite being known since 1932 (ref. 1) from a large collection of specimens, its morphology ...
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  • 9
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd
    Plant pathology 49 (2000), S. 0 
    ISSN: 1365-3059
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: The effects of temperature on the length of the incubation and latent periods of hawthorn powdery mildew, caused by Podosphaera clandestina, were studied. At constant temperatures over the range 10–28°C, the incubation period ranged from 5 to 14 days and the latent period from 5 to 16 days; no visible colonies had developed at 30°C after 15 days. The relationships between temperature and the rates of fungus development within the incubation and latent periods were well described by a nonlinear model. The resulting curves were asymmetrically bell-shaped with an optimum temperature of approximately 23°C. The lengths of the incubation and latent periods under fluctuating temperatures were also determined, and were used to evaluate the models developed from constant temperature experiments for their accuracy of prediction. The incubation and latent periods under fluctuating temperature regimes were predicted using a rate-summation scheme with a time step of 24 min, by integrating the respective incubation and latent rate functions obtained under constant temperatures. The predicted incubation or latent periods agreed well with the observed values. Under constant temperature the interval between the times when symptoms and sporulation on the same leaflet were first observed was very short, on average 〈1 day, and was not significantly correlated with temperature. However, this interval was negatively correlated with mean temperature under fluctuating regimes.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd
    Plant pathology 50 (2001), S. 0 
    ISSN: 1365-3059
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Spatio-temporal development of brown rot (Monilinia fructigena) on apple and pear was monitored in an apple (cv. Cox) orchard and a pear orchard of several cultivars over several years. Disease on individual trees was recorded weekly from July to harvest, individual fruits with brown rot were tagged but not removed and rot-origin identified. On apple cv. Cox and pear (cvs Conference and Comice), all primary rot arose from infection via wounds caused by insects, birds and growth cracks. Birds were the most important wounding agents on pear in the field. Secondary (fruit-to-fruit contact) rot was considerably less than primary rot, especially for pear. Incidence of disease (percentage of fruits with brown rot) increased gradually from late July up to harvest; the final disease incidence varied with seasons and cultivars, ranging from 1 to 11%. For pear, Comice had greater incidence than Conference. Significant aggregation of diseased fruits among trees was detected for assessment dates when the overall incidence of disease was greater than 0·5%. On Cox and Conference, significant correlation of disease incidence between adjacent trees or trees separated by one or more trees (i.e. spatial lag measured as units of distance between adjacent trees) was detected, but there was no clear relationship between the correlation, the distance or time. For Comice, there was consistent and significant positive correlation of brown rot incidence over 3 years. It is speculated that behavioural characteristics of wounding agents may have played an important role in influencing the spatio-temporal dynamics of brown rot on apple and pear.
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