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  • 1995-1999  (71)
  • 1990-1994  (90)
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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 116 (1994), S. 777-778 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1432-1793
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The existence of endosymbiotic sulfur-oxidizing chemoautotrophic and methanotrophic bacteria associating with marine mytilid mussels has previously been inferred by 16S rDNA analysis in Bathymodiolus puteoserpentis Von Cosel et al. 1994, a hydrothermal vent mussel from a site on the Mid-Atlantic Ridge. In mussels collected in June 1993, we found evidence of enzymes diagnostic of two distinct C1 assimilation pathways in this symbiosis. Assays for the utilization of radiolabelled methane and for immunodetection of methanol dehydrogenase were positive, indicating that oxidation and incorporation of this substrate are occurring in this symbiosis. Sulfide or thiosulfate had no detectable stimulatory effect on CO2 incorporation, and assays for the enzyme ribulose-1,5-bisphosphate carboxylase/oxygenase (RubisCO), an enzyme diagnostic for the Calvin–Benson cycle, were negative. RubisCO was detected in all samples examined by immunoblot analysis, indicating this enzyme is expressed in the B. puteoserpentis symbiosis. Stable isotope data showed that carbon isotope values were in agreement with previously reported values, and nitrogen isotope values were among the most depleted ever reported for bivalve symbioses. The carbon isotope values do not preclude the utilization of vent-derived methane. These data could be explained by the presence of two metabolically distinct bacterial symbionts or a Type X methanotrophic symbiont.
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 93 (1990), S. 3207-3214 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Overtone vibration–laser double resonance studies of DF(v=1–3) energy transfer yield self-relaxation rate constants for v=1, 2 and 3 of k1=(0.37±0.06)×10−12 cm3 mol−1 s−1, k2=(22.0±2.0)×10−12 cm3 mol−1 s−1, and k3=(17.0±1.8)×10−12 cm3 mol−1 s−1, respectively. The approach also directly measures the relative importance of vibration-to-vibration (V–V) and vibration-to-translation-and-rotation (V–T,R) energy transfer. The fraction of DF(v) molecules relaxing by V–V energy transfer is 1.1±0.1 and 0.72±0.10 for v=2 and v=3, respectively. Essentially all of the vibrational energy transfer in v=2 occurs via the V–V mechanism. The slower relaxation of DF(v=3) compared to DF(v=2), in contrast to simple scaling law predictions, reflects the decreasing influence of the V–V mechanism, even though it is still the primary relaxation pathway for DF(v=3). Comparison with HF self-relaxation qualitatively indicates that V–R energy transfer is important in V–T,R relaxation of DF(v=1).
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  • 4
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Ground water 28 (1990), S. 0 
    ISSN: 1745-6584
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: Mixing of fluids at fracture intersections was examined using both a series of plexiglass models and a two-dimensional, finite-element, discrete fracture model. The physical laboratory models included 12 models having two continuous, fully intersecting fractures with different intersection angles and apertures, a single model consisting of a single continuous fracture offsetting a second fracture, and a fracture system model consisting of parallel fractures in two intersecting sets. The plexiglass model results indicated essentially no mixing occurred in the fully intersecting fracture models when the apertures were equal. Mixing was found to be dependent only upon the relative size of the inlet and outlet fractures even with multiple intersections.For transport of a conservative solute in a discontinuous, random, discrete fracture system, the numerical model used the mixing algorithm for fracture intersections, developed from the physical model study. At each four-way intersection, a novel approach was used to uncouple and recouple the nodal points to ensure the proper assignment of concentrations to each fracture element. Using the laboratory-determined mixing algorithm, the numerical model demonstrated that more longitudinal and less lateral dispersion takes place than when complete mixing at fracture intersections is assumed. In addition, more longitudinal transport takes place in discontinuous than in continuous fracture systems. These findings indicate that contaminants migrating through fractured media, where the fracture walls are not in contact, will not be dispersed and diluted to the extent that previous numerical models have predicted; hence, the contaminant will be discharged to the biosphere in much greater concentration than expected.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1520-6904
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1520-6904
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
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  • 7
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 109 (1998), S. 5283-5289 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The Stark effect on the qR22(0,0.5) (ν=17 682.9251 cm−1) and qP11(0,1.5) (ν=17 682.1966 cm−1) branch features of the (0,0) B 2A1–X 2A1 band system of calcium methoxide, CaOCH3, was measured and analyzed to give the magnitude of the permanent electronic dipole moments, |μ|, of 1.58(8) D and 1.21(5) D for the X 2A1 and B 2A1 states, respectively. The dipole moments are compared with other monovalent calcium compounds and those predicted from a simple electrostatic model. Pure rotational transitions in the X 2A1 state were recorded using the pump/probe microwave-optical double resonance technique. The proton magnetic hyperfine splitting pattern confirms a C3v symmetry of the ground electronic state. The determined Fermi contact and dipolar parameters are: aF=−0.421(27) MHz; Taa=1.070(45) MHz, and |Tbb−Tcc|=0.292(47) MHz. The latter parameter is associated with the lifting of the K-degeneracy of this symmetric top molecule and mixing the I0=1/2 and I0=3/2 levels. © 1998 American Institute of Physics.
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  • 8
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 110 (1999), S. 881-889 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The Pe(1), F″=2.5 branch feature of the (0,0) D 3Π0e–X 3Δ1 band system of 51VN was recorded as a function of an applied static electric field. The resultant Stark splitting and shifts were analyzed giving values of 3.07(7) D and 6.1(4) D for the X 3Δ1 and D 3Π0e states, respectively, for the magnitude of the permanent electric dipole moment, |μ|. Similarly, the Ree(0.5) branch feature of the (0,0) A 4Π3/2–X 4Σ− band system of 52CrN was recorded as a function of an applied static electric field and analyzed to produce |μ| values of 2.31(4) D and 5.42(2) D for the X 4Σ− and A 4Π3/2 states, respectively. In order to facilitate the dipole moment determinations for 52CrN it was necessary to record and analyze the field free spectrum of the (0,0) A 4Π3/2–X 4Σ− subband system. A comparison of the dipole moments for the first row monoxides and mononitrides is made and trends are discussed with reference to a molecular orbital correlation scheme. © 1999 American Institute of Physics.
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  • 9
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 108 (1998), S. 2703-2711 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The pure rotational spectrum of BaCH3(X˜ 2A1) in its ground vibrational state has been recorded using millimeter/submillimeter direct absorption techniques, the first spectroscopic information obtained for this molecule. The radical was created using Broida-type oven/d.c. discharge methods by the reaction of barium vapor and Sn(CH3)4. Twenty-eight rotational transitions of the main isotopomer 138BaCH3 were recorded, as well as five for 136BaCH3 and three for the 137BaCH3 species. Being a prolate symmetric top, K ladder structure was observed in all transitions for BaCH3, as well as fine structure splittings which arise from the unpaired electron in the molecule. For the 137Ba isotopomer, hyperfine interactions were also resolved, arising from the spin of the barium nucleus. The complete data set has been analyzed with a 2A Hamiltonian, and rotational, spin-rotational, and magnetic hyperfine/nuclear quadrupole parameters accurately determined. The fine and hyperfine structure constants established from this study suggest a predominantly ionic bond for BaCH3, but with a considerable covalent component. Structural parameters for BaCH3 derived in this work are consistent with those of other alkaline earth monomethyl species. © 1998 American Institute of Physics.
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  • 10
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Plant breeding 116 (1997), S. 0 
    ISSN: 1439-0523
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Six six-row Nordic spring barley genotypes (Hordeum vulgare L.) were assessed in the field in Finland (1994 and 1995) for resistance to Rhynchosporium secalis (Oud.) J.J. Davis, the causal pathogen of scald, in artificially inoculated plots. The barleys were known not to contain major genes for resistance to scald and the purpose of these experiments was to identify quantitative differences in resistance to scald which might be exploitable in a breeding programme. Disease development was monitored, grain yield and yield components were recorded, and these data were compared with measurements taken from plants in plots kept free of disease. Data, averaged over both years, for disease development on the uppermost three leaves — areas under disease progress curves, terminal severity and apparent infection rates — indicated that ‘Verner’, ‘Pohto’ and ‘Pokko’ were symptomatically significantly more resistant to scald than ‘Arve’, ‘Loviisa’ and Jo 1599. Grain yields, thousand-grain weights, test weights and proportions of plump grains were all significantly reduced in plots inoculated with scald compared with those kept free of disease; ‘Verner’ appeared to be the most useful genotype for use in crossing programmes to improve scald resistance in Finnish barleys.
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