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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 105 (1996), S. 10535-10555 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We have measured the thermal conductivity of methane at temperatures from 308 K down to 190.585 K, which is just 21 mK above the critical temperature, and at densities up to 14 mol L−1. The data were obtained with an improved guarded parallel-plate cell with a new cryostat that was built especially for measurements in the critical region of methane. The new experimental data have a higher accuracy than those reported previously in the literature and enable us to examine the validity of the currently available theoretical description of the asymptotic and nonasymptotic behavior of the thermal conductivity of fluids in the critical region. Equations for the thermal conductivity of methane in a wide range of temperatures and densities are also presented. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 109 (1998), S. 717-736 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We have measured the thermal conductivity of an equimolar mixture of methane and ethane in the vicinity of the critical point. The new experimental data confirm that the thermal conductivity of a mixture does not diverge at the critical point but crosses over to a finite limiting behavior at the critical point. A quantitative representation of the thermal-conductivity data has been obtained in terms of a recently developed extension of the mode-coupling theory that incorporates the crossover between the behavior of the thermal conductivity close to and far away from the critical point. The same theory enables us also to predict other transport properties of the mixture in the vicinity of the critical point. © 1998 American Institute of Physics.
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 79 (1996), S. 2601-2608 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A magnetization model is presented that is used to cover trilayers containing two magnetic layers that are exchange coupled via an intermediate nonmagnetic layer and that have different crystalline anisotropies. The interfaces are coupled to the bulk by a twisted magnetization configuration which is evaluated using the Ritz method. By minimizing the total energy, experimental magnetization curves of strongly coupled Co/Ru sandwiches can be reproduced with a good precision and with the same set of parameters in two perpendicular field directions. These physical parameters can be determined with a good reliability and are in agreement with the literature except for the bulk anisotropy of the Co layer first deposited, which is twice as large as the known bulk value. This originates in the magnetoelastic contributions due to lattice misfit and interface roughness. It is shown that the interlayer exchange coupling forces the magnetization of both layers to be along the same axis in the low-field range notwithstanding the opposite sign of the anisotropy constants in most stacks. It is also demonstrated that the differences in the orientations of the moments in one Co layer are modest and depend on the various parameters. In particular, the bulk exchange constant is a decisive parameter that makes the calculated curves close to the experimental ones. © 1996 American Institute of Physics.
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 81 (1997), S. 4310-4312 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We present a magnetic sensor based on the giant magnetoresistance (GMR) effect, which can be used as a contactless potentiometer. The sensor consists of a novel GMR sensor scheme with an artificial antiferromagnetic subsystem. The sensor gives a sinusoidal signal in dependence on the direction of a rotating external magnetic field Hrot. With two sensors in a planar setup, the whole 360° angle range can easily be covered. The amplitude ΔR/R of the signal is about 5%. The signal amplitude runs through a very flat maximum and changes only by 5% within a field range of about 4.4–27.2 kA/m. This large field range, the magnetic window (Hw), is the main advantage of this sensor compared to other magnetic sensor physical principles for contactless potentiometers. Therefore, large mounting tolerances and variations in the field strength of the rotating permanent magnet can be accepted. The temperature dependence of the sensor is linear both for the ground resistance (R0) and the signal amplitude (ΔR), allowing simple and effective electronic temperature compensation. The sensor can be operated up to 150 °C. © 1997 American Institute of Physics.
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  • 5
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 68 (1996), S. 3635-3637 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We have studied the magnetic domain structure of a thin polycrystalline Co film by magnetic force microscopy (MFM). Domain walls of the cross-tie type have been observed for a Co film of 50 nm thickness. Due to the high lateral resolution of MFM we have been able to study the magnetic structure of a single cross tie. We have determined locations of Bloch lines within a domain wall comparing the experimental data with a theoretical model of a cross-tie wall. In order to explain our experimental results we have proposed a model for the interaction between a MFM tip and a cross-tie wall. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1572-9567
    Keywords: critical phenomena ; parallel-plate method ; thermal conductivity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A description is presented of the construction and operating procedure of an improved guarded parallel-plate instrument for measuring the thermal conductivity of fluids in the critical region. With the improved arrangement, it has been possible to reduce the temperature differences across the fluid layer between the two horizontal plates to values as low as 0.3 mK, thus allowing the thermal conductivity of fluids to be measured at temperatures as close as 20 mK to the critical temperature. The instrument has been used to measure the thermal conductivity of methane and of a mixture of methane and ethane in the close vicinity of the critical point.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 41 (1995), S. 148-158 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Rules are presented for the startup of an adiabatic tubular reactor, based on a qualitative analysis of the dynamic behavior of continuously-operated vapor- and liquid-phase processes. The relationships between the process dynamics, operating criteria, and operating constraints are investigated, since a reactor startup cannot be isolated from an entire plant startup. Composition control of the process material is critical to speed up plant startup operations and to minimize the amount of offgrade materials. The initial reactor conditions are normally critical for a successful startup. For process conditioning, a plant should have an operating mode at which the reactor can be included in a recycle loop together with its feed system and downstream process section. Experimental data of an adiabatic tubular reactor startup and thermal runaway demonstrate some operational problems when such an intermediate operating stage is missing. The derived rules are applied to an industrial, highly heat-integrated reactor section, and the resulting startup strategy is summarized in an elementary-step diagram.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 503-515 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The safeguarding methodology of chemical plants is usually based on controlling the instantaneous values of process state variables within a certain operating window, the process being brought to shutdown when operating constraints are exceeded. This method does not necessarily prevent chemical reactors suffering from a runaway during dynamic operations because (a) excessive amounts of unreacted chemicals can still accumulate in the process, and (b) no means are provided to the operating personnel to identify hazardous process deviations. A model-based startup and safeguarding procedure is developed for an industrial adiabatic tubular reactor to improve process safety during startup. The trajectories of manipulated variables are calculated by minimizing the amount of one of the main reactants in the reactor effuent. It is concluded that proper control of the initial reactor temperature profile is critical for a safe startup while the impact of other manipulated variables is relatively smaller than that of the initial reactor temperature profile.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Publication Date: 1997-11-01
    Print ISSN: 1063-651X
    Electronic ISSN: 1095-3787
    Topics: Physics
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  • 10
    Publication Date: 1996-03-01
    Print ISSN: 0021-8979
    Electronic ISSN: 1089-7550
    Topics: Physics
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