ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The results of the crystal structure analyses of (6RS,7SR,8RS)-7- methyl-8-phenyl-3-oxabicyclo[4.2.0]oct-1-en-8-ol (C14H16O2), (1SR,2RS,8RS)-8- methylthio-3-oxatricyclo[6.4.0.02,7]dodec-6-en-1-ol (C12H18O2S) and (1RS,2RS,6SR,7SR,8RS)-8-methyl-3-oxatricyclo[6.4.0.02,7]dodeca-1,6,7-triol (C12H20O4) allow interpretation of the nucleophilic attack reactions of ketone enolates on the short-lived dehydrodihydropyran intermediate, showing that the presence of the O atom influences the reactivity of the dienic system. The structure and conformation of the above compounds are discussed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270195010134
Permalink