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  • 1995-1999  (2)
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 32 (1996), S. 119-124 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: Crystallization kinetics studies for six experimental glass formulations in the system Na2O-CaO-SiO2-P2O5 synthesized by wet chemistry were conducted by means of differential thermal analysis. These glasses had CaO/P2O5 and SiO2/(CaO + Na2O) ratios ranging from 8.74-3.38 and 0.92-3.03, respectively. Samples of each glass (n = 30 were heated from 23 to 1250°C under N2 atmosphere at heating rates ranging from 10 to 50°C/min. Glass-ceramics were obtained after heat treating the initial glasses at temperatures determined from their DTA exotherms. The activation energy of crystallization for each glass composition was calculated from an expression-relating log-heating rate and the reciprocal of the exothermic peak temperature. The compositions of the six glasses were significantly different (p = 0.05). The activation energy of crystallization (Q) values ranged from 196 to 782 kJ/mole. A correlation was obtained between Q and CaO/P2O5 and between Q and the Young's modulus (p 〈 0.001). Two of the six glasses exhibited bulk crystallization. X-ray diffraction studies showed that four of the six glasses exhibited different proportions of crystalline phases following heat treatment. These phases were wollastonite (CaSiO3), Na2CaSi3O9, combeite [Na4Ca3SI6O16(OH)2], and some unidentifiable phases. Two of the six bioceramic materials had a mixture of unknown crystalline phases. © 1996 John Wiley & Sons, Inc.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 1995-06-01
    Description: Cordierite is a characteristic mineral of many peraluminous felsic igneous rocks. A combination of T-P-X parameters, which overlap the stability conditions for felsic magmas, control its formation. Critical among these parameters are relatively low T, low P, and typically high (Mg+Fe2+), Mg/Fe2+, A/CNK, aAl2O3, and fO2. Spatial and textural information indicate that cordierite may originate in one of three principal ways in felsic igneous rocks: Type 1 Metamorphic: (a) xenocrystic (generally anhedral, many inclusions, spatial proximity to country rocks and pelitic xenoliths); (b) restitic (generally anhedral, high-grade metamorphic inclusions); Type 2 Magmatic: (a,b) peritectic (subhedral to euhedral, associated with leucosomes in migmatites or as reaction rims on garnet); (c) cotectic (euhedral, grain size compatibility with host rock, few inclusions); (d) pegmatitic (large subhedral to euhedral grains, associated with aplite-pegmatite contacts or pegmatitic portion alone); and Type 3 Metasomatic (spatially related to structural discontinuities in host, replacement of feldspar and/or biotite, intergrowths with quartz). Of these, Type 2a (peritectic) and Type 2c (cotectic) predominate in granitic and rhyolitic rocks derived from fluid-undersaturated peraluminous magmas, and Type 2d (pegmatitic) may be the most common type in fluid-saturated systems.
    Print ISSN: 0026-461X
    Electronic ISSN: 1471-8022
    Topics: Geosciences
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