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  • crystal structure  (30)
  • Cell & Developmental Biology
  • 1995-1999  (34)
  • 1
    Electronic Resource
    Electronic Resource
    Die Kristallstruktur von KPdMIVF7 (MIV = Zr, Hf) (1995)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 621 (1995), S. 1047-1052 
    Details
    ISSN: 0044-2313
    Keywords: Zirconium fluoride ; hafnium fluoride ; ternary fluorides ; KPdMIVF7 (MIV = Zr, Hf) ; crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The Crystal Structure of KPdMIVF7 (MIV = Zr, Hf)Blue single crystals of KPdZrF7 are obtained by heating the binary fluorides in sealed Pt-tubes under dry argon (solid state reaction, T ≍ 720°C, t ≍ 14 d). The compound crystallizes orthorhombically in the space group Pnna-D2h6 (Nr. 52); lattice parameters are a = 1 132.3(5) pm, b = 797.5(2) pm, c = 639.8(1) pm; Z = 4 (Four cycle diffractometer data, AED2). According to [F4PdF2/1ZrF5] distortet [PdF6]-octaedra are connected with pentagonal-bipyramidal [ZrF7]-polyhedra via two bridging F-, resulting in [PdZrF11]-groups. These [PdZrF11]-groups built up a threedimensional-network with K+ in its spacings. KPdHfF7 crystallizes isotypically (a = 1 136.1(3) pm, b = 796.4(2) pm und c = 638.8(1) pm; four cycle diffractometer data, AED2).
    Notes: Durch Tempern der binären Fluoride im verschweißten Pt-Rohr unter Schutzgas (Ar, Festkörperreaktion, T ≍ 720°C, t ≍ 14d) erhält man blaue Einkristalle von KPdZrF7 [eigener Strukturtyp, orthorhombisch, Pnna-D2h6 (Nr. 52); a = 1 132,3(5) pm, b = 797,5(2) pm, c = 639,8(1) pm; Z = 4; Vierkreisdiffraktometerdaten AED2]. Pd2+ ist verzerrt oktaedrisch von 6 F- umgeben, wohingegen Zr4+ pentagonalbipyramidal von 7 F- koordiniert wird. Beide Koordinationspolyeder sind gemäß [F4PdF2/1ZrF5] kantenverknüpft und bilden mit weiteren solcher [PdZrF11]-Einheiten durch Eckenverknüpfung ein dreidimensionales Raumnetz, in dessen Lücken K+ eingelagert ist. Nach Vierkreisdiffraktometerdaten (AED2) kristallisiert KPdHfF7 isotyp (a = 1 136,1(3) pm, b = 796,4(2) pm und c = 638,8(1) pm).
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19956210626
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  • 2
    Electronic Resource
    Electronic Resource
    Cs2Cu3MIVF12 (MIV = Zr, Hf) - Kristallstruktur und magnetische Eigenschaften (1995)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 621 (1995), S. 993-1000 
    Details
    ISSN: 0044-2313
    Keywords: Zirconium(IV) fluoride ; hafnium(IV) fluoride ; Cs2Cu3MIVF12 (MIV = Zr, Hf) ; crystal structure ; magnetic properties ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Cs2Cu3MIVF12 (MIV = Zr, Hf) - Crystal Structure and Magnetic BehaviourColourless single crystals of Cs2Cu3ZrF12 are obtained by heating the binary fluorides in sealed Pt-tubes under dry argon (solid state reaction, T ≍ 700°C, t ≍ 7-10 d). The compound crystallizes trigonal-rhomboedrical in the space group R3m-D3d5 (Nr. 166); lattice parameters are a = 716.61(6) pm, c = 2 046.4(2) pm, Z = 3 (Four cycle diffractometer data, AED 2). The structure is dominated by layers of corner-sharing, Jahn-Teller-distorted [CuF6]-Octahedra, which are connected via regular [ZrF6]-Octahedra to stackings parallel [00.1]. Cs+-ions are located in the spacings of the octahedra-network. From powder data Cs2Cu3HfF12 with a = 716.32(4) pm, c = 2 048.6(2) pm is isotypic. Both compounds show antiferromagnetic behaviour already at temperatures about 200 K.
    Notes: Durch Umsetzung der binären Fluoride im verschweißten Pt-Rohr unter Schutzgas (Ar, Festkörperreaktion, T ≍ 700°C, t ≍ 20d) erhält man farblose Einkristalle von Cs2Cu3ZrF12. [Trigonal-rhomboedrisch, R3m-D3d5 (Nr. 166), a = 716,61(6) pm, c = 2 046,4(2) pm, Z = 3 (Vierkreisdiffraktometerdaten, AED 2)]. Strukturbestimmend sind Schichten eckenverknüpfter, Jahn-Teller-verzerrter [CuF6]-Oktaeder, welche - über reguläre [ZrF6]-Oktaeder verknüpft - Stapel entlang [00.1] bilden. In den Hohlräumen der Struktur sind Cs+-Ionen eingelagert. Nach Pulverdaten kristallisiert Cs2Cu3HfF12 mit a = 716,32(4) pm, c = 2 048,6(2) pm isotyp. Beide Stoffe zeigen bereits bei Temperaturen um 200 K antiferromagnetisches Verhalten.
    Additional Material: 8 Ill.
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    URL: http://dx.doi.org/10.1002/zaac.19956210617
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  • 3
    Electronic Resource
    Electronic Resource
    Zur Kristallstruktur von LiPdGaF6, RbPdAlF6 und K1,06Pd0,95Fe1,05F6 (1995)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 621 (1995), S. 1385-1394 
    Details
    ISSN: 0044-2313
    Keywords: Palladium ; quaternary fluorides ; LiPdGaF6 ; RbPdAlF6 ; K1.06Pd0.95Fe1.05F6 ; crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The Crystal Structure of LiPdGaF6, RbPdAlF6 and K1.06Pd0.95Fe1.05F6Single crystals of LiPdGaF6 (blue; trigonal, P31c-D3d2 (No. 163), a = 505.72(2), c = 923.7(2) pm; LiCaAlF6-Type [1]), RbPdAlF6 (violet; orthorhombic, Pnma-D2h16 (No. 62), a = 729.0(1), b = 711.1(1), c = 1006.5(2) pm; CsAgFeF6-Type [2]) and K1.06Pd0.95Fe1.05F6 (greenish-blue; tetragonal, P42/mbc-D4h13 (No. 135), a = 1 279.07(7), c = 800.2(1) pm; K1,08MnFeF6-Type [3]; four cycle diffractometer data, Siemens AED2) are obtained by heating the binary fluorides in sealed Pd-tubes under dry argon [solid state reaction, T ≈ 650, t ≈ 19 d (39 d, 24 d)].
    Notes: Durch Umsetzung von äquimolaren Gemengen der binären Fluoride im verschweißten Pd-Rohr unter Schutzgas [Ar, Festkörperreaktion, T = 650°C, t = 19 d (39 d, 24 d)] erhält man Einkristalle von LiPdGaF6 (blau, trigonal, P31c-D3d2 (No. 163), a = 505,72(2), c = 923,7(2) pm, LiCaAlF6-Typ [1]), RbPdAlF6 (violett, orthorhombisch, Pnma-D2h16 (No. 62), a = 729,0(1), b = 711,1(1), c = 1006,5(2) pm, CsAgFeF6-Typ [2]) sowie K1,06Pd0,95Fe1,05F6 (blau-grün, tetragonal, P42/mbc-D4h13 (No. 135), a = 1279,07(7), c = 800,2(1) pm; K1,08MnFeF6-Typ [3]; jeweils Vierkreisdiffraktometerdaten).
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19956210818
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  • 4
    Electronic Resource
    Electronic Resource
    Identification of heterotrimeric G proteins in human sperm tail membranes (1995)
    New York, NY [u.a.] : Wiley-Blackwell
    Molecular Reproduction and Development 40 (1995), S. 345-354 
    Details
    ISSN: 1040-452X
    Keywords: Signal transduction ; α-subunit ; β-subunit ; Peptide antisera ; Flagellum ; Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology
    Notes: Heterotrimeric G proteins play important roles as signal transducing components in various mammalian sperm functions. We were interested in the distribution of G proteins in human sperm tails. Prior to membrane preparation, spermatozoa were separated from contaminating cells which are frequently present in human ejaculates. Enriched human sperm tail membranes were generated by using hypoosmotic swelling and homogenization procedures. Antisera against synthetic peptides were used to identify G proteins in immunoblots. AS 8, an antiserum directed against an amino acid sequence that is found in most G protein α-subunits, and A 86, which detects all known pertussis toxin-sensitive α-subunits, reacted specifically with a 40-kDa protein. Antisera against individual G protein α-subunits failed to detect any specific antigens in enriched tail membranes AS 36, recognizing the ã2-subunit of G proteins, identified a 35-kDa protein in sperm tail membranes. Antisera against the 36-kDa β1-subunit did not detect any relevant proteins in the membrane fraction. Neither G protein α-subunits nor G protein β-subunits were found in the cytosol. ADP ribosylation of spermatozoal membrane or cytosolic proteins revealed no pertussis toxin-sensitive α-subunits. However, membrane preparations of nonpurified human spermatozoa contained α2 subunits, as shown immunologically and by ADP ribosylation; they most probably derived from somatic cells which are frequently present in human ejaculates. Our results stress the fact that spermatozoa need to be purified before sperm membrane preparation to avoid misinterpretations caused by contaminating cells. Furthermore, we suggest that G proteins in membranes of human sperm tails belong to a novel subtype of G protein α-subunits; the putative β-subunit was identified as a β2-subunit. © 1995 Wiley-Liss, Inc.
    Additional Material: 5 Ill.
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    URL: http://dx.doi.org/10.1002/mrd.1080400311
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  • 5
    Electronic Resource
    Electronic Resource
    Molecular genetics of the germinal center reaction (1998)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Cellular Physiology 177 (1998), S. 525-534 
    Details
    ISSN: 0021-9541
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: No abstract.
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  • 6
    Electronic Resource
    Electronic Resource
    Synthese und Kristallstruktur von Ba6Lu4Zn10O22 mit [OBa6]-OktaedernIn memoriam Professor Wilhelm Klemm (1996)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 622 (1996), S. 100-104 
    Details
    ISSN: 0044-2313
    Keywords: Barium ; zinc ; rare earth oxide ; crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On the Synthesis and Crystal Structure of Ba6Lu4Zn10O22 with [OBa6] OctahedraSingle crystals of Ba6Lu4Zn10O22 have been prepared by high temperature reactions and investigated by X-ray techniques. This compound is isotypic to Ba3In2Zn5O11 and the first member of the Rare Earth elements. Ba6Lu4Zn10O22 crystallizes with cubic symmetry, space group Td4-F43m, a = 13.452(1) Å and Z = 4. Zn2+ shows a tetrahedral, Lu3+ an octahedral and Ba2+ a three-fold capped trigonal prismatic coordination by O2-. The ZnO4 tetrahedra and LuO6 octahedra are forming macro polyhedra of the type Zn10O20 and Lu4O16. A discussion is given for the Ba6O33 and Ba6O42 groups.
    Notes: Mit Hochtemperaturreaktionen wurden Einkristalle von Ba6Lu4Zn10O22 erhalten und röntgenographisch untersucht. Diese Verbindung ist die erste aus der Reihe der Lanthanoide und ist isotyp zu Ba3In2Zn5O11. Ba6Lu4Zn10O22 kristallisiert kubisch in der Raumgruppe Td2-F43m mit a = 13,452(1) Å und Z = 4. Zn2+ ist tetraedrisch, Lu3+ oktaedrisch und Ba2+ dreifach überkappt trigonal prismatisch von O2--Ionen koordiniert. Die ZnO4-Tetraeder und LuO6-Oktaeder sind zu Makropolyedern des Typs Zn10O20 und Lu4O16 verknüpft. Diskutiert werden auch die Baugruppen Ba6O33 und Ba6O42.
    Additional Material: 4 Ill.
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    URL: http://dx.doi.org/10.1002/zaac.19966220115
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  • 7
    Electronic Resource
    Electronic Resource
    Zur Chemie des Dimesityleisens. VIII. Lösungsverhalten von Tetramesityldieisen und die Kristallstruktur eines Dimethoxyethan-Addukts (1996)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 622 (1996), S. 756-758 
    Details
    ISSN: 0044-2313
    Keywords: Dimesityliron ; crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Chemistry of Dimesityl Iron. VIII Solution Behaviour of Tetramesityldiiron and Crystal Structure of Dimesityl(dimethoxyethane)ironThe dimer dimesityliron yields in polar solvents solvated monomers. The adduct with dimethoxyethane was isolated and characterized by X-ray structure determination.
    Notes: Während Dimesityleisen in unpolaren Lösungsmitteln dimer vorliegt, spaltet es in stärker polaren Lösungsmitteln in solvatisierte Monomere auf. Mit Dimethoxyethan wurde ein Addukt isoliert und strukturell charakterisiert.
    Additional Material: 1 Ill.
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    URL: http://dx.doi.org/10.1002/zaac.19966220433
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  • 8
    Electronic Resource
    Electronic Resource
    H—TiO oder TiB2?? - eine Korrektur (1996)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 622 (1996), S. 1035-1037 
    Details
    ISSN: 0044-2313
    Keywords: Titanium diboride ; crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: H—TiO or TiB2? - A CorrectionReinvestigations of “H—TiO” single crystals and the comparison with measurements of TiB2 crystals have shown that “H—TiO” in fact is titanium diboride.
    Notes: Eine erneute Untersuchung der Einkristalle von „H—TiO“ und der Vergleich mit Messungen an TiB2-Kristallen hat gezeigt, daß es sich bei „H—TiO“ um Titandiborid handelte.
    Additional Material: 1 Ill.
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    URL: http://dx.doi.org/10.1002/zaac.19966220618
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  • 9
    Electronic Resource
    Electronic Resource
    Cis-/Trans-Isomerie bei Bis-(trisalkoxy)-hexavanadaten: cis-Na2[V6IVO7(OH)6{(OCH2)3CCH2OH}2] · 8 H2O, cis-(CN3H6)3[VIVV5VO13{(OCH2)3CCH2OH}2] · 4,5 H2O und trans-(CN3H6)2[V6VO13{(OCH2)3CCH2OH}2] · H2OProfessor Herbert W. Roesky zum 60. Geburtstag gewidmet (1995)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 621 (1995), S. 1818-1831 
    Details
    ISSN: 0044-2313
    Keywords: Polyoxovanadates ; alkoxy hexavanadates ; bis-(trisalkoxy)-hexavanadates: UV/VIS ; IR ; ESR ; magnetic measurements ; crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Cis-/Trans-Isomerism of Bis-(trisalkoxy)-hexavanadates: cis-Na2[V6IVO7(OH)6{(OCH2)3CCH2OH}2] · 8 H2O, cis-(CN3H6)3[VIVV5VO13{(OCH2)3CCH2OH}2] · 4.5 H2O and trans-(CN3H6)2[V6VO13{(OCH2)3CCH2OH}2] · H2OPolyoxovanadates with distorted Lindquist-structure, in which six of the twelve μ2-oxygen atoms are formally replaced by the oxygen atoms of two coordinated pentaerythritol ligands, can be prepared by a simple method in an aqueous medium. The “fully reduced”, six-fold protonated compound cis-Na2[V6VO7(OH)6{(OCH2)3CCH2OH}2] · 8 H2O (1), the mixed valence species cis-(CN3H6)3[VIVV5VO13{(OCH2)3CCH2OH}2] · 4.5 H2O (2) containing one localized VIV centre and the “fully oxidized” compound trans-(CN3H6)2[V6VO13{(OCH2)3CCH2 · OH}2] · H2O (3) have been synthesized and characterized by UV/VIS-, IR- and EPR-spectroscopy, by magnetic measurements, cyclic voltammetry and by a single-crystal X-ray structure analysis.The organic {(CH2)3CCH2OH}3+-groups tend to cap the triangular faces formed by μ2-oxygen atoms of the central approximately octahedral {V6O19}-unit. Therefore the anions of bis-(trisalkoxy)-hexavanadates can exist in a trans-form as well as in an isomeric cis-form referring to a “basic” plane of four vanadium atoms of the {V6}-octahedron. The different relative positions of the ligands have a significant influence on the redox potentials of the compounds.For structural details see “Inhaltsübersicht”.
    Notes: Die beschriebenen Trisalkoxy-polyoxovanadate mit verzerrter Lindqvist-Struktur, in der sechs der zwölf μ2-verbrückenden Sauerstoffatome formal durch die Sauerstoffatome von zwei koordinierten Pentaerythritolliganden ((HOCH2)3CCH2OH) ersetzt wurden, können auf einfache Weise im wäßrigen Medium dargestellt werden. Durch UV/VIS-, IR- und ESR-Spektroskopie sowie durch magnetische Messungen, Cyclovoltammetrie und Röntgenstrukturanalyse wurden die „vollständig reduzierte“, sechsfach protonierte Verbindung cis-Na2[V6IVO7(OH)6{(OCH2)3CCH2OH}2] ·8 H2O (1), das gemischtvalente, ein lokalisiertes V(IV)-Zentrum enthaltende Derivat cis-(CN3H6)3[VIVV5VO13{(OCH2)3CCH2OH}2] · 4,5 H2O (2) sowie die „vollständig oxidierte“ Verbindung trans-(CN3H6)2[V6VO13{(OCH2)3CCH2OH}2] · H2O (3) charakterisiert.Da die organischen {(CH2)3CCH2OH}3+-Gruppen, formal betrachtet, die jeweils aus drei μ2-O-Atomen gebildeten Flächen der zentralen, angenähert oktaedrischen {V6O19}-Einheit überdachen, können die Anionen der Bis-(trisalkoxy)-hexavandate sowohl in einer trans-Form als auch in einer stellungsisomeren cis-Form bezüglich einer aus vier Vanadiumatomen des {V6}-Oktaeders gebildeten „Basis“-Ebene auftreten. Die unterschiedliche Anordnung der Liganden hat einen signifikanten Einfluß auf die Redoxpotentiale der Verbindungen.1: cis-Na2[VI6VO7(OH)6{(OCH2)3CCH2OH}2] · 8 H2O: Raumgruppe P1, a = 987,2(2) pm, b = 1 080,6(2) pm, c = 1 654,3(3) pm, α = 94,83(1)°, β = 98,73(2)°, γ = 116,05(1)°, V = 1,5443(5) nm3, Z = 2, R = 0,067 für 5 913 unabhängige Reflexe [F 〉 4σ(F)].2: cis-(CN3H6)3[VIVV5VO13{(OCH2)3CCH2OH}2] · 4,5 H2O: Raumgruppe Pbca, a = 1 569,5(3) pm, b = 1 652,3(3) pm, c = 2 758,2(6) pm, V = 7,153(2) nm3, Z = 8, R = 0,126 für 2 698 unabhängige Reflexe [F 〉 4σ(F)].3: trans-(CN3H6)2[V6VO13{(OCH2)3CCH2OH}2] · H2O: Raumgruppe C2/c, a = 2 293,4(3) pm, b = 1 102,6(2) pm, c = 1 368,6(2) pm, β = 120,87(1)°, V = 2,9705(8) nm3, Z = 4, R = 0,046 für 2 206 unabhängige Reflexe [F 〉 4σ(F)].
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19956211103
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  • 10
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    Electronic Resource
    Verbindungen in den Systemen Kalium(Rubidium)/Gold/Antimon: K3Au3Sb2, Rb3Au3Sb2 und K1,74Rb0,26RbAu3Sb2Professor Herbert Jacobs zum 60. Geburtstag gewidmet (1996)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 622 (1996), S. 635-639 
    Details
    ISSN: 0044-2313
    Keywords: Alkali metal gold antimon ; synthesis ; single-crystals ; crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Compounds in the Systems Potassium(Rubidium)/Gold/Antimony: K3Au3Sb2, Rb3Au3Sb2, and K1,74Rb0,26RbAu3Sb2Brittle, silver coloured single crystals of K3Au3Sb2, Rb3Au3Sb2 and K1,74Rb0,26RbAu3Sb2 were obtainded by reaction of the alkali metal azides (KN3, RbN3) with gold and antimon powder at 550°C. The structures of the isotypic compounds (R3m, Z = 3) were determined by X-ray single-crystal diffractometer data: K3Au3Sb2, a = 6,198(2) Å, c = 21,520(5) Å, R/Rw (w = 1) = 0,046/0,058, Z(F02) ≥ 3σ(F02) = 175, Z(Var.) = 14; Rb3Au3Sb2, a = 6,443(3), c = 21,69(2), R/Rw (w = 1) = 0,059/0,082, Z(F02) ≥ 3σ(F02) = 258, Z(Var.) = 14; K1,74Rb0,26RbAu3Sb2, a = 6,288(2) Å, c = 21,617(5) Å, R/Rw (w = 1) = 0,049/0,069, Z(F02) ≥ 3σ(F02) = 390, Z(Var) = 14. The compounds crystallize with the K3Cu3P2-structure type. The Au—Sb partial structures consist of ∞2[AuSb2/3] layers with linear Sb—Au—Sb dumb-bells and SbAu3 pyramids. The layers are separated by two crystallographically independent alkali metal atoms along [001].
    Notes: Spröde, silberfarbene Einkristalle von K3Au3Sb2, Rb3Au3Sb2 und K1,74Rb0,26RbAu3Sb2 wurden durch Reaktion der Alkalimetallazide (KN3, RbN3) mit Gold- und Antimonpulver bei 550°C erhalten. Die Strukturen der isotypen Verbindungen (R3m, Z = 3) wurden aus Einkristall-Röntgen-Diffraktometerdaten bestimmt: K3Au3Sb2, a = 6,198(2) Å, c = 21,520(5) Å, R/Rw (w = 1) = 0,046/0,058, Z(F02) ≥ 3σ(F02) = 175, Z(Var.) = 14; Rb3Au3Sb2, a = 6,443(3), c = 21,69(2), R/Rw (w = 1) = 0,059/0,082, Z(F02) ≥ 3σ(F02) = 258, Z(Var.) = 14; K1,74Rb0,26RbAu3Sb2, a = 6,288(2) Å, c = 21,617(5) Å, R/Rw (w = 1) = 0,049/0,069, Z(F02) ≥ 3σ(F02) = 390, Z(Var) = 14. Die Verbindungen kristallisieren im K3Cu3P2-Typ. Die Au—Sb-Teilstruktur besteht aus ∞2[AuSb2/3]-Schichten mit linearen Sb—Au—Sb-Hanteln und SbAu3-Pyramiden. Die Schichten werden längs [001] durch zwei kristallographisch unterschiedliche Alkalimetallatome separiert.
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    URL: http://dx.doi.org/10.1002/zaac.19966220411
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