ISSN:
0749-1581
Keywords:
2D NMR
;
Perezone
;
Thiourea
;
NOESY
;
HMBC
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
A combination of NMR experiments, including 13C and 15N DEPT, COSY, NOESY, HMQC and HMBC experiments, was used to assign the structures and stereochemistries of two isomeric bicyclo[2.2.2]octenedione derivatives produced by the reaction of perezone with thiourea, followed by treatment with silica gel. A possible mechanism of the reaction is suggested.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1260330103
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