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  • 2000-2004  (253)
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  • 1
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 343-346 (May 2000), p. 500-510 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Journal of metastable and nanocrystalline materials Vol. 8 (May 2000), p. 500-510 
    ISSN: 1422-6375
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 112 (2000), S. 6678-6688 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The combination of vibrationally mediated photofragment yield spectroscopy, which excites molecules prepared in single vibrational states, and multiphoton fluorescence spectroscopy, which excites molecules cooled in a supersonic expansion, provides detailed information on the energetics and vibrational structure of the first excited singlet state (S1) of isocyanic acid (HNCO). Dissociation of molecules prepared in individual vibrational states by stimulated Raman excitation probes vibrational levels near the origin of the electronically excited state. Detection of fluorescence from dissociation products formed by multiphoton excitation through S1 of molecules cooled in a supersonic expansion reveals the vibrational structure at higher energies. Both types of spectra show long, prominent progressions in the N–C–O bending vibration built on states with different amounts of N–C stretching excitation and H–N–C bending excitation. Analyzing the spectra locates the origin of the S1 state at 32 449±20 cm−1 and determines the harmonic vibrational frequencies of the N–C stretch (ω3=1034±20 cm−1), the H–N–C bend (ω4=1192±19 cm−1), and the N–C–O bend (ω5=599±7 cm−1), values that are consistent with several ab initio calculations. The assigned spectra strongly suggest that the N–C stretching vibration is a promoting mode for internal conversion from S1 to S0. © 2000 American Institute of Physics.
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 114 (2001), S. 10835-10844 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Direct observation of all three photofragmentation channels of HNCO gives the relative yields of 3NH+CO, H+NCO, and 1NH+CO at nine different photolysis energies for both thermal and vibrationally excited molecules. Each higher energy channel dominates as it becomes accessible, but vibrational excitation changes the relative yield of 1NH markedly. Photolysis of HNCO(3ν1) at the same total energy yields up to 2.5 times more NCO with a corresponding reduction in 1NH. The relative yield of 3NH and NCO, however, is indifferent to vibrational excitation. The dependence of the yields on vibrational excitation supports a picture in which direct decomposition on the S1 surface produces 1NH+CO and in which internal conversion to S0 leads to H+NCO, by spin-allowed unimolecular decay, and to 3NH+CO, by intersystem crossing and decomposition on T1. The observed vibrational enhancement of the NCO yield is consistent with vibrational excitation impeding the decomposition to 1NH+CO on S1 and, thus, increasing the number of molecules that cross to S0 and decay to H+NCO. © 2001 American Institute of Physics.
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  • 5
    Electronic Resource
    Electronic Resource
    Bingley : Emerald
    The @journal of product & brand management 13 (2004), S. 192-199 
    ISSN: 1061-0421
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Economics
    Notes: The aim of this study is to find out the effect of pricing on the diffusion of cellular subscriptions in Finland. There is a lack of studies on the effect of (telecommunications) service pricing on its diffusion. In the present study, a modified logistic model is applied for estimating the impact of price on the diffusion. The effect of cellular tariffs and cellular phone prices on the market potential and the diffusion rate are evaluated. Whereas almost all previous studies focusing on durables suggest that price affects either the market potential or the diffusion rate, the results of this study indicate that cellular call tariffs and cellular phone prices are not significant predictors of diffusion of cellular subscriptions. It is thus concluded that the logistic diffusion model might implicitly capture the somewhat constant price decline of cellular communications.
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  • 6
    Electronic Resource
    Electronic Resource
    [s.l.] : Macmillian Magazines Ltd.
    Nature 412 (2001), S. 835-838 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Hen egg-white lysozyme (HEWL) was the first enzyme to have its three-dimensional structure determined by X-ray diffraction techniques. A catalytic mechanism, featuring a long-lived oxocarbenium-ion intermediate, was proposed on the basis of model-building studies. The ‘Phillips’ ...
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  • 7
    Electronic Resource
    Electronic Resource
    Palo Alto, Calif. : Annual Reviews
    Annual Review of Biomedical Engineering 2 (2000), S. 511-550 
    ISSN: 1523-9829
    Source: Annual Reviews Electronic Back Volume Collection 1932-2001ff
    Topics: Technology , Medicine
    Notes: Abstract We review some of the most recent advances in the area of wavelet applications in medical imaging. We first review key concepts in the processing of medical images with wavelet transforms and multiscale analysis, including time-frequency tiling, overcomplete representations, higher dimensional bases, symmetry, boundary effects, translational invariance, orientation selectivity, and best-basis selection. We next describe some applications in magnetic resonance imaging, including activation detection and denoising of functional magnetic resonance imaging and encoding schemes. We then present an overview in the area of ultrasound, including computational anatomy with three-dimensional cardiac ultrasound. Next, wavelets in tomography are reviewed, including their relationship to the radon transform and applications in position emission tomography imaging. Finally, wavelet applications in digital mammography are reviewed, including computer-assisted diagnostic systems that support the detection and classification of small masses and methods of contrast enhancement.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd
    Global change biology 8 (2002), S. 0 
    ISSN: 1365-2486
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: Natural peatlands accumulate carbon (C) and nitrogen (N). They affect the global climate by binding carbon dioxide (CO2) and releasing methane (CH4) to the atmosphere; in contrast fluxes of nitrous oxide (N2O) in natural peatlands are insignificant. Changes in drainage associated with forestry alter these greenhouse gas (GHG) fluxes and thus the radiative forcing (RF) of peatlands. In this paper, changes in peat and tree stand C stores, GHG fluxes and the consequent RF of Finnish undisturbed and forestry-drained peatlands are estimated for 1900–2100. The C store in peat is estimated at 5.5 Pg in 1950. The rate of C sequestration into peat has increased from 2.2 Tg a--1 in 1900, when all peatlands were undrained, to 3.6 Tg a--1 at present, when c. 60% of peatlands have been drained for forestry. The C store in tree stands has increased from 60 to 170 Tg during the 20th century. Methane emissions have decreased from an estimated 1.0–0.5 Tg CH4--C a--1, while those of N2O have increased from 0.0003 to 0.005 Tg N2O--N a--1. The altered exchange rates of GHG gases since 1900 have decreased the RF of peatlands in Finland by about 3 mW m--2 from the predrainage situation. This result contradicts the common hypothesis that drainage results in increased C emissions and therefore increased RF of peatlands. The negative radiative forcing due to drainage is caused by increases in CO2 sequestration in peat (--0.5 mW m--2), tree stands and wood products (--0.8 mW m--2), decreases in CH4 emissions from peat to the atmosphere (--1.6 mW m--2), and only a small increase in N2O emissions (+0.1 mW m--2). Although the calculations presented include many uncertainties, the above results are considered qualitatively reliable and may be expected to be valid also for Scandinavian countries and Russia, where most forestry-drained peatlands occur outside Finland.
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  • 9
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd
    Global change biology 6 (2000), S. 0 
    ISSN: 1365-2486
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: We measured a cut-away peatland's CH4 dynamics using the static chamber technique one year before and two years after restoration (rewetting). The CH4 emissions were related to variation in vegetation and abiotic factors using multiple linear regression. A statistical model for CH4 flux with cottongrass cover (Eriophorum vaginatum L.), soil temperature, water level, and effective temperature sum index as driving variables explained most (r2 = 0.81) of the temporal and spatial variability in the fluxes. In addition to the direct increasing effect of raised water level on CH4 emissions, rewetting also promoted an increase of cottongrass cover which consequently increased carbon flux (substrate availability) into the system. The seasonal CH4 dynamics in tussocks followed seasonal CO2 dynamics till mid August but in late autumn CH4 emissions increased while CO2 influxes decreased. The reconstructed seasonal CH4 exchange was clearly higher following the rewetting, although it was still lower than emissions from pristine mires in the same area. However, our simulation for closed cottongrass vegetation showed that CH4 emissions from restored peatlands may remain at a lower level for a longer period of time even after sites have become fully vegetated and colonized by mire plants.
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  • 10
    Electronic Resource
    Electronic Resource
    Oxford, UK; Malden, USA : Blackwell Science Inc
    Restoration ecology 12 (2004), S. 0 
    ISSN: 1526-100X
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology
    Notes: The reintroduction of Sphagnum fragments has been found to be a promising method for restoring mire vegetation in a cutaway peatland. Although it is known that moisture controls Sphagnum photosynthesis, information concerning the sensitivity of carbon dynamics on water-level variation is still scarce. In a 4-year field experiment, we studied the carbon dynamics of reintroduced Sphagnum angustifolium material in a restored (rewetted) cutaway peatland. Cutaway peatland restored by Sphagnum reintroduction showed high sensitivity to variation in water level. Water level controlled both photosynthesis and respiration. Gross photosynthesis (PG) had a unimodal response to water-level variation with optimum level at −12 cm. The range of water level for high PG (above 60% of the maximum light-saturated PG) was between 22 and 1 cm below soil surface. Water level had a dual effect on total respiration. When the water level was below soil surface, peat respiration increased rapidly along the lowering water level until the respiration rate started to slow down at approximately −30 cm. Contrary to peat respiration, the response of Sphagnum respiration to water-level variation resembled that of photosynthesis with an optimum at −12 cm. In optimal conditions, Sphagnum reintroduction turned the cutaway site from carbon source to a sink of 23 g C/m2 per season (mid-May to the end of September). In dry conditions, lowered photosynthesis together with the higher peat respiration led to a net loss of 56 g C/m2. Although the water level above the optimum amplitude restricted CO2 fixation, a decrease in peat respiration led to a positive CO2 balance of 9 g C/m2.
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