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  • 1
    ISSN: 1750-3841
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Conformational changes in bovine serum albumin (BSA), Ca++-free α-lactalbumin(apo-α-lac), and Ca++-saturated α-lactalbumin(holo-ct-lac) were examined via Fourier transform infrared (FTIR) spectroscopy after pressure treatment up to 1270 MPa. BSA showed minimal irreversible secondary structural changes with pressurization, showing a slight loss of β-sheet structure in favor of α-helix. Apo-α-lac underwent major irreversible changes and exhibited infrared bands characteristic of aggregation upon decompression. Holo-α-lac showed extensive resistance to high pressure with no major structural changes. The rich disulfide content in BSA and the presence of Ca++ in holo-α-lac may play important roles in stabilizing these proteins against pressure denaturation.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Understanding spatial population dynamics is fundamental for many questions in ecology and conservation. Many theoretical mechanisms have been proposed whereby spatial structure can promote population persistence, in particular for exploiter–victim systems (host–parasite/pathogen, ...
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  • 3
    Electronic Resource
    Electronic Resource
    Bradford : Emerald
    The @journal of management development 20 (2001), S. 785-794 
    ISSN: 0262-1711
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Economics
    Notes: This paper addresses the effectiveness of the processes involved in business administration proprammes for managers in Iran. It aims to understand the foundation of appropriate business administration for managers and to explore their views and perceptions in relation to the skills and knowledge required of them.The methodology employed consists of survey questionnaire and fieldwork involving semi-structured interviews as the main sources of qualitative and quantitative data. The respondents were current participants in business administration programs at the Payame Noor University. The study tested the validity and relevance of the "integrated model" of managerial skills in order to identify the required categories of skills and knowledge, namely task, people, and self-related skills. The results showed that a combination of these skills enables the managers to work more effectively. However, there seems to be a gap between what is offered and what managers actually need. Also it was discovered that in Iran business managers tend to place more emphasis on the importance of the task and self-development categories of knowledge and skills rather than the people-related ones. These results have numerous implications for the business schools and other universities who deal with managers in Iran.
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  • 4
    Electronic Resource
    Electronic Resource
    Bradford : Emerald
    Anti-corrosion 51 (2004), S. 399-405 
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The inhibition effects of sodium silicate and polyphosphate on corrosion of carbon steel in a potable water supply have been studied using weight loss, electrochemical impedance and Tafel polarization measurements. In the water supply under test there were sufficient calcium ions, (220?ppm), to form the normal polyphosphates salts, which is a requisite for good protection. It was concluded that the inhibition efficiency of polyphosphate was higher than that of silicate. The synergistic inhibition effects of polyphosphate on the inhibition of silicate were studied. The results illustrated that silicates and polyphosphates can be useful as corrosion inhibitors for reducing the corrosion of carbon steel in potable water supply distribution systems. The optimal concentration for silicate alone was determined to be 11?ppm and for polyphosphate alone was 8?ppm. The optimum ratio of concentration for sodium silicate to sodium polyphosphate was 4?:?3.
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Bulletin of engineering geology and the environment 59 (2000), S. 239-246 
    ISSN: 1435-9537
    Keywords: Mots clés Sédiment ; Vase ; Aménagement ; Erosion ; Estuaire de la Loire ; France ; Keywords Sediment ; Mud ; Planning works ; Erosion ; Loire estuary ; France
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Description / Table of Contents: Abstract  The planning works realized in the Loire estuary (France) during the course of the twentieth century have brought about an important inflow of sea water to this site. The consequences can be observed through important changes in the location of the extreme limits of both the dynamic tide and the salinity front at 0.5‰; the dynamic tide has progressed from 63 km from the river mouth in 1903 to 100 km in 1992 and the salinity front from 38 km in 1948 to 70 km in 1991. Modifications of the hydraulic conditions have also affected the dynamics of the cohesive sediments present in the estuary. The purpose of this study is to determine the impact of the past and future planning works in the Loire estuary on the erosion and deposition of cohesive sediments in relation to hydraulic conditions. The principal sedimentary processes (transportation, deposition, settlement, erosion) are simulated by simplified models from measurements carried out both in situ and in the laboratory. The dynamics of the cohesive sediment in the Loire estuary are linked with the fortnightly cycle of the tide as follows: when the tidal coefficient falls below 70, almost all the suspended matter is quickly deposited and collects near the estuary bed to form a lens-shaped body of fluid mud which consolidates during 6 days of neap tides. Finally, as soon as the tide coefficient rises above 75, this body of fluid mud is taken again into suspension and only the fraction that was highly concentrated in the course of the settlement remains on the bottom. The sediments remaining on the estuary bed in the course of a fortnightly cycle of the tide represent the residual sedimentation rate over this period. Knowledge of the maximum tide current velocities in the estuary permits the determination of the maximum hydrodynamic stress on the bottom and the critical concentration of the mud susceptible to being eroded by this current, taking into account the yield stress of the mud. In other respects, the quantity of mud that is greater than this critical concentration per surface unit and time unit can be calculated according to a theoretical model developed by Sanchez and Grovel. This methodology allows the evaluation of the residual sedimentation rate representing a layer of 0.08 m per year in front of the harbour of Montoir for the hydraulic conditions of 1976, with a maximum current velocity on the surface of 2.40 m s–1. Following the dredging works realized between St-Nazaire and Donges after 1976, the level of the bottom has changed from –10.00 to –13.25 m (with respect to the hydrographic datum). These works have brought about a reduction in maximum velocities of 15% and an increase in the residual sedimentation rate of about 100%. This increase is in agreement with the theoretical estimation of this study. This study also describes the high sedimentation rate observed in a locally dredged berth and located in the zone of the estuary where a lens-shaped body of fluid mud is formed during slack tides. The sedimentation rate depends then on the frequency of the dredging works because the dredged zone can be filled up in a few days. Finally, a methodology is developed in order to estimate the erosion rate induced by an increase in current velocities. This methodology takes into account the vertical concentration gradient in the bed resulting from consolidation, the hydrodynamic stress linked to current velocity, the yield stress of sediment which varies with concentration and the critical hydrodynamic stress for erosion estimated from experimental measurements in laboratory. All the methodologies presented in this paper have been applied only to the estuary of the river Loire. Application to any other similar site is possible after laboratory experiments on local sediments in order to adjust the behavioural laws used to evaluate the permeability coefficient, the effective stress and the yield stress. This study shows that knowledge of hydraulic conditions and local sedimentary processes is very important for predicting the impact of planning works in an estuary.
    Notes: Résumé Une conséquence des travaux d'aménagement réalisés dans les estuaires est la modification de l'hydraulique, ce qui affecte la dynamique sédimentaire des vases en créant des zones qui s'engraissent et d'autres qui s'érodent. La modélisation numérique permet de prévoir toute modification hydraulique liée aux travaux d'aménagement avec une assez grande précision. En revanche, du fait de la complexité du problème, les modèles hydrosédimentaires, même les plus performants, donnent des résultats plus qualitatifs que quantitatifs et ne permettent pas de répondre à un certain nombre des questions pratiques que peut se poser un ingénieur. Le but de cet article est d'étudier le lien entre les travaux d'aménagement de l'estuaire de la Loire, l'hydraulique, et les problèmes d'envasement et d'érosion observés dans différents secteurs de l'estuaire. Ceci est possible par l'utilisation de méthodes simples, grâce à la modélisation des principaux processus sédimentaires en jeu (transport, dépôt, tassement, érosion).
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Cluster computing 3 (2000), S. 61-61 
    ISSN: 1573-7543
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Shock waves 10 (2000), S. 151-158 
    ISSN: 1432-2153
    Keywords: Key words: Vertical co-axial diaphragmless shock tube, Rubber diaphragm, Repeatability of shock tube, Toroidal shock wave focusing
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics , Technology
    Notes: Abstract. This paper reports on the characteristics of a compact vertical diaphragmless shock tube, which was constructed and tested in the Shock Wave Research Center to study experimentally the behavior of toroidal shock waves. It is 1.15 m in height and has a self-sustained co-axial vertical structure consisting of a 100 mm i.d. outer tube and an 80 mm o.d. inner tube. To create a ring shaped shock wave between the inner and outer tubes, a rubber sheet is inserted to separate a high pressure driver gas from a test gas, which is bulged with auxiliary high pressure helium from the behind. When the rubber membrane is contracted by the sudden release of the auxiliary gas so as to break the seal, shock waves are formed. Special design features of the shock tube are described and their role in producing repeatable shock waves is discussed. Its special opening characteristics make possible the production of annular shaped shock waves that are unlikely met with a conventional tube that uses rupturing diaphragms. Performance of the shock tube is evaluated in terms of the shock wave Mach numbers and the measured flow properties. It eventually showed a higher degree of repeatability and the scatter in the shock wave Mach numbers Ms was found to be 0.2% for Ms ranging from 1.1 to 1.8. The shock wave Mach number so far measured agreed very well with the simple shock tube theory.
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 32 (2003), S. 177-180 
    ISSN: 1434-6036
    Keywords: PACS. 71.15.Mb Density functional theory, local density approximation, gradient and other corrections
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract: The electronic structure, total density of states DOS and electronic density in ferroelectric tetragonal crystal BaTiO3 are studied using WIEN2k package. This employs the full potential-linearized augmented plan wave FP-LAPW method in the framework of the density functional theory DFT with the generalized gradient approximation (GGA). The results show an indirect band gap of 2.30 eV at the Γ point in the Brillouin zone. The calculated band structure and density of states of BaTiO3 agree with the previous experimental and theoretical results, as do the charge distribution and the prediction of the nature of the chemical bonding.
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  • 9
    ISSN: 1434-1948
    Keywords: Thiacalixarene ; Trimetallic sandwich ; Cobalt ; Zinc ; Divergent receptors ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Reaction between deprotonated p-tert-butyltetrathiacalix[4]arene and CoII or ZnII under strictly defined conditions leads to the formation of sandwich species in which a trimetallic unit is held between two opposed, divergently oriented, staggered O- and S-bound calixarene ligands in the cone conformation. Despite the isomorphous nature of the crystalline compounds, there is a subtle difference in the coordination of CoII and ZnII, presumably related to the differences in metal radius and electron configuration combined with structural restrictions imposed by the calixarene framework, in that whereas all three Co atoms may be considered six-coordinate (and approximately octahedral), only two of the Zn atoms appear so, the third being five-coordinate and more nearly trigonal bipyramidal in its coordination geometry.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Publication Date: 2000-09-15
    Print ISSN: 0163-1829
    Electronic ISSN: 1095-3795
    Topics: Physics
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