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  • 2000-2004  (6)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 138 (2000), S. 176-185 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Partition coefficients (D) for Nb and Ta between rutile and haplogranite melts in the K2O-Al2O3-SiO2 system have been measured as functions of the K2O/Al2O3 ratio, the concentrations of Nb2O5 and Ta2O5, the temperature, in air and at 1 atmosphere pressure. The Ds increase in value as the K* [K2O/(K2O + Al2O3)] molar ratio continuously decreases from highly peralkaline [K* ∼ 0.9] to highly peraluminous [K* ∼ 0.35] melts. The D values increase more dramatically with a unit decrease in K* in peraluminous melts than in peralkaline melts. This compositional dependence of Ds can be explained by the high activity of NbAlO4 species in peraluminous melts and the high activity of KONb species (or low activity of NbAlO4 species) in peralkaline melts. A coupled substitution, Al+3 + Nb+5 (or Ta+5) = 2Ti+4, accounts for the Ds of Nb (Ta) being much greater in peraluminous melts than in peralkaline melts because this substitution allows Nb (Ta) to enter into the rutile structure more easily. The Ds of Ta between rutile and melt are greater than those of Nb at comparable concentrations because the molecular electronic polarizability of Ta is weaker than that of Nb. The Nb+5 with a large polarizing power forms a stronger covalent bond with oxygen than Ta+5 with a small polarizing power. The formation of the strong bond, Nb-O, distorts the rutile structure more severely than the weak bond, Ta-O; therefore, it is easier for Ta to partition into rutile than for Nb. These results imply that the utilization of the Nb/Ta ratio in liquid as a petrogenetic indicator in granitic melts must be done with caution if rutile (or other TiO2-rich phases) is a liquidus phase. The crystallization of rutile will increase the Nb/Ta ratio of the residual liquid because the Ds of Ta between rutile and melts are greater than those of Nb.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2000-02-01
    Print ISSN: 0148-0227
    Electronic ISSN: 2156-2202
    Topics: Geosciences
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  • 3
    Publication Date: 2001-11-01
    Print ISSN: 0148-0227
    Electronic ISSN: 2156-2202
    Topics: Geosciences
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  • 4
    Publication Date: 2000-02-09
    Print ISSN: 0010-7999
    Electronic ISSN: 1432-0967
    Topics: Geosciences
    Published by Springer
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  • 5
    Publication Date: 2019-07-13
    Description: The successful models for the internal evolution of the Moon must consider the volume, distribution, timing, composition and, ultimately, the petrogenesis of mare basaltic volcanism. Indeed, given the paucity of geophysical data, the internal state of the Moon in the past can be gleaned only be unraveling the petrogenesis of the various igneous products on the Moon and, particularly, the mare basalts. most useful in constraining the depth and composition of their source region [Delano, 1980] despite having undergone a certain degree of shallow level olivine crystallization.The bulk of the lunar volcanic glass suite can be modeled as the partial melting products of an olivine + orthopyroxene source region deep within the lunar mantle. Ti02 contents vary from 0.2 wt % -1 7.0wt [Shearer and Papike, 1993]. Values that extreme would seem to require a Ti- bearing phase such as ilmenite in the source of the high-Ti (but not in the VLT source) because a source region of primitive LMO olivine and orthopyroxene, even when melted in small degrees cannot account for the observed range of Ti02 compositions. The picritic glasses are undersaturated with respect to ilmenite at all pressures investigated therefore ilmenite must have been consumed during melting, leaving an ilmenite free residue and an undersaturated melt [Delano, 1980, Longhi, 1992, Elkins et al, 2000 among others]. Multi- saturation pressures for the glasses potentially represent the last depths at which the liquids equilibrated with a harzburgite residue before ascending to the surface. These occur at great depths within the lunar mantle. Because the liquids have suffered some amount of crystal fractionation, this is at best a minimum depth. If the melts are mixtures, then it is only an average depth of melting. Multisaturation, nevertheless, is still a strong constraint on source mineralogy, revealing that the generation of the lunar basalts was dominated by melting of olivine and orthopyroxene.
    Keywords: Geophysics
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  • 6
    Publication Date: 2019-07-13
    Description: An understanding of the petrogenesis of lunar magmas, particularly mare basalts and the parent magmas to the Mg-rich suite, remains an unfulfilled goal. The fact is not surprising given the complexity of the problem. On the Moon, the source region for lunar magmas is not primitive mantle but rather a series of cumulate rocks that vary widely in both minerology and major and minor element contents. The stratigraphy of the cumulate mantle is not likely to be very regular given that the culumate pile is formed initially in an unstable configuration and subsequent thermal and compositional heterogeneities on a number of length scales. These lithologic heterogeneities, the large range of pressures and temperatures over which melts are generated on the Moon, and the close juxtaposition of cumulate rock with widely varying solidii introduce significant complications to the nature of the melting relations that control melt generation. These factors, coupled with the likelihood that polybaric fractional melting of varying efficiencies ultimately control the composition of planetary progress, are ample reasons why the lunar magmas remain the enigma they are. To make progress, phase equilibria studies must be coupled with a detailed understanding of the time scales and the dynamics of crystal and melt reequilibration processes.
    Keywords: Lunar and Planetary Science and Exploration
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