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  • Springer  (47)
  • BioMed Central
  • 2000-2004  (47)
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  • 1
    ISSN: 1572-8935
    Keywords: Functional monomers ; Polymerization ; Copolymerization ; Kinetic studies ; Reactivity ratios
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract 1-Cyanoethanoyl-4-acryloylthiosemicarbazide (CEATS) was synthesized for the first time as a new chelating monomer. Its structure was confirmed by both elemental and spectral analyses. Radical polymerization and copolymerization of CEATS was been carried out in dimethylformamide (DMF) in the presence of azobisisobutyronitrile (AIBN) as an initiator. Kinetic studies for the polymerization behavior of CEATS were performed. The complex formation of the CEATS monomer and polymer (PCEATS) with Cu II cation was investigated and its stability constant determined. The rate of copolymerization of CEATS with some conventional monomers, namely vinyl acetate, methyl methacrylate and acrylonitrile, was measured as a function of the mole fraction of the monomers. The reactivity ratios (r1, r2) for the various copolymer systems investigated together with the Q and e values of the CEATS monomer were determined. Moreover, the thermal gravimetric analysis of the prepared polymers and their copolymers with acrylonitrile were also studied.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Monatshefte für Chemie 131 (2000), S. 1031-1038 
    ISSN: 1434-4475
    Keywords: Keywords. Potentiometry; Glycine; Cephalosporins; Complexes.
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary.  The interaction of Ca(II), Cu(II), Zn(II), Pb(II), and La(III) ions with the antibiotics cephalexin, cefadroxil, cephaloridine, and cefoperazone as secondary ligands was investigated potentiometrically. The formation constants were determined for a ligand-to-metal ratio of 1:1 at 25°C and KNO3. The protonation constants of the complexes were evaluated for the system . The order of stability of the binary and ternary complexes were examined. It was found that glycine adds preferably [M(II)-cephalosporin] rather than to the aqueous complexes of M(II). In all cases 1:1:1 complexes were formed.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 23 (2001), S. 191-199 
    ISSN: 1434-6036
    Keywords: PACS. 71.20.-b Electron density of states and band structure of crystalline solids – 71.20.Eh Rare earth metals and alloys
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract: The electronic properties of rare-earth arsenides have been calculated from first principles. In the calculations we have treated the rare-earth f electrons both as core-like and as valence-like electrons. We consider the changes in the energy bands and in the density of states near the Fermi level which are found to be relevant, except for the case of LuAs, and discuss this in relation with the role played from the rare-earth 5d derived states. Moreover we show that the rare-earth 5d related bands are particularly sensitive to the variation of the lattice constant; change in the lattice constant of less than 1% leads to a different behaviour with respect to the crossing of the rare-earth 5d derived bands and the As 4p derived bands along the Δ-direction. This point is discussed in connection with the possibility of having a semimetal-semiconductor transition in the rare-earth arsenides.
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  • 4
    ISSN: 1434-4475
    Keywords: Keywords. Sea water; Brine; Crystallization sequence; Simulation.
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung.  Die Kristallisationsabfolge beim Abdampfen von Salzsolen wurde bei 25°C aufder Basis der entsprechenden Phasendiagramme computerunterstützt berechnet. Dabei wurden sowohl die auskristallisierenden festen Phasen bestimmt als auch deren Massenbilanzen ermittelt. Um quantitative Information über das Abdampfverhalten von Salzsolen zu erhalten, wurden diesen Berechnungen zwei Grenzannahmen zugrunde gelegt: i) das Fest-flüssig-Gleichgewicht stellt sich laufend ein, sodaß sich feste Phasen während des Verdampfungsprozesses teilweise oder vollständig wieder auflösen können, bzw. ii) die festen Phasen sedimentieren und trennen sich von der flüssigen Phase, sodaß keine Wiederauflösung möglich ist. Tages- bzw. jahreszeitliche Temperaturschwankungen sowie metastabile Gleichgewichte wurden nicht berücksichtigt.
    Notes: Summary.  A computer assisted calculation of the crystallization sequence of a brine is performed on the basis of the respective phase diagrams at 25°C. The nature of the solids and the mass balance are determined. The calculation gives immediate quantitative information of the brine behavior during evaporation. The calculation is performed assuming that i) the solids are always in equilibrium with the liquid, i.e. that some solid phases can be partially or completely redissolved during evaporation, or ii) the solids are separated from liquid by sedimentation and no redissolution is possible. The seasonal or day-night fluctuations of temperature and metastable equilibria have not been taken into account.
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  • 5
    ISSN: 1432-1211
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Communications in mathematical physics 208 (2000), S. 761-770 
    ISSN: 1432-0916
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Physics
    Notes: Abstract: Let $M$ be a compact immersed submanifold of the Euclidean space, the hyperbolic space or the standard sphere. For any continuous potential q on M, we give a sharp upper bound for the second eigenvalue of the operator −Δ+q in terms of the total mean curvature of M and the mean value of q. Moreover, we analyze the case where this bound is achieved. As a consequence of this result we obtain an alternative proof for the Alikakos–Fusco conjecture concerning the stability of the interface in the Allen–Cahn reaction diffusion model.
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 63 (2000), S. 525-532 
    ISSN: 1572-8943
    Keywords: bitumen ; portland cement ; safety considerations ; solidification ; thermal stability
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The thermal stability of solidified NaNO3 salts in bitumen and cement has been investigated for safety considerations in the field of solidification of radioactive waste. The thermal decomposition of bitumen and cement in presence of NaNO3 in a temperature range 22–650°C has been studied. The fraction decomposed of the pure samples and mixtures showed slow linear reactions followed by acceleratory and decay stages. Data are analyzed according to both Freeman-Carroll and Coats-Redfern kinetics to evaluate the activation energy and the order of reactions of all mixtures. It is found that the activation energies of bitumen and cement were 594 and 203 kJ mol-1, respectively. The order of reactions of bitumen and cement was 2 and 4, respectively. The addition of NaNO3 shortens the duration of the induction period in all mixtures. It was concluded that solidification of radioactive waste containing NaNO3 in bitumen and cement should be applied in the temperature range 22–300°C. At temperature higher than300°C solidification should be in cement.
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  • 8
    ISSN: 1573-1472
    Keywords: Coherent structures ; Numerical modelling ; Turbulence
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract In two preceding papers, coherent structures of theatmospheric boundary layer (ABL), such as rollvortices or cells, were investigated through radar andaircraft observations collected during the TRAC-93(Turbulence Radar Aircraft Cells) experiment held inFrance in June 1993. The analysis of this experimentaldata set provided information on the spatialcharacteristics of these organisations (length scale,orientation, type ... ), their temporal and verticalevolution, and their relation with the dynamic andthermodynamic conditions of the ABL. For the thirdpaper in this series, a large eddy simulation model is used to examine the impact of thecoherent structures on the ABL vertical fluxes. Theanalysis of the simulated horizontal fields is madewith two-dimensional auto and cross-correlationsapplied on different pertinent ABL variables. Theresults emphasise a directional anisotropy of theseorganised fields throughout the ABL, much morepronounced in the heat flux fields, not only at thelength scale of organisations but also at theturbulence scales. This finding has an importantconsequence for traditional ABL flux measurementsbased on the hypothesis of isotropic and homogeneousturbulence. It can explain part of the underestimationof the surface fluxes often mentioned in theliterature. This approach makes it possible tomodify the concept of diffusion time (in chemicalmodelling) and could also lead to revised ABLparameterisations in Range Scale models.
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Journal of intelligent information systems 14 (2000), S. 131-154 
    ISSN: 1573-7675
    Keywords: content-based access of images ; image representation ; intelligent information retrieval ; knowledge representation ; image databases ; query containment ; description logics ; intentional reasoning
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science
    Notes: Abstract The problem of content management of multimedia data types (e.g., image, video, graphics) is becoming increasingly important with the development of advanced multimedia applications. Traditional database management systems are inadequate for the handling of such data types. They require new techniques for query formulation, retrieval, evaluation, and navigation. In this paper we develop a knowledge-based framework for modeling and retrieving image data by content. To represent the various aspects of an image object's characteristics, we propose a model which consists of three layers: (1) Feature & Content Layer, intended to contain image visual features such as contours, shapes, etc.; (2) Object Layer, which provides the (conceptual) content dimension of images; and (3) Schema Layer, which contains the structured abstractions of images, i.e., a general schema about the classes of objects represented in the object layer. We propose two abstract languages on the basis of description logics: one for describing knowledge of the object and schema layers, and the other, more expressive, for making queries. Queries can refer to the form dimension (i.e., information of the Feature & Content Layer) or to the content dimension (i.e., information of the Object Layer). These languages employ a variable free notation. As the amount of information contained in the previous layers may be huge and operations performed at the Feature & Content Layer are time-consuming, resorting to the use of materialized views to process and optimize queries may be extremely useful. For that, we propose a formal framework for testing containment of a query in a view expressed in our query language.
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  • 10
    ISSN: 1573-9686
    Keywords: Oxidation reduction ; Methylene blue ; Toluidine blue O ; Ubiquinone ; Mathematical modeling ; Multiple indicator dilution ; Lung cell culture ; Physiome ; Hyperoxia
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Technology
    Notes: Abstract The pulmonary endothelium is a chemical reactor that modifies blood composition in several ways, including reduction of the oxidized forms of certain redox active substances in the blood. The physiological functions of the transplasma membrane electron transport systems involved in the latter are not fully understood, but an argument is made that they are involved in antioxidant defense. In addition, the experimental approaches used to characterize the process, including studies at whole organ, cell culture, and subcellular levels, along with the use of mathematical modeling, may be representative of the physiome concept wherein a goal is the integration of information obtained at all levels of biological organization. In this article, separation of intra- and extracellular events involved in the disposition of redox active probes within the lungs is the particular example. © 2000 Biomedical Engineering Society. PAC00: 8716Uv, 8716Dg, 8715Rn, 8719Uv
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