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  • Springer Nature  (74)
  • Oxford University Press  (35)
  • American Institute of Physics (AIP)  (33)
  • American Chemical Society (ACS)
  • 2000-2004  (73)
  • 1985-1989  (43)
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  • 1
    Publikationsdatum: 1988-01-01
    Print ISSN: 1367-4803
    Digitale ISSN: 1460-2059
    Thema: Biologie , Informatik , Medizin
    Publiziert von Oxford University Press
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 89 (1988), S. 3057-3062 
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: A nonperturbative theory of predissociation based upon an effective Hamiltonian is presented. For a model diatomic system in which a (bound-state) Morse potential-energy curve is crossed by an (unbound-state) exponential potential-energy curve, the exact effective Hamiltonian may be obtained in high precision for any well behaved interaction potential. The real and imaginary parts of the eigenvalues of the effective Hamiltonian give the (shifted) energies and widths, respectively, of the predissociative states. Numerical results are obtained and compared with both a semiclassical approximation and those derived from solutions of coupled Schrödinger equations. In the weak-coupling regime the agreement between the present method and semiclassical results is good, and better in general than the coupled-equations results, which apparently suffer from instability problems. For couplings of intermediate strength, the semiclassical method breaks down, as do fully quantum-mechanical first-order perturbation approximations, as is demonstrated by comparison with the converged nonperturbative results. Fixed points of the spectrum appear at "resonance'' values of the coupling strength which bring the exact energy eigenvalue into resonance with one of the adiabatic levels so that the imaginary part (level width) of the former vanishes. Thus beyond a critical coupling strength, stronger coupling enhances the stability of a resonance.
    Materialart: Digitale Medien
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  • 3
    Digitale Medien
    Digitale Medien
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 90 (1989), S. 5102-5107 
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: Electrochemical techniques are applied to a study of selected intrinsic physical properties (independent of dopant) of polyacetylene, (CH)x. Electrochemical voltage spectroscopy (EVS) is used to characterize the energies of charge injection and removal for both cis-(CH)x and trans-(CH)x. The difference in charge injection and ejection potentials is shown to give a direct measure of the approximate semiconductor band gap and the results are compared with similar data from optical measurements. Charge injection and ejection potentials are used to define the redox potentials of (CH)x and are used in conjunction with equilibrium potential measurements at varying oxidation or reduction levels of polyacetylene to present a unifying concept to the electrochemistry of (CH)x.
    Materialart: Digitale Medien
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  • 4
    Digitale Medien
    Digitale Medien
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 88 (1988), S. 5984-5985 
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: The nature of the metastable state of hydrogen trimers described by Ga and Kuppermann (ref.1) is further discussed. The analysis is based on linewidth measurements in the emission spectrum of the trimer, the quantum mechanical selection rules, and earlier beam and photoionization measurements.(AIP)
    Materialart: Digitale Medien
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  • 5
    Digitale Medien
    Digitale Medien
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 88 (1988), S. 4949-4956 
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: The nuclear displacement operator (NDO) for Born–Oppenheimer electronic wave functions (BOEWF) is introduced and some recurrence formulas are obtained. The formulas for Born couplings and higher derivatives of BOEWF with respect to nuclear coordinates are derived from very general considerations and relations among these quantities are given. The series form, exponential, and integral forms of the NDO are exhibited. Particularly, it is proven that for the two-state systems the NDO has a very simple form by which it is convenient to study two-state dynamical processes. It is shown that the NDO satisfies a differential equation which is analogous to that for the time-evolution operator in the presence of a time-dependent perturbation. The physical meanings of these two operators are compared. It is demonstrated that the NDO is uniquely determined by the vector Born coupling matrix, and that the nuclear motion may be analyzed in terms of a local non-Abelian gauge transformation.
    Materialart: Digitale Medien
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  • 6
    ISSN: 1089-7674
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The Z-pinch-driven hohlraum (ZPDH) [J. H. Hammer et al., Phys. Plasmas 6, 2129 (1999)] is a promising approach to high yield inertial confinement fusion currently being characterized in experiments on the Sandia Z accelerator [M. E. Cuneo et al., Phys. Plasmas 8, 2257 (2001)]. Simulations show that capsule radiation symmetry, a critical issue in ZPDH design, is governed primarily by hohlraum geometry, dual-pinch power balance, and pinch timing. In initial symmetry studies on Z without the benefit of a laser backlighter, highly-asymmetric pole-hot and equator-hot single Z-pinch hohlraum geometries were diagnosed using solid low density foam burnthrough spheres. These experiments demonstrated effective geometric control and prediction of polar flux symmetry at the level where details of the Z-pinch implosion and other higher order effects are not critical. Radiation flux symmetry achieved in Z double-pinch hohlraum configurations exceeds the measurement sensitivity of this self-backlit foam ball symmetry diagnostic. To diagnose radiation symmetry at the 2%–5% level attainable with present ZPDH designs, high-energy x rays produced by the recently-completed Z-Beamlet laser backlighter are being used for point-projection imaging of thin-wall implosion and symmetry capsules. © 2002 American Institute of Physics.
    Materialart: Digitale Medien
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  • 7
    ISSN: 1089-7674
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Detailed measurements in two dimensions by probes and Thomson scattering reveal unexpected local electric potential and electron pressure (pe) maxima near the divertor X point in L-mode plasmas in the DIII-D tokamak [J. L. Luxon and L. G. Davis, Fusion Technol. 8, 441 (1985)]. The potential drives E×B circulation about the X point, thereby exchanging plasma between closed and open magnetic surfaces at rates that can be comparable to the total cross-separatrix transport. The potential is consistent with the classical parallel Ohm's law. A simple model is proposed to explain the pressure and potential hills in low power, nearly detached plasmas. Recent two-dimensional edge transport modeling with plasma drifts also shows X-point pressure and potential hills but by a different mechanism. These experimental and theoretical results demonstrate that low power tokamak plasmas can be far from poloidal uniformity in a boundary layer just inside the separatrix. Additional data, although preliminary and incomplete, suggest that E×B circulation across the separatrix might be a common feature of low confinement behavior. © 2001 American Institute of Physics.
    Materialart: Digitale Medien
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  • 8
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Physics of Plasmas 7 (2000), S. 3663-3680 
    ISSN: 1089-7674
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The results of detailed comparisons between experimental measurements of the scrape-off layer and divertor plasmas and simulations using the UEDGE code for a DIII-D discharge [J. Luxon et al., Proceedings of the 11th International Conference on Plasma Physics and Controlled Nuclear Fusion (International Atomic Energy Agency, Vienna, 1986), Vol. I, p. 159] are reported. The simulations focus on understanding the flow of both fuel and impurity particles throughout the edge and scrape-off layer (SOL) plasma. The core impurity content and the core hydrogen ionization rate can be explained by sputtering and recycling in the divertor region alone. The model reproduces most of the detailed experimental measurements. The simulations include the effect of intrinsic impurities, assumed to be carbon originating from sputtering of the plasma facing surfaces. The simulations accurately reproduce the total radiated power, although the spatial profile of radiation is somewhat narrower in the simulation. The measured carbon density on closed field lines is reproduced well with the simulation. Comparison of carbon emission lines indicates the total carbon sputtering yield is a factor of 2 to 4 less than expected, although the total radiated power and core carbon content are insensitive to the sputtering yield. The agreement between simulation and experiment permits more meaningful interpretation of the experimental measurements. © 2000 American Institute of Physics.
    Materialart: Digitale Medien
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  • 9
    ISSN: 1089-7674
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Intermittent plasma objects (IPOs) featuring higher pressure than the surrounding plasma, and responsible for ∼50% of the E×BT radial transport, are observed in the scrape off layer (SOL) and edge of the DIII-D tokamak [J. Watkins et al., Rev. Sci. Instrum. 63, 4728 (1992)]. Conditional averaging reveals that the IPOs, produced at a rate of ∼3×103 s−1, are positively charged and also polarized, featuring poloidal electric fields of up to 4000 V/m. The IPOs move poloidally at speeds of up to 5000 m/s and radially with E×BT/B2 velocities of ∼2600 m/s near the last closed flux surface (LCFS), and ∼330 m/s near the wall. The IPOs slow down as they shrink in radial size from 4 cm at the LCFS to 0.5 cm near the wall. The IPOs appear in the SOL of both L and H mode discharges and are responsible for nearly 50% of the SOL radial E×B transport at all radii; however, they are highly reduced in absolute amplitude in H-mode conditions. © 2001 American Institute of Physics.
    Materialart: Digitale Medien
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  • 10
    Digitale Medien
    Digitale Medien
    Woodbury, NY : American Institute of Physics (AIP)
    Chaos 10 (2000), S. 366-370 
    ISSN: 1089-7682
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The spherical quantum billiard with a time-varying radius, a(t), is considered. It is proved that only superposition states with components of common rotational symmetry give rise to chaos. Examples of both nonchaotic and chaotic states are described. In both cases, a Hamiltonian is derived in which a and P are canonical coordinate and momentum, respectively. For the chaotic case, working in Bloch variables (x,y,z), equations describing the motion are derived. A potential function is introduced which gives bounded motion of a(t). Poincaré maps of (a,P) at x=0 and the Bloch sphere projected onto the (x,y) plane at P=0 both reveal chaotic characteristics. © 2000 American Institute of Physics.
    Materialart: Digitale Medien
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