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1

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A 13C tracer study to identify the origin of dissolved organic carbon in forested mineral soils (2004)

Hagedorn, F. ; Saurer, M. ; Blaser, P.

Oxford, UK : Blackwell Science Ltd

European journal of soil science 55 (2004), S. 0

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ISSN: 1365-2389

Source: Blackwell Publishing Journal Backfiles 1879-2005

Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition

Notes: The relative contributions of sources of carbon in soils, such as throughfall, litter, roots, microbial decay products and stable organic fractions, to dissolved organic C are controversial. To identify the origin of dissolved organic C, we made use of a 4-year experiment where spruce and beech, growing on an acidic loam and on a calcareous sand, were exposed to increased CO2 that was depleted in 13C. We traced the new C inputs from trees into dissolved organic C, into water-extractable organic C, and into several particle-size fractions. In addition, we incubated the labelled soils for 1 year and measured the production of dissolved organic C and CO2 from new and old soil C. In the soil solutions of the topsoil, the dissolved organic C contained only 5–10% new C from the trees. The δ13C values of dissolved organic C resembled those of C pools smaller than 50 µm, which strongly suggests that the major source of dissolved organic C was humified old C. Apparently, throughfall, fresh litter and roots made only minor contributions to dissolved organic C. Water-extractable organic C contained significantly larger fractions of new C than did the natural dissolved organic C (25–30%). The δ13C values of the water-extractable organic C were closely correlated with those of sand fractions, which consisted of little decomposed organic carbon. The different origin of dissolved and water-extractable organic C was also reflected in a significantly larger molar UV absorptivity and a smaller natural 13C abundance of dissolved organic C. This implies that the sampling method strongly influences the characteristics and sources of dissolved organic C. Incubation of soils showed that new soil C was preferentially respired as CO2 and only a small fraction of new C was leached as dissolved organic C. Our results suggest that dissolved organic C is produced during incomplete decomposition of recalcitrant native C in the soils, whereas easily degradable new components are rapidly consumed by microbes and thus make only a minor contribution to the dissolved C fraction.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1046/j.1365-2389.2003.00578.x

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Sorption and transport of metals in preferential flow paths and soil matrix after the addition of wood ash (2001)

Bundt, M. ; Zimmermann, S. ; Blaser, P. ; [et al.]

Oxford, UK : Blackwell Science Ltd

European journal of soil science 52 (2001), S. 0

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ISSN: 1365-2389

Source: Blackwell Publishing Journal Backfiles 1879-2005

Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition

Notes: As a consequence of heterogeneous transport in soils, only a small part of the soil might be responsible for sorbing incoming elements. After staining preferential flow paths in forested Dystric Cambisol with a colour dye, we sampled soil material from the flow paths and from the soil matrix. We measured chemical properties and sorption isotherms of these two flow regions and estimated the significance of preferential flow paths for the transport of solutes leached from wood ash applied at the surface. In the A horizon (0–9 cm depth), the cation exchange capacity of the flow paths was 83.8 mmolc kg−1, while that of the soil matrix was only 74.6 mmolc kg−1. The base saturation was 42% and soil organic matter content was 41% larger in flow paths than in the soil matrix. The sorption capacity for Cu was also larger than in the matrix, whereas the sorption capacity for Sr was similar in both flow regions. The impact of the addition of 8 t wood ash ha−1 on soil chemical properties was restricted mainly to the flow paths in the uppermost 20 cm of the soil; it was negligible in the matrix and at greater depths. Concentrations of exchangeable Ca in the flow paths increased nearly 10-fold during the 6 months following the addition of the wood ash, and those of organically bound Pb by 50%. The opposite effect was found for exchangeable Al. Our results show that only part of the whole soil volume, approximately 50% of 0–20 cm in our study, is involved in transporting and sorbing the elements applied with the wood ash or as tracers. Such differences must be considered when calculating the maximal impact of any addition of fertilizer, wood ash, or liming agent.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1046/j.1365-2389.2001.00405.x

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3

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Carbon sequestration in forest soils: effects of soil type, atmospheric CO2 enrichment, and N deposition (2001)

Hagedorn, F. ; Maurer, S. ; Egli, P. ; [et al.]

Oxford, UK : Blackwell Science Ltd

European journal of soil science 52 (2001), S. 0

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ISSN: 1365-2389

Source: Blackwell Publishing Journal Backfiles 1879-2005

Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition

Notes: Soil contains the major part of carbon in terrestrial ecosystems, but the response of this carbon to enriching the atmosphere in CO2 and to increased N deposition is not completely understood. We studied the effects of CO2 concentrations at 370 and 570 μmol CO2 mol−1 air and increased N deposition (7 against 0.7 g N m−2 year−1) on the dynamics of soil organic C in two types of forest soil in model ecosystems with spruce and beech established in large open-top chambers containing an acidic loam and a calcareous sand. The added CO2 was depleted in 13C and thus the net input of new C into soil organic carbon and the mineralization of native C could be quantified.Soil type was the greatest determining factor in carbon dynamics. After 4 years, the net input of new C in the acidic loam (670 ± 30 g C m−2) exceeded that in the calcareous sand (340 ± 40 g C m−2) although the soil produced less biomass. The mineralization of native organic C accounted for 700 ± 90 g C m−2 in the acidic loam and for 2800 ± 170 g C m−2 in the calcareous sand. Unfavourable conditions for mineralization and a greater physico-chemical protection of C by clay and oxides in the acidic loam are probably the main reasons for these differences. The organic C content of the acidic loam was 230 g C m−2 more under the large than under the small N treatment. As suggested by a negligible impact of N inputs on the fraction of new C in the acidic loam, this increase resulted mainly from a suppressed mineralization of native C. In the calcareous sand, N deposition did not influence C concentrations. The impacts of CO2 enrichment on C concentrations were small. In the uppermost 10 cm of the acidic loam, larger CO2 concentrations increased C contents by 50–170 g C m−2. Below 10 cm depth in the acidic loam and at all soil depths in the calcareous sand, CO2 concentrations had no significant impact on soil C concentrations. Up to 40% of the ‘new’ carbon of the acidic loam was found in the coarse sand fraction, which accounted for only 7% of the total soil volume. This suggests that a large part of the CO2-derived ‘new’ C was incorporated into the labile and easily mineralizable pool in the soil.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1046/j.1365-2389.2001.00412.x

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Palaeogroundwater of glacial origin in the Cambrian-Vendian aquifer of northern Estonia (2001)

Vaikmae, R. ; Vallner, L. ; Loosli, H. H. ; [et al.]

In: Geological Society Special Publication 189: 17-27.

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Publication Date: 2001-01-01

Description: A strongly depleted stable isotope composition, absence of 3H and a low radiocarbon concentration are the main indicators of glacial origin of groundwater in the Cambrian-Vendian aquifer in northern Estonia. It is concluded from noble gas analyses that palaeorecharge occurred at temperatures c. 0{degrees}C. In some wells unexpectedly high gas concentrations have been found. Excess air, up to c. 50 %, is common but two-five times oversaturation is very unusual, requiring special processes and explanations, e.g. oversaturation may indicate recharge under highpressure conditions, perhaps by subglacial meltwater recharge through the aquifers. Analyses of the gas composition in some groundwater samples also showed a rather high concentration of CH4, indicating the influence of biogenic reactions in the subsurface that could cause the rather negative {delta}13C values. Results of {delta}13C analyses in two CH4 samples also show that the CH4 is most likely of a biogenic origin. Based on the isotope data, the results of noble gas analyses, and considering the palaeoclimatic and palaeoenvironmental situation in Estonia during the late Weichselian time, it is concluded that palaeorecharge of Cambrian-Vendian aquifer most probably occurred during the last glaciation, probably by subglacial drainage through the tunnel valleys.

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Isotopic methods and their hydrogeochemical context in the investigation of palaeowaters (2001)

Loosli, H. H. ; Aeschbach-Hertig, W. ; Barbecot, F. ; [et al.]

In: Geological Society Special Publication 189: 193-212.

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Publication Date: 2001-01-01

Description: Isotope and geochemical techniques are the primary way in which the residence time, recharge conditions and subsequent evolution of palaeowaters can be determined. Isotopic species and noble gas concentrations are used as residence time and palaeoclimate indicators. Among the former, 14C is pre-eminent in late Quaternary studies because of an age range which covers the Pleistocene-Holocene transition. However, its use is constrained by frequent difficulties in determining the dilution of dissolved 14C due to water-rock interaction. A combination of 14C data with 226Ra and 4He results may be useful for Holocene waters but they can also be used to validate the carbon systematics assumed for 14C dating. For waters beyond the range of 14C dating, 81Kr, 36Cl, 4He and chemical tracers can be applied. Stable isotope ratios and noble gas concentrations primarily reflect climatic conditions at the time of recharge. While the noble gases provide absolute values for recharge temperatures, stable isotopes are only relative indicators that vary regionally. The PALAEAUX programme has examined these aspects in some detail by looking at the {delta}18O shift between Pleistocene and Holocene waters on the European scale, and by calculating {delta}18O/{Delta}T ratios from {delta}18O v. recharge temperature plots for aquifers at different distances from the Atlantic Ocean. Indications are that the more positive {delta}18O value of ocean water during the Pleistocene dominates in the more westerly European countries over the negative {delta}18O shift during cooler conditions. There are also indications that air-mass circulation during the Pleistocene was similar to the present day. The evolution of a palaeowater can best be studied by measuring chemical tracers; this is possible in freshwater aquifers, where a clear trend of geochemical reactions is observed, and in freshening marine aquifers. Chemical and isotopic tracers can also be used to study the movement of the front between palaeowater and younger components that must be identified in coastal aquifers to guarantee a sustainable water use.

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