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  • Copernicus  (19)
  • American Chemical Society (ACS)  (3)
  • 2010-2014  (22)
  • 1
    Publication Date: 2013-01-04
    Description: Environmental Science & Technology DOI: 10.1021/es302959h
    Print ISSN: 0013-936X
    Electronic ISSN: 1520-5851
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering
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  • 2
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    American Chemical Society (ACS)
    Publication Date: 2013-08-18
    Description: Chemical Reviews DOI: 10.1021/cr400071f
    Print ISSN: 0009-2665
    Electronic ISSN: 1520-6890
    Topics: Chemistry and Pharmacology
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  • 3
    Publication Date: 2014-02-13
    Description: Analytical Chemistry DOI: 10.1021/ac403966h
    Print ISSN: 0003-2700
    Electronic ISSN: 1520-6882
    Topics: Chemistry and Pharmacology
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  • 4
    Publication Date: 2013-07-01
    Description: This study analyzes the added value of a regional climate model hindcast with respect to snow water equivalent (SWE) for Siberia when compared to SWE estimates from forcing NCEP-R. In addition, we examine the discrepancies of simulated SWE to several recent reanalysis products (NCEP-R2 NCEP-CFSR, ERA-Interim). We apply the regional climate model COSMO-CLM (CCLM) to a 50 km grid spacing using NCEP-R1 as driving force to obtain a 63 yr (1948 to 2010) gridded dataset of historical SWE. Simulated regional climate data is necessary because of the absence of station data in that region. To perform large-scale assessments we use the satellite-derived daily SWE product of ESA DUE GlobSnow from 1987 to 2010. Russian station SWE data is used for cross-checking the findings. In January (mid-winter), the SWE hindcast is in good agreement with GlobSnow, whereas it overestimates SWE during the melting season. CCLM shows a clear added value in providing realistic SWE information compared to the driving reanalysis. The temporal consistency of CCLM is higher than that presented by ERA-Interim and NCEP-R2.
    Print ISSN: 1994-0416
    Electronic ISSN: 1994-0424
    Topics: Geography , Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 5
    Publication Date: 2013-06-27
    Description: The aim of this study is to derive a realistic estimation of the Surface Mass Balance (SMB) of the Greenland ice sheet (GrIS) through statistical downscaling of Global Coupled Model (GCM) outputs. To this end, climate simulations performed with the CNRM-CM5.1 Atmosphere-Ocean GCM within the CMIP5 (Coupled Model Intercomparison Project phase 5) framework are used for the period 1850–2300. From the year 2006, two different emission scenarios are considered (RCP4.5 and RCP8.5). Simulations of SMB performed with the detailed snowpack model Crocus driven by CNRM-CM5.1 surface atmospheric forcings serve as a reference. On the basis of these simulations, statistical relationships between total precipitation, snow-ratio, snowmelt, sublimation and near-surface air temperature are established. This leads to the formulation of SMB variation as a function of temperature variation. Based on this function, a downscaling technique is proposed in order to refine 150 km horizontal resolution SMB output from CNRM-CM5.1 to a 15 km resolution grid. This leads to a much better estimation of SMB along the GrIS margins, where steep topography gradients are not correctly represented at low-resolution. For the recent past (1989–2008), the integrated SMB over the GrIS is respectively 309 and 243 Gt yr–1 for raw and downscaled CNRM-CM5.1. In comparison, the Crocus snowpack model forced with ERA-Interim yields a value of 245 Gt yr–1. The major part of the remaining discrepancy between Crocus and downscaled CNRM-CM5.1 SMB is due to the different snow albedo representation. The difference between the raw and the downscaled SMB tends to increase with near-surface air temperature via an increase in snowmelt.
    Print ISSN: 1994-0432
    Electronic ISSN: 1994-0440
    Topics: Geography , Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 6
    Publication Date: 2012-11-07
    Description: This study analyzes the added value of a regional climate model hindcast of CCLM compared to global reanalyses in providing a reconstruction of recent past snow water equivalent (SWE) for Siberia. Consistent regional climate data in time and space is necessary due to lack of station data in that region. We focus on SWE since it represents an important snow cover parameter in a region where snow has the potential to feed back to the climate of the whole Northern Hemisphere. The simulation was performed in a 50 km grid spacing for the period 1948 to 2010 using NCEP Reanalysis 1 as boundary forcing. Daily observational reference data for the period of 1987–2010 was obtained by the satellite derived SWE product of ESA DUE GlobSnow that enables a large scale assessment. The analyses includes comparisons of the distribution of snow cover extent, example time series of monthly SWE for January and April, regional characteristics of long-term monthly mean, standard deviation and temporal correlation averaged over subregions. SWE of CCLM is compared against the SWE information of NCEP-R1 itself and three more reanalyses (NCEP-R2, NCEP-CFSR, ERA-Interim). We demonstrate a significant added value of the CCLM hindcast during snow accumulation period shown for January for many subregions compared to SWE of NCEP-R1. NCEP-R1 mostly underestimates SWE during whole snow season. CCLM overestimates SWE compared to the satellite-derived product during April – a month representing the beginning of snow melt in southern regions. We illustrate that SWE of the regional hindcast is more consistent in time than ERA-Interim and NCEP-R2 and thus add realistic detail.
    Print ISSN: 1994-0432
    Electronic ISSN: 1994-0440
    Topics: Geography , Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 7
    Publication Date: 2010-03-22
    Description: Storfjorden (Svalbard) is a sill-fjord with an active polynya and exemplifies the dense water formation process over the Arctic shelves. Here we report on our simulations of Storfjorden covering the freezing season of 1999–2000 using an eddy-permitting 3-D ocean circulation model with a fully coupled dynamic and thermodynamic sea-ice model. The model results in the polynya region and of the dense water plume flowing over the sill crest are compared to observations. The connections of the overflow at the sill to the dense water production at the polynya and to the local wind forcing are investigated. Both the overflow and the polynya dynamics are found to be sensitive to wind forcing. In response to freezing and brine rejection over the polynya, the buoyancy forcing initiates an abrupt positive density anomaly. While the ocean integrates the buoyancy forcing over several polynya events (about 25 days), the wind forcing dominates the overflow response at the sill at weather scale. In the model, the density excess is diluted in the basin and leads to a gradual build-up of dense water behind the sill. The overflow transport is typically inferred from observations using a single current profiler at the sill crest. Despite the significant variability of the plume width, we show that a constant overflow width of 15 km produces realistic estimates of the overflow volume transport. Another difficulty in monitoring the overflow is measuring the plume thickness in the absence of hydrographic profiles. Volume flux estimates assuming a constant plume width and the thickness inferred from velocity profiles explain 58% of the modelled overflow volume flux variance and agrees to within 10% when averaged over the overflow season.
    Print ISSN: 1812-0784
    Electronic ISSN: 1812-0792
    Topics: Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 8
    Publication Date: 2010-01-05
    Description: The formation of deep and intermediate waters in the Arctic Ocean is primarily due to high salinity shelf waters sinking down the continental slopes. Storfjorden (Svalbard) is a sill-fjord with an active polynya and exemplifies the dense water formation process over the Arctic shelves. Here we report on our simulations of Storfjorden covering the freezing season of 1999–2000 using an eddy-permitting 3-D ocean circulation model with a fully coupled dynamic and thermodynamic sea-ice model. The model results in the polynya region and of the dense water plume flowing over the sill crest are compared to observations. The connections of the overflow at the sill to the dense water production at the polynya and to the local wind forcing are investigated. Both the overflow and the polynya dynamics are found to be sensitive to wind forcing. In response to freezing and brine rejection over the polynya, the buoyancy forcing initiates an abrupt positive density anomaly. While the ocean integrates the buoyancy forcing over several polynya events (about 25 days), the wind forcing dominates the overflow response at the sill at weather scale. In the model, the density excess is diluted in the basin and leads to a gradual build-up of dense water behind the sill. The overflow transport is typically inferred from observations using a single current profiler at the sill crest. Despite the significant variability of the plume width, we show that a constant overflow width of 15 km produces realistic estimates of the overflow volume transport. Another difficulty in monitoring the overflow is measuring the plume thickness in the absence of hydrographic profiles. Volume flux estimates assuming a constant plume width and the thickness inferred from velocity profiles explain 58% of the modelled overflow volume flux variance and agrees to within 10% when averaged over the overflow season.
    Print ISSN: 1812-0806
    Electronic ISSN: 1812-0822
    Topics: Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 9
    Publication Date: 2013-12-03
    Description: Due to their heterogeneous nature, karst aquifers pose a major challenge for hydrogeological investigations. Important procedures like the delineation of catchment areas for springs are hindered by the unknown locations and hydraulic properties of highly conductive karstic zones. In this work numerical modeling was employed as a tool in delineating catchment areas of several springs within a karst area in southwestern Germany. For this purpose, different distributive modeling approaches were implemented in the finite element simulation software Comsol Multiphysics®. The investigation focuses on the question to which degree the effect of karstification has to be taken into account for accurately simulating the hydraulic head distribution and the observed spring discharges. The results reveal that the representation of heterogeneities has a large influence on the delineation of the catchment areas. Not only the location of highly conductive elements but also their geometries play a major role for the resulting hydraulic head distribution and thus for catchment area delineation. The size distribution of the karst conduits derived from the numerical models agrees with knowledge from karst genesis. It was thus shown that numerical modeling is a useful tool for catchment delineation in karst aquifers based on results from different field observations.
    Print ISSN: 1027-5606
    Electronic ISSN: 1607-7938
    Topics: Geography , Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 10
    Publication Date: 2011-08-25
    Description: In this paper we present a semi-automatic method to infer groundwater flow-paths based on the extraction of lineaments from digital elevation models. This method is especially adequate in remote and inaccessible areas where in-situ data are scarce. The combined method of linear filtering and object-based classification provides a lineament map with a high degree of accuracy. Subsequently, lineaments are differentiated into geological and morphological lineaments using auxiliary information and finally evaluated in terms of hydro-geological significance. Using the example of the western catchment of the Dead Sea (Israel/Palestine), the orientation and location of the differentiated lineaments are compared to characteristics of known structural features. We demonstrate that a strong correlation between lineaments and structural features exists. Using Euclidean distances between lineaments and wells provides an assessment criterion to evaluate the hydraulic significance of detected lineaments. Based on this analysis, we suggest that the statistical analysis of lineaments allows a delineation of flow-paths and thus significant information on groundwater movements. To validate the flow-paths we compare them to existing results of groundwater models that are based on well data.
    Print ISSN: 1027-5606
    Electronic ISSN: 1607-7938
    Topics: Geography , Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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