ALBERT

Beschreibung: Only few well-dated records document the evolution of Southeast Asian paleoenvironments during the Cenozoic. Here we analyse continental pollen assemblages from Late Oligocene and Miocene fossil sites of Thailand. In agreement with previous studies, palynoflora from the Oligocene suggests warm temperate forested habitats at 24–26 Ma, whereas Middle Miocene assemblages are made of thermophilous taxa. This change can be linked to the major climate reorganization that brought warmer and wetter conditions over Southeast Asia around 22 Ma. This study also provides the first submillional records from the Middle Miocene of Thailand. Thirteen samples of lignite layers from the sivaladapid-bearing Mae Moh site, dated between 13.3 and 13.1 Ma, and six samples from the hominoid-bearing Chiang Muan deposit, dated between 12.4 and 12.2 Ma, document oscillations between tropical woodlands and grasslands in northern Thailand. These pollen records likely reflect climate variations linked to insolation variations. Late Miocene palynological assemblages from Khorat, northeastern Thailand, document fluviolacustrine paleoenvironments alternatively covered by thermophilous trees and grasslands. These records show that both sivaladapids and early hominoids from Thailand have evolved in tropical environments with high variability in the vegetation cover.

Beschreibung: Ozone concentrations in the Po Valley of Northern Italy often exceed international regulations. As both a source of radicals and an intermediate in the oxidation of most volatile organic compounds (VOCs), formaldehyde (HCHO) is a useful tracer for the oxidative processing of hydrocarbons that leads to ozone production. We investigate the sources of HCHO in the Po Valley using vertical profile measurements acquired from the airship Zeppelin NT over an agricultural region during the PEGASOS 2012 campaign. Using a 1-D model, the total VOC oxidation rate is examined and discussed in the context of formaldehyde and ozone production in the early morning. While model and measurement discrepancies in OH reactivity are small (on average 3.4±11%), HCHO concentrations are underestimated by as much as 1.5 ppb (45%) in the convective mixed layer. A similar underestimate in HCHO was seen in the 2002–2003 FORMAT Po-Valley measurements, though the additional source of HCHO was not identified. Oxidation of unmeasured VOC precursors cannot explain the missing HCHO source, as measured OH reactivity is explained by measured VOCs and their calculated oxidation products. We conclude that local direct emissions from agricultural land are the most likely source of missing HCHO. Model calculations demonstrate that radicals from degradation of this non-photochemical HCHO source increase model ozone production rates by as much as 0.7 ppb h−1 (10%) before noon.

Beschreibung: The performance of 20 European laboratories involved in long-term non-methane hydrocarbon (NMHC) measurements within the framework of Global Atmosphere Watch (GAW) and European Monitoring and Evaluation Programme (EMEP) was assessed with respect to the ACTRIS (Aerosols, Clouds, and Trace gases Research InfraStructure Network) and GAW data quality objectives (DQOs). Compared to previous intercomparisons the DQOs of ACTRIS are much more demanding with deviations to a reference value of less than 5% and repeatability of better than 2% for mole fractions above 0.1 nmol mol−1. The participants were asked to measure both a 30 component NMHC mixture in nitrogen (NMHC_N2) at approximately 1 nmol mol−1 and whole air (NMHC_air), following a standardised operation procedure including zero- and calibration gas measurements. Furthermore, they had to report details on their instruments and they were asked to assess measurement uncertainties. The NMHCs were analysed either by gas chromatography-flame ionisation detection or gas chromatography-mass spectrometer methods. Most systems performed well for the NMHC_N2 measurements (88% of the reported values were within the GAW DQOs and even 58% within the ACTRIS DQOs). For NMHC_air generally more frequent and larger deviations to the assigned values were observed compared to NMHC_N2 (77% of the reported values were within the GAW DQOs, but only 48% within the ACTRIS DQOs). Important contributors to the poorer performance in NMHC_air compared to NMHC_N2 were a more complex matrix and a larger span of NMHC mole fractions (0.03–2.5 nmol mol−1). Issues, which affected both NMHC mixtures, are the usage of direct vs. two-step calibration, breakthrough of C2–C3 hydrocarbons, blank values in zero-gas measurements (especially for those systems using a Nafion® Dryer), adsorptive losses of aromatic compounds, and insufficient chromatographic resolution. Essential for high-quality results are experienced operators, a comprehensive quality assurance and quality control, well characterised systems, and sufficient man-power to operate the systems and evaluate the data.