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  • 2015-2019  (601)
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Year
  • 1
    Publication Date: 2020-12-02
    Description: At Integrated Ocean Drilling Program (IODP) Expedition 317 Site U1352, east of the South Island New Zealand, we continuously cored a 1927-m-thick Holocene-to-Eocene section where we can uniquely document downhole changes in induration and lithification in siliciclastic to calcareous fine-grained sediment using a wide range of petrological, physical-property, and geochemical data sets. Porosity decreases from around 50% at the surface to 5–10% at the base of the deepest hole, with a corresponding increase in density from ∼ 2 to ∼ 2.5 g cm3. There are progressive bulk mineral changes with depth, including an increase in carbonate and decrease in quartz and clay content. Grain compaction is first seen in thin section at 347 m below sea floor and intensifies downhole. Pressure solution (chemical compaction) begins at 380 m and is common below 1440 m, with stylolite development below 1600 m, and sediment injection features below 1680 m. Porewater geochemistry and petrographic observations document two active zones of cementation, one shallow (eogenetic) down to ∼ 50 m, as evidenced by micritic nodules and pore-water geochemistry driven by methane oxidation by sulfate, and another burial-related cementation zone (mesogenetic) starting at ∼ 300 m. A transitional zone occurs between 50 and 300 m. Our results quantify downhole diagenetic changes and verify depth estimates for these processes inferred from outcrop studies, and provide an actualistic example of cementation and compaction trends in a slope setting.
    Description: Published
    Description: 272–287
    Description: 5A. Paleoclima e ricerche polari
    Description: JCR Journal
    Keywords: 04.04. Geology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2019-04-15
    Description: The Amazon delivers a fifth of the global continental runoff and riverine dissolved organic carbon (DOC) to the ocean. Intensified biogeochemical processes are expected at the junction of the Amazon's major blackwater tributary, the Rio Negro, and its parent, the Rio Solimbes, due to large gradients in pH, conductivity, DOC and particle load. Dissolved organic matter (DOM) plays a major role in aquatic biogeochemical processes which are poorly understood on the molecular level. To gain insights into the potential role of DOM in non-conservative processes, we assessed dynamics of Cu, Fe and DOM by ultrahigh resolution mass spectrometry in: (1) endmembers, (2) regional samples and (3) laboratory mixing experiments under presence/absence of natural particles (〉0.2 p.m). The relative abundances of 3600 DOM molecular formulae were interpreted via multivariate statistics which revealed major dynamics in the DOM molecular composition. 〉40% of molecular formulae displayed conservative behavior even in the presence of natural particles, agreeing with bulk DOC behavior, but opposing the oftenpresumed non-conservative behavior of DOM. Another 16-27% of formulae fluctuated in FT-ICRMS signal intensity during mixing, but did not show consistent non-conservative behavior. Both rivers left a clear molecular imprint within the DOM of the Amazon, each being linked to 〉800 molecular formulae. Characteristic for the Rio Negro was a dominance of phenolics with a wide molecular mass range (centered at similar to 400 Da), and for the Rio Solimbes more saturated but lower-molecular mass compounds (centered at similar to 300 Da). Both Fe and Cu showed distinct non-conservative mixing patterns under particle presence. In the controlled mixing experiments including original particles at natural concentration, up to 0.5 ttg/L Cu was released from the particles into solution at 20-40% blackwater contribution. Our molecular analysis revealed distinct DOM compositional changes in polyphenol- and nitrogencontaining formulae paralleling this release, suggesting links to desorption of potential ligands and charge-induced effects at particle surfaces caused by pH and conductivity changes in the course of mixing. (C) 2019 Elsevier Ltd. All rights reserved.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
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  • 3
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    In:  EPIC3New Advances in Geophysics: The Future of Passive Seismic Acquisition, Edinburgh, 2018-11-12-2018-11-13
    Publication Date: 2018-12-07
    Description: Ocean-bottom seismometers (OBSs) allow us to extend seismological research to the oceans to constrain offshore seismicity but also image the marine subsurface. A challenge is the high noise level on OBS records, which is created not only by bottom currents but also by the specific seismometer models used. We present a uantitative noise model for the LOBSTER OBS, which is the main instrument of DEPAS, currently the largest European OBS pool, stationed at Alfred-Wegener-Institut (AWI) Bremerhaven. Studying sensor noise in vault conditions and current sensitivity at an oceanographic measurement mast, we can show that the previously reported high noise level of the instrument is caused by the original sensor (Güralp CMG-40T-OBS) or its housing. We also show that a strong signal that has been reported between 1 and 5 Hz can be attributed to head- buoy cable strumming. This noise signal can actually be used to estimate bottom current velocities with relatively high precision to a few cm/s. We provide a current-dependent quantitative noise model that can be used for experiment design in future deployments. We further show that replacing the original sensor with a Trillium compact considerably improves the performance of the pool OBS at moderate cost.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Conference , notRev
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  • 4
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    In:  EPIC3European Geosciences Union General Assembly 2018, Vienna, Austria, 2018-04-08-2018-04-13
    Publication Date: 2018-02-25
    Description: Current measurements in the oceans are of importance for understanding the global exchange of water masses and also to verify the output of Earth System Models (ESM). The benthic layer in abyssal depths, which makes up the largest part of the global sea floor, is poorly sampled in this respect, even though the current velocities there are of importance for understanding the global circulation, but also its impact on the benthic fauna. We show that the noise recorded by a widely used brand of ocean-bottom-seismometers (LOBSTER) be tween 1 and 10 Hz is highly sensitive to the current velocity. This is due to resonance frequency of the head buoy cable being very close to the Kármán vortex shedding frequency for currents of a few centimeter per second. This creates a clear, harmonic signal, which has been found at deployments of the instrument in various regions in the Atlantic and the Indian Ocean. Since OBS are measuring permanently for a year or more and are deployed over wide areas, this may become a completely novel dataset for physical oceanography. We tested the proposed relationship by installing three ocean bottom seismometers near an oceanographic measuring pile located at Darss Silt in the south-western Baltic sea. where hourly current records from an acoustic doppler current profiler (ADCP) are available.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Conference , notRev
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  • 5
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    In:  EPIC3International training course on ocean bottom and amphibian experiment seismological data, 5th YES Congress, Potsdam, 2019-09-05-2019-09-06
    Publication Date: 2019-12-22
    Repository Name: EPIC Alfred Wegener Institut
    Type: Conference , notRev
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  • 6
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    In:  EPIC3Seismological Research Letters, 89(5), pp. 1845-1845, ISSN: 0895-0695
    Publication Date: 2018-12-07
    Description: Ocean-bottom seismometers (OBSs) allow us to extend seismo-logical research to the oceans to constrain offshore seismicity but also image the marine subsurface. A challenge is the high noise level on OBS records, which is created not only by bottom currents but also by the specific seismometer models used. We present a quantitative noise model for the LOBSTER OBS, which is the main instrument of DEPAS, currently the largest European OBS pool, stationed at Alfred-Wegener-Institut (AWI) Bremerhaven. Studying sensor noise in vault conditions and current sensitivity at an oceanographic measurement mast, we can show that the previously reported high noise level of the instrument is caused by the original sensor (Güralp CMG-40T-OBS). We also show that a strong signal that has been reported between 1 and 5 Hz can be attributed to head-buoy cable strumming. We provide a current-dependent quantitative noise model that can be used for experiment design in future deployments and show that the performance of the pool OBS can be improved at moderate cost by replacing the CMG-40T-OBS with a sensor of a proven noise floor below 10−8 nm=s2 , for example, a Trillium compact.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 7
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    In:  EPIC3European Geosciences Union General Assembly 2018, Vienna, Austria, 2018-04-08-2018-04-13
    Publication Date: 2018-02-25
    Description: The DEPAS (DEutscher Pool für Amphibische Seismologie) is the largest pool of wideband ocean-bottom seismometers in Europe. It consists of LOBSTER OBS, manufactured by KUM, which are equipped with Güralp CMG-40T-OBS and Trillium compact sensors. Multiple operators reported a relatively high long-period noise level of the original CMG-40T-equipped design. It has been discussed whether the source of this noise is the integration of the seismometer into the frame or the instrument itself. Using vault installations of the seismometer and test deployments of different LOBSTER next to a current sensor, we can show that the long-period noise is caused by the CMG-40T-OBS sensor itself. Equipped with a Trillium compact seismometer, the LOBSTER has a median vertical noise level of -155 dB at 120s period for current velocities below 10cm/s, which is essentially the self-noise of the seismometer. Even at relatively high bottom currents above 20 cm/s, the noise level does not exceed the Peterson New High Noise Model at these periods. We present a quantitative noise model for the LOBSTER and conclude that its rugged design is suited for seismology on periods below 300 seconds, if it is equipped with a good seismometer.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Conference , notRev
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  • 8
    Publication Date: 2016-02-07
    Description: RHUM-RUM is a German-French seismological experiment based on the sea floor surrounding the island of La Réunion, western Indian Ocean (Barruol and Sigloch, 2013). Its primary objective is to clarify the presence or absence of a mantle plume beneath the Reunion volcanic hotspot. RHUM-RUM's central component is a 13-month deployment (October 2012 to November 2013) of 57 broadband ocean bottom seismometers (OBS) and hydrophones over an area of 2000  ×  2000  km2 surrounding the hotspot. The array contained 48 wideband OBS from the German DEPAS pool and 9 broadband OBS from the French INSU pool. It is the largest deployment of DEPAS and INSU OBS so far, and the first joint experiment. This article reviews network performance and data quality: of the 57 stations, 46 and 53 yielded good seismometer and hydrophone recordings, respectively. The 19 751 total deployment days yielded 18 735 days of hydrophone recordings and 15 941 days of seismometer recordings, which are 94 and 80 % of the theoretically possible yields. The INSU seismic sensors stand away from their OBS frames, whereas the DEPAS sensors are integrated into their frames. At long periods (〉  10  s), the DEPAS seismometers are affected by significantly stronger noise than the INSU seismometers. On the horizontal components, this can be explained by tilting of the frame and buoy assemblage, e.g. through the action of ocean-bottom currents, but in addition the DEPAS intruments are affected by significant self-noise at long periods, including on the vertical channels. By comparison, the INSU instruments are much quieter at periods 〉  30  s and hence better suited for long-period signals studies. The trade-off of the instrument design is that the integrated DEPAS setup is easier to deploy and recover, especially when large numbers of stations are involved. Additionally, the wideband sensor has only half the power consumption of the broadband INSU seismometers. For the first time, this article publishes response information of the DEPAS instruments, which is necessary for any project where true ground displacement is of interest. The data will become publicly available at the end of 2017.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , peerRev
    Format: application/pdf
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  • 9
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    In:  EPIC3International training course on ocean bottom and amphibian experiment seismological data, 5th YES Congress, Potsdam, 2019-09-05-2019-09-06
    Publication Date: 2019-12-22
    Repository Name: EPIC Alfred Wegener Institut
    Type: Conference , notRev
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  • 10
    Publication Date: 2017-06-06
    Description: Block polymer self-assembly typically translates molecular chain connectivity into mesoscale structure by exploiting incompatible blocks with large interaction parameters (χij). In this article, we demonstrate that the converse approach, encoding low-χ interactions in ABC bottlebrush triblock terpolymers (χAC≲ 0), promotes organization into a unique mixed-domain lamellar morphology, which we designate LAMP. Transmission electron microscopy indicates that LAMP exhibits ACBC domain connectivity, in contrast to conventional three-domain lamellae (LAM3) with ABCB periods. Complementary small-angle X-ray scattering experiments reveal a strongly decreasing domain spacing with increasing total molar mass. Self-consistent field theory reinforces these observations and predicts that LAMP is thermodynamically stable below a critical χAC, above which LAM3 emerges. Both experiments and theory expose close analogies to ABA′ triblock copolymer phase behavior, collectively suggesting that low-χ interactions between chemically similar or distinct blocks intimately influence self-assembly. These conclusions provide fresh opportunities for block polymer design with potential consequences spanning all self-assembling soft materials.
    Print ISSN: 0027-8424
    Electronic ISSN: 1091-6490
    Topics: Biology , Medicine , Natural Sciences in General
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