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  • 2015-2019  (60)
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  • 1
    Call number: AWI G6-18-91956
    Description / Table of Contents: Earth's climate varies continuously across space and time, but humankind has witnessed only a small snapshot of its entire history, and instrumentally documented it for a mere 200 years. Our knowledge of past climate changes is therefore almost exclusively based on indirect proxy data, i.e. on indicators which are sensitive to changes in climatic variables and stored in environmental archives. Extracting the data from these archives allows retrieval of the information from earlier times. Obtaining accurate proxy information is a key means to test model predictions of the past climate, and only after such validation can the models be used to reliably forecast future changes in our warming world. The polar ice sheets of Greenland and Antarctica are one major climate archive, which record information about local air temperatures by means of the isotopic composition of the water molecules embedded in the ice. However, this temperature proxy is, as any indirect climate data, not a perfect recorder of past climatic variations. Apart from local air temperatures, a multitude of other processes affect the mean and variability of the isotopic data, which hinders their direct interpretation in terms of climate variations. This applies especially to regions with little annual accumulation of snow, such as the Antarctic Plateau. While these areas in principle allow for the extraction of isotope records reaching far back in time, a strong corruption of the temperature signal originally encoded in the isotopic data of the snow is expected. This dissertation uses observational isotope data from Antarctica, focussing especially on the East Antarctic low-accumulation area around the Kohnen Station ice-core drilling site, together with statistical and physical methods, to improve our understanding of the spatial and temporal isotope variability across different scales, and thus to enhance the applicability of the proxy for estimating past temperature variability. The presented results lead to a quantitative explanation of the local-scale (1–500 m) spatial variability in the form of a statistical noise model, and reveal the main source of the temporal variability to be the mixture of a climatic seasonal cycle in temperature and the effect of diffusional smoothing acting on temporally uncorrelated noise. These findings put significant limits on the representativity of single isotope records in terms of local air temperature, and impact the interpretation of apparent cyclicalities in the records. Furthermore, to extend the analyses to larger scales, the timescale-dependency of observed Holocene isotope variability is studied. This offers a deeper understanding of the nature of the variations, and is crucial for unravelling the embedded true temperature variability over a wide range of timescales.
    Type of Medium: Dissertations
    Pages: xxi, 197 Seiten , Illustrationen, Diagramme
    Language: English
    Note: Contents: 1 General introduction. - 1.1 Challenges of isotope-based temperature reconstructions. - 1.2 Thesis overview. - 1.3 Author contributions. - 2 Theoretical background. - 2.1 The isotopic composition of firn and ice. - 2.1.1 Fractionation of water isotopologues. - 2.1.2 Relationship with temperature. - 2.1.3 Measuring of the isotopic composition. - 2.2 Processes within the firn column. - 2.2.1 The firn column of polar ice sheets. - 2.2.2 The density of firn. - 2.2.3 The temperature profile of firn. - 2.2.4 Vapour diffusion in firn. - 2.3 Internal climate variability. - 3 Regional climate signal vs.local noise: a two-dimensional view of water isotopes. - 3.1 Introduction. - 3.2 Data and methods. - 3.3 Results. - 3.3.1 Trench isotope records. - 3.3.2 Single-profile representativity. - 3.3.3 Mean trench profiles. - 3.3.4 Spatial correlation structure. - 3.3.5 Statistical noise model. - 3.4 Discussion. - 3.4.1 Local noise vs. regional climate signal. - 3.4.2 Representativity of isotope signals. - 3.4.3 Implications. - 3.5 Conclusions. - 3.6 Appendix A: Derivation of noise model. - 3.6.1 Definitions. - 3.6.2 Derivation of model correlations. - 3.6.3 Estimation of parameters. - 3.7 Appendix B: Noise level after diffusion. - 4 Constraints on post-depositional isotope modifications in east antarctic firn. - 4.1 Introduction. - 4.2 Data and methods. - 4.2.1 Sampling and measurements. - 4.2.2 Trench depth scale. - 4.2.3 Spatial variability of trench profiles. - 4.2.4 Quantification of downward advection, densification and diffusion. - 4.2.5 Statistical tests. - 4.3 Results. - 4.3.1 Comparison of T15 and T13 isotope data. - 4.3.2 Expected isotope profile changes. - 4.3.3 Temporal vs. spatial variability. - 4.4 Discussion. - 4.4.1 Densification, diffusion and stratigraphic noise. - 4.4.2 Additional post-depositional modifications. - 4.5 Conclusions. - 5 On the similarity and apparent cycles of isotope variations. - 5.1 Introduction. - 5.2 Data and Methods. - 5.2.1 Data. - 5.2.2 Spectral analysis. - 5.2.3 Rice’s formula. - 5.2.4 Cycle length and amplitude estimation. - 5.2.5 Model for vertical isotope profiles. - 5.3 Results. - 5.3.1 Spectral analysis of isotope profiles. - 5.3.2 Theoretical and observed cycle length. - 5.3.3 Illustrative examples. - 5.3.4 Depth dependency of cycle length. - 5.3.5 Simulated vs. observed isotope variations. - 5.4 Discussion and summary. - 5.5 Conclusions. - 5.6 Appendix A: Input sensitivity. - 5.7 Appendix B: Additional results. - 5.8 Appendix C: Spectral significance testing. - 6 Timescale-dependency of antarctic isotope variations. - 6.1 Introduction. - 6.2 Data and methods. - 6.2.1 DML and WAIS isotope records. - 6.2.2 Spectral model. - 6.2.3 Timescale-dependent signal-to-noise ratio. - 6.2.4 Effects of diffusion and time uncertainty. - 6.2.5 Present-day temperature decorrelation. - 6.3 Results. - 6.3.1 Illustration of model approach. - 6.3.2 DML and WAIS isotope variability. - 6.4 Discussion. - 6.4.1 Interpretation of noise spectra. - 6.4.2 Interpretation of signal spectra. - 6.4.3 Signal-to-noise ratios. - 6.4.4 Differences between DML and WAIS. - 6.5 Conclusions. - 7 Declining temperature variability from LGM to holocene. - 8 General discussion and conclusions. - 8.1 Short-scale spatial and temporal isotope variability. - 8.1.1 Local spatial variability. - 8.1.2 Seasonal to interannual variability. - 8.1.3 Spatial vs. temporal variability. - 8.2 Extension to longer scales. - 8.2.1 Spatial vs. temporal variability on interannual timescales. - 8.2.2 Holocene and longer timescales. - 8.3 Concluding remarks and outlook. - Bibliography. - A Methods to: declining temperature variability from lgm to holocene. - A.1 Temperature proxy data. - A.2 Model-based temperature and variability change. - A.3 Temperature recalibration of proxy records. - A.3.1 Recalibration of ice-core records. - A.3.2 Recalibration of marine records. - A.4 Variance and variance ratio estimation. - A.5 Noise correction. - A.5.1 Testing effect of noise correction. - A.6 Effect of ecological adaption and bioturbation. - A.7 Effect of proxy sampling locations. - B Layering of surface snow and firn: noise or seasonal signal?. - B.1 Introduction. - B.2 Materials and methods. - B.2.1 Firn-core density profiles. - B.2.2 Trench density profiles. - B.2.3 Dielectric profiling and density estimates. - B.2.4 Comparison of DEP and CT density. - B.2.5 Ion measurements. - B.3 Results. - B.3.1 2-D trench density data. - B.3.2 Spatial correlation structure. - B.3.3 Comparison of mean density, isotope and impurity profiles. - B.3.4 Spectral analysis of vertical density data. - B.4 Discussion. - B.4.1 Spatial variability. - B.4.2 Representativeness of single profiles. - B.4.3 Seasonal cycle in snow density. - B.4.4 Density layering in firn and impurities. - B.5 Conclusions. - Acknowledgements - Danksagung.
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  • 2
    Publication Date: 2015-12-02
    Description: 3D microstructure-performance relationships in Ni-YSZ anodes for electrolyte-supported cells are investigated in terms of the correlation between the triple phase boundary (TPB) length and polarization resistance (Rpol). Three different Ni-YSZ anodes of varying microstructure are subjected to eight reduction-oxidation (redox) cycles at 950 °C. In general the TPB lengths correlate with anode performance. However, the quantitative results also show that there is no simplistic relationship between TPB and Rpol. The degradation mechanism strongly depends on the initial microstructure. Finer microstructures exhibit lower degradation rates of TPB and Rpol. In fine microstructures, TPB loss is found to be due to Ni coarsening, while in coarse microstructures reduction of active TPB results mainly from loss of YSZ percolation. The latter is attributed to weak bottlenecks associated with lower sintering activity of the coarse YSZ. The coarse anode suffers from complete loss of YSZ connectivity and associated drop of TPBactive by 93%. Surprisingly, this severe microstructure degradation did not lead to electrochemical failure. Mechanistic scenarios are discussed for different anode microstructures. These scenarios are based on a model for coupled charge transfer and transport, which allows using TPB and effective properties as input. The mechanistic scenarios describe the microstructure influence on current distributions, which explains the observed complex relationship between TPB lengths and anode performances. The observed loss of YSZ percolation in the coarse anode is not detrimental because the electrochemical activity is concentrated in a narrow active layer. The anode performance can be predicted reliably if the volume-averaged properties (TPBactive, effective ionic conductivity) are corrected for the so-called short-range effect, which is particularly important in cases with a narrow active layer.
    Electronic ISSN: 1996-1944
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Published by MDPI Publishing
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  • 3
    Publication Date: 2017-04-07
    Print ISSN: 1367-4803
    Electronic ISSN: 1460-2059
    Topics: Biology , Computer Science , Medicine
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  • 4
    Publication Date: 2016-11-17
    Description: The oldest ice core records are obtained from the East Antarctic plateau. Water stable isotopes records are key for reconstructions of past climatic conditions both over the ice sheet and at the evaporation source. The accuracy of such climate reconstructions crucially depends on the knowledge of all the processes affecting the water vapour, precipitation and snow isotopic composition. Atmospheric fractionation processes are well understood and can be integrated in Rayleigh distillation and complex isotope enabled climate models. However, a comprehensive quantitative understanding of processes potentially altering the snow isotopic composition after the deposition is still missing, especially for exchanges between vapour and snow. In low accumulation sites such as found on the East Antarctic Plateau, these poorly constrained processes are especially likely to play a significant role. This limits the interpretation of isotopic composition from ice core records, specifically at short time scales. Here, we combine observations of isotopic composition in the vapour, the precipitation, the surface snow and the buried snow from various sites of the East Antarctic Plateau. At the seasonal scale, we highlight a significant impact of metamorphism on surface snow isotopic signal compared to the initial precipitation isotopic signal. In particular, in summer, exchanges of water molecules between vapour and snow are driven by the sublimation/condensation cycles at the diurnal scale. Using highly resolved isotopic composition profiles from pits in five East Antarctic sites, we identify a common 20 cm cycle which cannot be attributed to the seasonal variability of precipitation. Altogether, the smaller range of isotopic compositions observed in the buried and in the surface snow compared to the precipitation, and also the reduced slope between surface snow isotopic composition and temperature compared to precipitation, constitute evidences of post-deposition processes affecting the variability of the isotopic composition in the snow pack. To reproduce these processes in snow-models is crucial to understand the link between snow isotopic composition and climatic conditions and to improve the interpretation of isotopic composition as a paleoclimate proxy.
    Print ISSN: 1994-0432
    Electronic ISSN: 1994-0440
    Topics: Geography , Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 5
  • 6
    Publication Date: 2016-07-22
    Description: In low-accumulation regions, the reliability of δ18O-derived temperature signals from ice cores within the Holocene is unclear, primarily due to the small climate changes relative to the intrinsic noise of the isotopic signal. In order to learn about the representativity of single ice cores and to optimise future ice-core-based climate reconstructions, we studied the stable-water isotope composition of firn at Kohnen Station, Dronning Maud Land, Antarctica. Analysing δ18O in two 50 m long snow trenches allowed us to create an unprecedented, two-dimensional image characterising the isotopic variations from the centimetre to the 100-metre scale. Our results show seasonal layering of the isotopic composition but also high horizontal isotopic variability caused by local stratigraphic noise. Based on the horizontal and vertical structure of the isotopic variations, we derive a statistical noise model which successfully explains the trench data. The model further allows one to determine an upper bound for the reliability of climate reconstructions conducted in our study region at seasonal to annual resolution, depending on the number and the spacing of the cores taken.
    Print ISSN: 1814-9324
    Electronic ISSN: 1814-9332
    Topics: Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 7
    Publication Date: 2017-04-05
    Description: Stable water isotopes in firn and ice cores are extensively used to infer past climate changes. In low-accumulation regions their interpretation is however challenged by poorly constrained effects that may influence the initial isotope signal during and after deposition. This is reflected in snow-pit isotope data from Kohnen Station, Antarctica, which exhibit a clear seasonal cycle but also strong inter-annual variations that contradict local temperature observations. These inconsistencies persist even after averaging many profiles and are thus not explained by local stratigraphic noise. Previous studies have suggested that post-depositional processes may significantly influence the isotopic composition of East Antarctic firn. Here, we reject the hypothesis of post-depositional change within the open-porous firn beyond diffusion and densification. To this end, we analyse 22 stable water isotope profiles obtained from two snow trenches at Kohnen Station and examine the temporal isotope modifications by comparing the new with published trench data extracted 2 years earlier. The initial isotope profiles undergo changes over time due to downward-advection, firn diffusion and densification in magnitudes consistent with independent estimates. Beyond that, we find no evidence for additional modification of the original isotope record. These results show that the discrepancy between local temperatures and isotopes most likely originates from spatially coherent processes prior to or during deposition, such as precipitation intermittency or systematic isotope modifications acting on drifting or loose surface snow.
    Print ISSN: 1994-0432
    Electronic ISSN: 1994-0440
    Topics: Geography , Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 8
    Publication Date: 2017-09-11
    Description: Stable water isotopes in polar ice provide a wealth of information about past climate evolution. Snow pit studies allow us to relate observed weather and climate conditions to the measured isotope variations in the snow. They therefore offer the possibility to test our understanding of how isotope signals are formed and stored in firn and ice. As stable water isotopes in the snowfall are strongly correlated to air temperature, isotopes in the near surface snow are supposed to depict the seasonal cycle at a given site. Accordingly, variation between sites in accumulation rate is expected to be matched by variation in the number of seasonal cycles. However, snowpit studies from different accumulation conditions in East Antarctica reported similar isotopic variability and comparable apparent cycles in the δ18O and δD profiles with typical wavelengths of ∼ 20 cm. These observations are unexpected as the accumulation rates strongly differ between the sites, ranging from 20 to 80 mm w.e. yr−1 (∼ 5–25 cm of snow per year). Various mechanism have been proposed to explain the isotopic variations individually at each site; however, none of these is consistent with the similarity of the different profiles independent of the local accumulation conditions. Here, we systematically analyze the properties and origins of isotopic variations in high-resolution firn profiles from eight East Antarctic sites. First, we confirm the suggested cycle length (mean distance between peaks) of ∼ 20 cm by counting the isotopic maxima. Spectral analysis further shows a strong similarity between the sites but indicates no dominant periodic features. Finally, the apparent cycle length increases with depth for most East Antarctic sites, which is inconsistent with burial and compression of a regular seasonal cycle. We show that these results can be explained by isotopic diffusion acting on a noise dominated isotope signal. The firn diffusion length is rather stable across the East Antarctic and thus leads to similar power spectral densities of the isotopic variations. This in turn implies a similar distance between isotopic maxima in the firn profiles. Our results explain a large set of observations discussed in the literature, providing a simple explanation for the interpretation of apparent cycles in shallow isotope records, without invoking complex mechanisms. Finally, the results underline previous suggestions that isotopic signals in single ice cores from low-accumulation regions have a small signal-to-noise ratio and thus likely do not allow the reconstruction of interannual to decadal climate variations.
    Print ISSN: 1994-0432
    Electronic ISSN: 1994-0440
    Topics: Geography , Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 9
    Publication Date: 2017-11-03
    Description: The oldest ice core records are obtained from the East Antarctic plateau. Water isotopes records are key to reconstructing past climatic conditions over the ice sheet and at the evaporation source. The accuracy of climate reconstructions depends on knowledge of all the processes affecting water vapour, precipitation and snow isotopic compositions. Fractionation processes are well understood and can be integrated in Rayleigh distillation and isotope enabled climate models. However, a quantitative understanding of processes potentially altering the snow isotopic composition after the deposition is still missing. In low accumulation sites, such as those found in Antarctica, these poorly constrained processes are likely to play a significant role and limit the interpretation of isotopic composition. Here, we combine observations of isotopic composition in the vapour, the precipitation, the surface snow and the buried snow from Dome C, a deep ice core site on the East Antarctic Plateau. At the seasonal scale, we suggest a significant impact of metamorphism on surface snow isotopic signal compared to the initial precipitation signal. Particularly, in summer, exchanges of water molecules between vapour and snow are driven by the sublimation/condensation cycles at the diurnal scale. Using highly resolved isotopic composition profiles from pits in five Antarctic sites, we identify common patterns, despite different accumulation rates, which cannot be attributed to the seasonal variability of precipitation. Altogether, the difference in the signals observed in the precipitation, surface snow and buried snow isotopic composition constitute evidences of post-deposition processes affecting ice core records in low accumulation areas.
    Print ISSN: 1994-0432
    Electronic ISSN: 1994-0440
    Topics: Geography , Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 10
    Publication Date: 2017-09-12
    Description: The isotopic composition of water in ice sheets is extensively used to infer past climate changes. In low-accumulation regions their interpretation is, however, challenged by poorly constrained effects that may influence the initial isotope signal during and after deposition of the snow. This is reflected in snow-pit isotope data from Kohnen Station, Antarctica, which exhibit a seasonal cycle but also strong interannual variations that contradict local temperature observations. These inconsistencies persist even after averaging many profiles and are thus not explained by local stratigraphic noise. Previous studies have suggested that post-depositional processes may significantly influence the isotopic composition of East Antarctic firn. Here, we investigate the importance of post-depositional processes within the open-porous firn (≳ 10 cm depth) at Kohnen Station by separating spatial from temporal variability. To this end, we analyse 22 isotope profiles obtained from two snow trenches and examine the temporal isotope modifications by comparing the new data with published trench data extracted 2 years earlier. The initial isotope profiles undergo changes over time due to downward advection, firn diffusion and densification in magnitudes consistent with independent estimates. Beyond that, we find further modifications of the original isotope record to be unlikely or small in magnitude (≪ 1 ‰ RMSD). These results show that the discrepancy between local temperatures and isotopes most likely originates from spatially coherent processes prior to or during deposition, such as precipitation intermittency or systematic isotope modifications acting on drifting or loose surface snow.
    Print ISSN: 1994-0416
    Electronic ISSN: 1994-0424
    Topics: Geography , Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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