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  • 1
    Publication Date: 2022-05-25
    Description: © The Author(s), 2015. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Deep Sea Research Part II: Topical Studies in Oceanography 116 (2015): 303-320, doi:10.1016/j.dsr2.2014.11.020.
    Description: The concentration and the major phase composition (particulate organic matter, CaCO3, opal, lithogenic matter, and iron and manganese oxyhydroxides) of marine particles is thought to determine the scavenging removal of particle-reactive TEIs. Particles are also the vector for transferring carbon from the atmosphere to the deep ocean via the biological carbon pump, and their composition may determine the efficiency and strength of this transfer. Here, we present the first full ocean depth section of size-fractionated (1–51 µm, 〉51 µm) suspended particulate matter (SPM) concentration and major phase composition from the US GEOTRACES North Atlantic Zonal Transect between Woods Hole, MA and Lisbon, Portugal conducted in 2010 and 2011. Several major particle features are notable in the section: intense benthic nepheloid layers were observed in the western North American margin with concentrations of SPM of up to 1648 µg/L, two to three orders of magnitude higher than surrounding waters, that were dominated by lithogenic material. A more moderate benthic nepheloid layer was also observed in the eastern Mauritanian margin (44 µg/L) that had a lower lithogenic content and, notably, significant concentrations of iron and manganese oxyhydroxides (2.5% each). An intermediate nepheloid layer reaching 102 µg/L, an order of magnitude above surrounding waters, was observed associated with the Mediterranean Outflow. Finally, there was a factor of two enhancement in SPM at the TAG hydrothermal plume due almost entirely to the addition of iron oxyhydroxides from the hydrothermal vent. We observe correlations between POC and CaCO3 in large (〉51 µm) particles in the upper 2000 m, but not deeper than 2000 m, and no correlations between POC and CaCO3 at any depth in small (〈51 µm) particles. There were also no correlations between POC and lithogenic material in large particles. Overall, there were very large uncertainties associated with all regression coefficients for mineral ballast (“carrying coefficients”), suggesting that mineral ballast was not a strong predictor for POC in this section.
    Description: US and International GEOTRACES Offices (NSF OCE-0850963 and OCE-1129603)
    Keywords: Particles ; SPM ; CaCO3 ; Opal ; Biogenic silica ; POC ; Ballast ; Dust ; Lithogenic material
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
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  • 2
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 33(1), (2019): 15-36, doi:10.1029/2018GB005985.
    Description: Better constraints on the magnitude of particulate export and the residence times of trace elements are required to understand marine food web dynamics, track the transport of anthropogenic trace metals in the ocean, and improve global climate models. While prior studies have been successful in constructing basin‐scale budgets of elements like carbon in the upper ocean, the cycling of particulate trace metals is poorly understood. The 238U‐234Th method is used here with data from the GP‐16 GEOTRACES transect to investigate the upper ocean processes controlling the particulate export of cadmium, cobalt, and manganese in the southeastern Pacific. Patterns in the flux data indicated that particulate cadmium and cobalt behave similarly to particulate phosphorus and organic carbon, with the highest export in the productive coastal region and decreasing flux with depth due to remineralization. The export of manganese was influenced by redox conditions at the low oxygen coastal stations and by precipitation and/or scavenging elsewhere. Residence times with respect to export (total inventory divided by particulate flux) for phosphorus, cadmium, cobalt, and manganese in the upper 100 and 200 m were determined to be on the order of months to years. These GEOTRACES‐based synthesis efforts, combining a host of concentration and tracer data with unprecedented resolution, will help to close the oceanic budgets of trace metals.
    Description: This work was supported by the National Science Foundation (OCE‐1232669 and OCE‐1518110), and Erin Black was also funded by a NASA Earth and Space Science Graduate Fellowship (NNX13AP31H). The authors would like to thank the captain, crew, and scientists aboard the R/V Thomas G. Thompson. A special thanks to two anonymous reviewers and Virginie Sanial for providing the additional 228Ra‐based estimates for Cd. All original data have been made available in either the supporting information or through BCO‐DMO (see Website and Database References).
    Description: 2019-06-10
    Keywords: Tthorium ; Export ; Trace metals ; Residence time
    Repository Name: Woods Hole Open Access Server
    Type: Article
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