Publication Date:
2015-12-15
Description:
As already extensively discussed in Part I of this series, the ‘climax’ of the studies at the ETH on the synthesis of corrins was reached with the conception and experimental realization of the corrin synthesis via a final ring closure between rings A and D by the photochemical A / D -secocorrin corrin cycloisomerization. As it was the case for the ‘ old corrin synthesis ’, described in Part IV of this series [4], the ‘ new synthesis ’ was first explored in a model system, before it became the antetype of the photochemical variant of the synthesis of vitamin B 12 .
Print ISSN:
0018-019X
Electronic ISSN:
1522-2675
Topics:
Chemistry and Pharmacology
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