ALBERT

Description: Highlights • Debunscha Maar magmas mixed and fractional crystallised at upper mantle depths • Its main magma source is peridotite with a minor pyroxenite component • Amphibole signal and high olivine Ca/Al indicate a metasomatised peridotite mantle • Mantle potential temperatures give no sign of an anomalous hot mantle Abstract Debunscha Maar is a monogenetic volcano forming part of the Mt. Cameroon volcanic field, located within the Cameroon Volcanic Line (CVL). Partly glassy cauliflower bombs have primitive basanite-picrobasalt compositions and contain abundant normally and reversely zoned olivine (Fo 77–87) and clinopyroxene phenocrysts. Naturally quenched melt inclusions in the most primitive olivine phenocrysts show compositions which, when corrected for post-entrapment modification, cover a wide range from basanite to alkali basalt (MgO 6.9–11.7 wt.%), and are generally more primitive than the matrix glasses (MgO 5.0–5.5 wt.%) and only partly fall on a common liquid line of descent with the bulk rock samples and matrix glasses. Melt inclusion trace element compositions lie on two distinct geochemical trends: one (towards high Ba/Nb) is thought to represent the effect of various proportions of anhydrous lherzolite and amphibole-bearing peridotite in the source, while the other (for example, high La/Y) reflects variable degrees of partial melting. Comparatively low fractionation-corrected CaO in the melt inclusions with the highest La/Y suggests minor involvement of a pyroxenite source component that is only visible at low degrees of melting. Most of the samples show elevated Gd/Yb, indicating up to 8% garnet in the source. The range of major and trace elements represented by the melt inclusions covers the complete geochemical range given by basalts from different volcanoes of the Cameroon volcanic line, indicating that geochemical signatures that were previously thought to be volcano-specific in fact are probably present under all volcanoes. Clinopyroxene-melt barometry strongly indicates repeated mixing of compositionally diverse melts within the upper mantle at 830 ± 170 MPa prior to eruption. Mantle potential temperatures estimated for the primitive melt inclusions suggest that the thermal influence of a mantle plume is not required to explain the magma petrogenesis.

Description: Highlights • Data set of Br and Cl emissions from 29 large CAVA eruptions (VEI 〉 5). • Melt inclusions are strongly enriched in chlorine and bromine compared to their respective matrix glasses. • Fluid partitioning is 4 to 68 times more efficient for Br than for Cl. • Subducted calcareous sediments are the major control on the arc-magmatic bromine contents. • Average CAVA eruption would add 368% EESC of recent annual loading to stratosphere. Abstract Large explosive volcanic eruptions inject gases, aerosols, and fine ashes into the stratosphere, potentially influencing climate and atmosphere composition on a global scale. Although the potential climate effect of chlorine (Cl) and bromine (Br) injections into the stratosphere is known, the global mass fluxes are poorly constrained. In this study we focus on the magmatic degassing systematics and budgets of Br and Cl, and on constraining the major sources of Br in a subduction setting. We therefore present a regional time series of Br and Cl emissions from 29 highly explosive eruptions throughout the Central American Volcanic Arc (CAVA), covering the last 200 ka, and a range of magmatic compositions and eruption magnitudes. We have measured Br and Cl in matrix glasses and melt inclusions using synchrotron radiation micro X-ray fluorescence spectrometry (SR micro-XRF) and electron microprobe, respectively. Melt inclusions of the CAVA tephras generally have higher Br (0.9 to 17.9 ppm) and Cl (770 to 3800 ppm) contents than the matrix glasses (0.39 to 1.5 ppm Br, 600 to 2800 ppm Cl). Moreover, the difference between maximum and minimum concentrations observed in melt inclusions of a given sample ranges between 9 and 90% of the maximum observed concentration for Br, and between 2 and 40% for Cl. Such intra-sample variations arise from variable pre-eruptive degassing of these halogens into a magmatic fluid phase. The relative loss of Br from the melt is 4 to 68 times higher than that of Cl. The masses of Br (2–1100 kt) and Cl (0.1 to 800 Mt) emitted by the eruptions generate instantaneous additions to the stratosphere potentially amounting to ∼6–5600% of the present-day stratospheric annual global loading of Equivalent Effective Stratospheric Chlorine. As the size of the stratospheric impact is primarily a function of eruption magnitude, we use magnitude-frequency relationships to estimate that eruptions adding ∼10% to resident EESC loading would occur every 〈40 years while every ∼200 years an eruption would double the EESC loading. Comparing the variations in Br and Cl concentrations and particularly minimum Cl/Br ratios in melt inclusions with geochemical trace-element proxies (e.g. U/La, Ba/Th) and lead-isotope compositions, which change along the arc in response to changing subduction conditions, we suggest that subducted calcareous sediment is a major source of magmatic Br but also infer an important role of fluids expelled from serpentinized subducted mantle. Extrapolation of CAVA volcanic Br emissions to the global subduction system thus needs to consider variations in the nature of subducted lithologies.

Description: Highlights • Individual evolution of temporal and spatial co-existing magma suites • Determination of pre-eruptive magma chamber conditions of the Cão Grande Formation magma chambers • Cão Grande Formation phonolite magmas typically reach H2O-saturation prior to the eruption. Abstract The Cão Grande Formation (CGF) on the western plateau of Santo Antão is a sequence of four phonolitic tephras (Canudo Tephra, Cão Grande I Tephra, Cão Grande II Tephra and Furninha Tephra) produced by highly explosive eruptions that alternatingly originated from a basanitic - phonolitic and a nephelinitic - phonolitic magmatic system. Detailed stratigraphy and petrological investigations of each unit are used to demonstrate the unusual situation that two distinct highly evolved magmas differentiated contemporaneously in separate magmatic systems. Chemical thermobarometry suggests that both magmatic systems not only temporally co-existed, but also that their magma chambers resided close to each other at 7 to 16 km depth, beneath the western plateau of Santo Antão. However, the distinct melt and magma compositions indicate that both systems evolved independently. The only interaction between both magmatic systems was an injection of magma from the nephelinitic - phonolitic magmatic system into the Cão Grande II Tephra (CG II) phonolitic reservoir, which is associated to the basanitic - phonolitic magmatic system. Compositional zonations in the tephra deposits indicate that the eruptions of the CGF tapped stratified magma reservoirs that mainly resulted from crystal accumulation generating downward increasing magma density. However, the CG II tephras also show a significant gradient in melt (glass) compositions. Magmas of the Canudo Tephra (CT) and the Cão Grande I Tephra (CG I) were H2O-saturated and their eruptions were probably triggered by fluid overpressure in the magma chamber. On the other hand, the CG II magma was H2O-undersaturated; we therefore assume that the injection of the hot nephelinitic - phonolitic magma system-type melt/magma triggered the eruption. The zoned deposit of the Furninha Tephra (FT) indicates mafic magma replenishment into a phonolitic reservoir directly prior to the eruption, thus providing a probable triggering mechanism. The new magma chamber models and thermobarometric results for the four CGF units provide constraints for hazard assessments, because similar events may occur in the future considering the longevity of the CGF magma systems.

Description: Highlights • Extensive set of 170 40Ar39Ar single-crystal ages for Cadamosto Seamount. • Volcanic eruption ages at Cadamosto Seamount are all young (〈 100 ka). • Three samples dominated by sanidine phenocrysts preserve a 21.04 ± 0.62 ka age. • Sanidine antecrysts in two samples show complex chemical zonation patterns. • Antecryst ages suggest long-lived magmatic activity in the seamount, up to 1.52 Ma. Abstract Cadamosto Seamount is located in the SW of the Cape Verde Archipelago in the central Atlantic Ocean off the west coast of Africa. Many radiometric dates exist for the islands in the archipelago; however, no geochronological information has been obtained from the numerous seamounts. The timescales for igneous processes in the submarine realm are thus poorly understood. In this study, we investigated five lavas that were sampled by dredging and ROV (remotely operated vehicle) from the flanks and summit areas of the largely phonolitic Cadamosto Seamount during two different research cruises. Chemical zonation patterns of minerals were determined by electron microprobe, and radiometric ages were obtained from single-crystal total-fusion and single−/multi-grain step-heating 40Ar39Ar analyses of sanidine, nepheline and sodalite-group minerals. Our 40Ar39Ar results reveal young sanidine eruption ages (all 〈100 ka) at Cadamosto Seamount: (1) Three western flank/summit lavas have a relatively simple petrology dominated by phenocrysts, and overlap with mean sanidine ages of 20.98 ± 0.87 ka, 21.44 ± 0.80 ka and 22.3 ± 2.0 ka, with a combined mean age of 21.04 ± 0.62 ka from the three samples (all uncertainties are quoted at 2σ). The remaining two samples from the summit/NE flank are dominated by complex zoned sanidines with resorbed antecrystic cores and phenocrystic rims. These samples yield older sanidine ages of 51.8 ± 2.4 ka and 97 ± 14 ka, which are interpreted to be maximum eruption ages. This is due to the dominance of antecrysts in these two samples and the possibility that the analyzed sanidine grains may be a mixture of older antecrystic cores and younger phenocrystic rims. The older 40Ar39Ar ages of many sanidine and nepheline antecrysts also give us clues regarding older magmatic events at Cadamosto Seamount, despite these grains having undergone resorption and phenocrystic rim overgrowths, resulting in some radiogenic 40Ar loss during entrainment in the subsequent magmas. The antecrysts minimum ages extend back to 1.5215 ± 0.0083 Ma, which supports the age progression of magmatism observed in the southern islands chain of the Cape Verde Archipelago. The youngest volcanic eruption period (21.14 ± 0.62 ka) occurred during the Last Glacial Maximum, a period of global sea level lowstands. We suggest that the comparatively rapid unloading leading up to the lowstand may have reduced pressure conditions within the Cadamosto Seamount magma plumbing system, and thus led to enhanced submarine eruption activity.