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  • 1
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    Geological Society of America (GSA)
    In: Geology
    Publication Date: 2016-06-30
    Description: Naturally occurring Cr(VI) has been ascribed to terrestrial Cr(III) oxidation by Mn (di)oxides, generated through reaction of Mn(II) with molecular oxygen (O 2 ). However, hydrogen peroxide (H 2 O 2 ) is a potential oxidant of Cr(III) that may form in serpentinization (high H 2 , low O 2 ) systems where chromite [i.e., the main mineralogical source of Cr(III)] is abundant. Accordingly, here we evaluate H 2 O 2 and chromite interactions in serpentinization systems to determine pathways of Cr(III) oxidation that alters the current paradigm of O 2 -dependent oxidation. Field observations support that metastable H 2 O 2 and Cr(VI) are present in serpentinization-related fluids relatively absent of O 2 . Further, laboratory experiments demonstrate and support that H 2 O 2 is a kinetically facile oxidant of chromite, especially under alkaline conditions, which provides a variety of alternative means by which Cr(VI) may be generated and supplied to the oceans not directly linked to atmospheric O 2 . Thus, Cr(III) oxidation pathways, and their influence on the Cr isotopic record, must account for anoxic Cr(III) oxidation in serpentinization systems as well as a variety of H 2 O 2 -induced Cr(III) oxidation pathways that may occur in both terrestrial and marine systems.
    Print ISSN: 0091-7613
    Electronic ISSN: 1943-2682
    Topics: Geosciences
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  • 2
    Publication Date: 2015-10-02
    Description: Numerical calculations assuming linear elasticity by Böse et al. (2014) indicate that an M w  7.75 earthquake on the Newport–Inglewood fault would cause 5 m/s of horizontal peak ground velocity (PGV) within the Los Angeles basin. However, the dynamic strain from this event would take much of the uppermost few hundred meters of basin rock beyond its frictional elastic limit. Stiff quartz-rich beds within the basin are fragile geological features that would fail and crack before the rest of the clay-rich rock mass. Repeated cracking would reduce the shear modulus of the quartz-rich beds to the level that cracking barely occurred during strong events. When interpreted in this way, data from such stiff beds near the Los Angeles International Airport indicate past PGV of ~1.6 m/s, comparable with near-field records from the strike-slip 2002 Denali and 1992 Landers earthquakes. Numerical calculations capable of representing nonlinear failure within shallow bedded rocks are warranted. Online Material: Digital ROSRINE S -wave borehole logs.
    Print ISSN: 0037-1106
    Electronic ISSN: 1943-3573
    Topics: Geosciences , Physics
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  • 3
    Publication Date: 2016-10-08
    Description: Strong Rayleigh waves are expected to bring the shallow subsurface into frictional failure. They may nonlinearly interact with high-frequency S waves. The widely applied Drucker and Prager (1952) rheology predicts that horizontal compression half-cycle of strong Rayleigh waves will increase the strength of the subsurface for S waves and predicts that S waves with dynamic accelerations 〉1 g will reach the surface. We did not observe this effect. Rather, we observed that strong high-frequency S waves arrived at times of low Rayleigh-wave particle velocity. Physically, high-frequency S waves cause failure on horizontal fractures in which Rayleigh waves do not change the normal traction. Failure then may depend on the ratio of the shear invariant to the ambient vertical stress. The shear invariant is the square root of the sum of the squares of terms proportional to the resolved horizontal velocity from Rayleigh waves and to the resolved high-frequency dynamic acceleration from S waves. That is, an ellipse should bound resolved dynamic acceleration versus resolved particle velocity. Records from seven stations from the 2011 Tohoku earthquake and El Pedregal station during the 2015 Coquimbo Chilean earthquake exhibit this expected effect of this nonlinear interaction.
    Print ISSN: 0037-1106
    Electronic ISSN: 1943-3573
    Topics: Geosciences , Physics
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  • 4
    Publication Date: 2018-02-10
    Description: Seafloor and passive margins gradually subside as a result of thermal contraction of the underlying lithosphere. Thermal subsidence is also an attractive mechanism for the Michigan basin. For subsidence to occur within this previously stable continental region, some mechanism is needed to heat the lithosphere and to reduce the buoyancy of the continental crust. Mechanical stretching of the lithosphere along with its crust does both at the same time. The ponding of plume material beneath the crust supplies heat, but does not directly thin the crust. The British Isles and the Congo basin provide analogies to the Michigan basin. Continental stretching before subsidence is evident within the British Isles and the Congo basin. Stretching is not obvious in Michigan, but undetected rifts extending from the Iapetus break-up margin may exist. A closed region of thin lithosphere beneath the Irish Sea may have trapped hot buoyant material from the Iceland plume; the Michigan basin may have trapped material from an Iapetus age plume near Montreal. Cratonic basins provide information on the tail of the subsidence curve, unlike more ephemeral oceanic crust and passive margins. The poorly resolved tails in the Michigan and the Congo basins are consistent with the time subsidence constant, c. 280 myr predicted by stagnant lid convection formalism.
    Print ISSN: 0305-8719
    Electronic ISSN: 2041-4927
    Topics: Geosciences
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  • 5
    Publication Date: 2018-02-11
    Description: Seafloor and passive margins gradually subside as a result of thermal contraction of the underlying lithosphere. Thermal subsidence is also an attractive mechanism for the Michigan basin. For subsidence to occur within this previously stable continental region, some mechanism is needed to heat the lithosphere and to reduce the buoyancy of the continental crust. Mechanical stretching of the lithosphere along with its crust does both at the same time. The ponding of plume material beneath the crust supplies heat, but does not directly thin the crust. The British Isles and the Congo basin provide analogies to the Michigan basin. Continental stretching before subsidence is evident within the British Isles and the Congo basin. Stretching is not obvious in Michigan, but undetected rifts extending from the Iapetus break-up margin may exist. A closed region of thin lithosphere beneath the Irish Sea may have trapped hot buoyant material from the Iceland plume; the Michigan basin may have trapped material from an Iapetus age plume near Montreal. Cratonic basins provide information on the tail of the subsidence curve, unlike more ephemeral oceanic crust and passive margins. The poorly resolved tails in the Michigan and the Congo basins are consistent with the time subsidence constant, c. 280 myr predicted by stagnant lid convection formalism.
    Print ISSN: 0305-8719
    Electronic ISSN: 2041-4927
    Topics: Geosciences
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  • 6
    Publication Date: 2016-12-02
    Description: Strong long-period (~3 s) seismic waves impose dynamic strains on the shallow subsurface. The dynamic strain is the dynamic velocity divided by the phase velocity of the waves. The dynamic stress is the strain times the shear modulus. A testable hypothesis is that the shear modulus of the rock self-organizes so that the rock barely fails in friction with typical imposed dynamic strains. The predicted value of stiffness divided by depth is then independent of depth for constant rock density and constant coefficient of friction with the water table at the surface. Predicted stiffness divided depth deviates from constancy for finite-water-table depth. Prior laboratory studies indicate that the coefficient of friction is lower in clay-rich rocks than in clay-free rocks. These effects provide appraisal of the concept in which hydrology and lithology are constrained. Four boreholes near Parkfield, California, qualitatively exhibit the predicted effects. There is some indication of the predicted effect of water-table depth within accumulating sediments penetrated by borehole McGlincy (MGCY) in the Santa Clara Valley of California, but the effect of clay is not well resolved, due to a dearth of clay-rich beds.
    Print ISSN: 0037-1106
    Electronic ISSN: 1943-3573
    Topics: Geosciences , Physics
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  • 7
    Publication Date: 1988-12-01
    Print ISSN: 0956-540X
    Electronic ISSN: 1365-246X
    Topics: Geosciences
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  • 8
    Publication Date: 1987-07-01
    Print ISSN: 0956-540X
    Electronic ISSN: 1365-246X
    Topics: Geosciences
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  • 9
    Publication Date: 2011-08-19
    Description: The evolution of a planetary atmosphere can be powerfully influenced by the planetary interior's function as both a source and a sink of atmospheric constituents; the interior can in turn be strongly influenced by the atmosphere because the mechanism of interior heat loss depends on a volatile content for which the atmosphere can serve both as sink and source. The dependence of mantle rheology on volatile content could furnish a feedback mechanism tending to keep regassing/degassing in balance, thereby maintaining a relatively constant atmospheric mass. Consideration of the abundances of radiogenic and nonradiogenic noble gases in the earth's atmosphere, and of the fluxes of these gases from the mantle, support a large degassing event early on, followed by a decrease in degassing efficiency with time and relatively inefficient outgassing over most of geologic time.
    Keywords: ASTROPHYSICS
    Format: text
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  • 10
    Publication Date: 2013-08-31
    Description: It has recently been suggested that a reported spike in seawater (87)Sr/(86)Sr at the K-T boundary is the signature of an impact-generated acid deluge. However, the amount of acid required is implausibly large. Some about 3 x 10 to the 15th power moles of Sr must be weathered from silicates to produce the inferred Sr spike. The amount of acid required is at least 100 and probably 1000 times greater. Production of 3 x 10 to the 18th power moles of NO is clearly untenable. The atmosphere presently contains only 1.4 x 10 to the 20th power moles of N-sub 2 and 3.8 x 10 to the 19th power moles of O sub 2 If the entire atmosphere were shocked to 2000 K and cooled within a second, the total NO produced would be about 3 x 10 to the 18th power moles. This is obviously unrealistic. A (still to short) cooling time of 10th to the 3rd power sec reduces NO production by an order of magnitude. In passing, we note that if the entire atmosphere had in fact been shocked to 2000 K, acid rain would have been the least of a dinosaur's problems. Acid rain as a mechanism poses poses other difficulties. Recently deposited carbonates would have been most susceptable to acid attack. The researchers' preferred explanation is simply increased continental erosion following ecological trauma, coupled with enchanced levels of CO-sub 2.
    Keywords: ENVIRONMENT POLLUTION
    Type: Lunar and Planetary Inst., Global Catastrophes in Earth History: An Interdisciplinary Conference on Impacts, Volcanism, and Mass Mortality; p 223-224
    Format: application/pdf
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