Publikationsdatum:
2021-10-29
Beschreibung:
The stereoselective Suzuki–Miyaura cross-coupling of (Z)-β-enamido triflates is demonstrated. Depending on the nature of the ligand in the palladium catalyst, either retention or inversion of the configuration during the synthesis of β,β-diaryl-substituted enamides is observed. Thus, the method provides synthetic access to both isomers of the target enamides from (Z)-β-enamido triflates.
Print ISSN:
2195-951X
Digitale ISSN:
1860-5397
Thema:
Chemie und Pharmazie
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