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  • 1
    Publication Date: 2023-01-04
    Description: Highlights • UAV-based thermal imaging allows precise mapping of diffusive thermal water discharge. • High tidal ranges affect fluid flow and promote larger thermal anomaly. • The La Jolla thermal anomaly is caused by a discharge of 330 ± 44 L s−1 of thermal water. • The La Jolla advective heat output (40.5 ± 5.2 MWt) can power a desalinization plant. The exploration of unexploited geothermal resources is required to encourage the use of renewable energy. This study focuses on La Jolla beach, Ensenada, Mexico. The beach hosts a thermal anomaly with temperatures of up to 52 °C at the surface and up to 93 °C at 20 cm depth. The objectives were to: map the thermal anomaly, understand the impact of tides, quantify the thermal water discharge rate and heat output, and discuss a direct use of the energy. The mapping was performed with Unmanned Aerial Vehicles equipped with optical and thermal cameras at two different dates. Additional temperature measurements were performed with a thermocouple, while the total fluid discharge was estimated from flow measurements. A comparison between the campaigns indicated that the highest surface temperature area was more than three times larger in 2019 than in 2018 (259 m2 vs. 69 m2). Such change was due to the tidal range and associated hydrostatic pressure variations. The total thermal water discharge is 330 ± 44 L s−1, which corresponds to an advective heat output of 40.5 ± 5.2 MWt. The use of this energy in a Multi-Effect Distillation desalinization plant can contribute to cover the shortage of freshwater in Ensenada.
    Type: Article , PeerReviewed
    Format: text
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  • 2
    Publication Date: 2023-10-25
    Description: Boron (B) and Lithium (Li) concentrations were studied in the Platani river, one of the most important catchments of South-Central Sicily which is under semiarid climatic conditions for roughly eight months to a year. In this area, evaporites result in potential B and Li sources for surface waters. Results from river waters have measured ionic strength values between 0.1 and 4.54 M. B and Li distributions in these waters were studied in colloidal (CF, extracted by ultrafiltration from the 0.45 μm filtrate) and total dissolved (TDF) fractions and in fractions extracted from corresponding riverbed sediments, according to changes of the B/Li ratio. In river waters, CF and TDF showed very similar B/Li values, suggesting that only negligible fractionation occurs between Li and B in the aqueous phase. Similar evidence was observed between B/Li values in TDF and the labile sediment fraction, whereas an inverse relationship arose between B/Li values in TDF and in the easily reducible sediment fraction. This relationship indicates that Mn oxy-hydroxides preferentially react with aqueous B species relative to Li at the riverbed sediment interface. The extent of the B-Mn oxy-hydroxide reactions is influenced by the ionic strength, so that only B/Li values below 4 are measured in river waters with ionic strength values above 0.5 M. Comparing B/Li and ionic strength values measured in the Platani river with those from oxic brines worldwide, the same preferential B removal relative to Li is observed. This evidence suggests that B is removed as positively-charged borate ion-pairs, formed in the aqueous phase under higher ionic strength conditions, reacting with negatively charged surfaces of Mn oxy-hydroxides. The observed B reactivity relative to Li could be exploited to bring down the B excess from natural or waste waters, allowing the natural reactions with Mn oxy-hydroxides to take place under natural conditions.
    Description: Published
    Description: 135509
    Description: 1T. Struttura della Terra
    Description: JCR Journal
    Keywords: B/Li ratio; Ionic strength; Mine drainage; Mn-oxyhydroxides; Salt minerals
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2023-03-02
    Description: The physicochemical and isotopic characteristics of groundwater and dissolved gas of central Mexico provide valuable information about the geologic and tectonic context of the area. Low–high-enthalpy manifestations (up to 98 °C in springs and more than 100 °C in geothermal wells) are distributed within the San Juan del Río, Querétaro, and Celaya hydrologic basins, located at the boundary between the current Mexican magmatic arc and an extensional continental area with intraplate volcanism called Mesa Central Province. Groundwaters in the study area represent a mixture between the cold water end-member with a Ca2+-Mg2+-HCO3- composition and a hydrothermal end-member enriched in Na+ , K+ , SO4 2−, and Cl-. Cold and hot groundwaters δ2 H and δ18O plot along the same evaporation lines and do not exhibit a magmatic input. Dissolved and free gas do not show a typical volcanic composition signature. He and Ne isotope composition provide evidence of an important contribution of non-atmospheric noble gases. Although helium composition mainly has a crustal origin (21–83%), the mantellic contribution (1–39%) is higher than expected for an area lacking recent volcanism. A volatile-rich magma aging at depth was discarded as the source of this mantellic helium signature but points out a recent mantellic contribution. Thus, we propose that mantellic helium comes from the sublithospheric mantle into the shallow crust through the highly permeable tectonic boundaries between the geologic provinces, namely the N−S Taxco−San Miguel de Allende and ChapalaTula fault systems. Mantellic helium flow rates through these fault systems were estimated to have values ranging from 0.1 m/yr to 2.9 m/yr. This He flux range implies that aside from subduction, mantle volatile degassing enhanced by crustal fault systems is the main degassing process in the region studied.
    Description: Published
    Description: 335–347
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2023-06-19
    Description: The volatiles released by the volcanic structures of the world contribute to natural environmental pollution both during the passive and active degassing stages. The Island of Vulcano is characterized by solfataric degassing mainly localized in the summit part (Fossa crater) and in the peripheral part in the Levante Bay. The normal solfataric degassing (high-temperature fumarolic area of the summit and boiling fluids emitted in the Levante Bay area), established after the last explosive eruption of 1888–90, is periodically interrupted by geochemical crises characterized by anomalous degassing that are attributable to increased volcanic inputs, which determine a sharp increase in the degassing rate. In this work, we have used the data acquired from the INGV (Istituto Nazionale di Geofisica e Vulcanologia) geochemical monitoring networks to identify, evaluate, and monitor the geochemical variations of the extensive parameters, such as the SO2 flux from the volcanic plume (solfataric cloud) and the CO2 flux from the soil in the summit area outside the fumaroles areas. The increase in the flux of volatiles started in June–July 2021 and reached its maximum in November of the same year. In particular, the mean monthly flux of SO2 plume of 22 tons day−1 (t d−1) and of CO2 from the soil of 1570 grams per square meter per day (g m2 d −1) increased during this event up to 89 t d−1 and 11,596 g m2 d −1, respectively, in November 2021. The average annual baseline value of SO2 output was estimated at 7700 t d−1 during normal solfataric activity. Instead, this outgassing increased to 18,000 and 24,000 t d−1 in 2021 and 2022, respectively, indicating that the system is still in an anomalous phase of outgassing and shows no signs of returning to the pre-crisis baseline values. In fact, in the first quarter of 2023, the SO2 output shows average values comparable to those emitted in 2022. Finally, the dispersion maps of SO2 on the island of Vulcano have been produced and have indicated that the areas close to the fumarolic source are characterized by concentrations of SO2 in the atmosphere higher than those permitted by European legislation (40 µg m−3 for 24 h of exposition) on human health.
    Description: This research was funded by the INGV-DPCN (Italian National Institute of Geophysics and Volcanology-Italian National Department for Civil Protection) volcanic surveillance program of Vulcano island, ObFu 0304.010. Moreover, this investigation was partially funded by TORS project in the framework of institutional INGV projects (“Ricerca Libera”, ObFu 9999.549 and Pianeta Dinamico Task V2, ObFu 1020.010).
    Description: Published
    Description: 3086
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: SO2 output ; Soil CO2 fluxes ; Air pollutant ; Vulcano Island ; Geochemical crisis ; Summit degassing ; SO2 map dispersion ; Extensive parameters ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Publication Date: 2024-03-20
    Description: Volcanic lakes are complex natural systems and their chemical composition is related to a myriad of processes. The chemical composition of major, minor, Rare Earth Elements (REE) and physico-chemical parameters at the hyperacid crater lake of Rincón de la Vieja volcano (Costa Rica) are here investigated during February 2013–August 2014. The study of the lake chemical composition allows to identify the main geochemical processes occurring in the lake and to track the changes in the volcanic activity, both important for active volcanoes monitoring. The total REE concentration ( REE) dissolved in the crater lake varies from 2.7 to 3.6 mg kg−1 during the period of observation. REE in the water lake samples normalized to the average volcanic local rock (REEN-local rock) are depleted in light REE (LREE). On the contrary REEN-local rock in the solids precipitated (mainly gypsum/anhydrite), from lake water samples in laboratory at 22°C, are enriched in LREE. The low variability of (La/Pr)N-local rock and (LREE/ HREE)N-local rock ratios (0.92–1.07 and 0.66–0.81, respectively) in crater lake waters is consistent with the low phreatic activity (less than 10 phreatic eruptions in 2 years) observed during the period of observation. This period of low activity precedes the unrest started in 2015, thus, it could be considered as a pre-unrest, characterized by infrequent phreatic eruptions. No clear changes in the REE chemistry are associated with the phreatic eruption occurred at mid- 2013. The results obtained investigating water-rock interaction processes at theRincón de la Vieja crater lake show that rock dissolution and mineral precipitation/ dissolution are the main processes that control the variability of cations composition over time. In particular, precipitation and dissolution of gypsum and alunite are responsible for the variations of REE in the waters. Despite the low variations of (La/Pr)N-local rock and (LREE/HREE)N-local rock ratios, this study allows to suggest that REE can be used, together with major elements, as practical tracers of water-rock interaction processes and mineral precipitation/ dissolution at active hyperacid crater lakes over time, also during periods of quiescence and low phreatic activity.
    Description: Published
    Description: 1197568
    Description: OSV3: Sviluppo di nuovi sistemi osservazionali e di analisi ad alta sensibilità
    Description: JCR Journal
    Keywords: Rare earth elements ; hyperacid crater lake ; geochemical monitoring ; sulfate minerals ; water-rock interaction
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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