ALBERT

Description: Highlights • Five Pleistocene and Holocene explosive eruptions of Mt. Erciyes dated. • Holocene Dikkartın and Perikartın pumices chemically equal Mediterranean S1 tephra. • Karagüllü dome eruption identified as the source of a Black Sea cryptotephra. • Eastward dispersal of Dikkartın fall-out consistent with probabilistic modeling. • Southerly S1 tephra occurrence suggests low altitude ash dispersal from Mt. Ericyes. Abstract Deposition of early Holocene Eastern Mediterranean S1 tephra and a Black Sea cryptotephra coincides with cultural transitions in the Fertile Crescent termed the Neolithic Revolution as well as sapropel formation during climate variability of the African humid period, classifying them as paramount regional marker horizons for archaeology as well as paleoclimatology. Their correlations with specific eruptions of the Mt. Erciyes stratovolcanic complex (Central Anatolia) remained inconclusive though. Here, we use zircon double-dating by (U–Th)/He and U–Th disequilibrium methods, major and trace element tephra glass geochemistry, and probabilistic modeling of tephra dispersal in an attempt to characterize all major late Quaternary proximal tephras of Mt. Erciyes, and to correlate them with distal deposits. Furthermore, we discuss contrasting proximal and distal tephra dispersal. Three nearly-coeval rhyolitic satellite domes (Dikkartın, Perikartın, and Karagüllü) erupted at Mt. Erciyes in the early Holocene, and their dome extrusions were all preceded by explosive phases producing pyroclastic material that formed tephra fall and pyroclastic flow deposits. The new eruption age of 9.03 ± 0.55 ka (1σ uncertainty here and elsewhere) for proximal Dikkartın pumice is consistent with 14C-based S1 tephra chronologies in distal locations averaging 8.92 ± 0.03 cal ka BP. Perikartın pyroclastic flow deposits predate S1 tephra by ca. 0.8 ka according to a pair of published 14C ages, and stratigraphically overlie Karagüllü fall-out, here dated to 8.2 ± 1.8 ka. Previously undated proximal tephras of Mt. Erciyes erupted in the Late (85.2 ± 4.9 ka) and Middle Pleistocene (154.5 ± 5.3 ka). S1 tephra glass is chemically similar to that of Dikkartın fall-out, but also indistinguishable from that of Perikartın fall-out. Karagüllü pumice is characterized by a distinct glass chemical composition, which correlates with that of unnamed cryptotephra reported for the southeastern Black Sea instead, where these results call for a re-evaluation of existing age models. Maximum lithic clast size isopleths for proximal Dikkartın fall-out indicate eastward dispersal of a 20 ± 5 km high eruption plume by stratospheric winds, in agreement with results of probabilistic tephra dispersal modeling. This azimuth contrasts with the known distribution of S1 tephra at distal locations that are all south of Mt. Erciyes. Significant tephra occurrences at up to 1300 km distance and orthogonal to prevalent stratospheric wind directions either result from very atypical wind conditions (probability ≪10 %), or are caused by tephra transport by prevailing low altitude winds. Two scenarios are proposed for low altitude transport: eolian reworking of primary fall-out (more likely from the more widespread Dikkartın deposits), or co-ignimbrite ash cloud dispersal (more likely from the Perikartın eruption which predominantly produced pyroclastic flows). Because S1 tephra is chemically indistinguishable from both Dikkartın and Perikartın by major and trace element glass compositions, its exact source and dispersal mechanism remain ambiguous, although existing 14C ages for Perikartın predating those for S1 tephra favor Dikkartın as its source.

Description: The transfer of vast amounts of carbon from a deep oceanic reservoir to the atmosphere is considered to be a dominant driver of the deglacial rise in atmospheric CO2. Paleoceanographic reconstructions reveal evidence for the existence of CO2-rich waters in the mid to deep Southern Ocean. These water masses ventilate to the atmosphere south of the Polar Front, releasing CO2 prior to the formation and subduction of intermediate-waters. Changes in the amount of CO2 in the sea water directly affect the oceanic carbon chemistry system. Here we present B/Ca ratios, a proxy for delta carbonate ion concentrations Δ[CO32−], and stable isotopes (δ13C) from benthic foraminifera from a sediment core bathed in Antarctic Intermediate Water (AAIW), offshore New Zealand in the Southwest Pacific. We find two transient intervals of rising [CO32−] and δ13C that that are consistent with the release of CO2 via the Southern Ocean. These intervals coincide with the two pulses in rising atmospheric CO2 at ~ 17.5–14.3 ka and 12.9–11.1 ka. Our results lend support for the release of sequestered CO2 from the deep ocean to surface and atmospheric reservoirs during the last deglaciation, although further work is required to pin down the detailed carbon transfer pathways.

Description: The Koudiat Aïcha Zn-Cu-Pb deposit (3–Mt ore @ 3 wt.% Zn, 1 wt.% Pb, 0.6 wt.% Cu) in the Jebilet massif (Morocco) comprises stratabound lenticular orebodies and crosscutting sulfide-bearing quartz ± carbonate veins in the lower Carboniferous Sarhlef volcano sedimentary succession. The veins are characterized by abundant pyrrhotite, sphalerite, subordinate chalcopyrite and galena and rare Ag and Au minerals. The stratabound massive sulfide ores are attributed to a “VMS” type, whereas the origin of the sulfide–quartz ± carbonate veins remains poorly understood. New mineralogical and microanalytical data (SEM, EPMA and LA-ICP-MS) combined with fluid inclusion results point to two-stage vein formation. The early stage involved C–H–O–N Variscan metamorphic fluids which percolated through fractures and shear zones and deposited pyrite at 〉400 °C, followed by the formation of pyrrhotite and sphalerite (300 ± 20 °C) in quartz veins and in banded and breccia ores. The pyrrhotite–sphalerite mineralization was overprinted by aqueous brines (34 to 38 wt% eq. NaCl + CaCl2) that precipitated carbonate and Cu-Pb sulfides (±Ag-Au) at ~180–210 °C through mixing with low-salinity fluids during tectonic reworking of early-formed structures and in late extension fractures. The latter ore fluids were similar to widspread post-Variscan evaporitic brines that circulated in the Central Jebilet. Overlapping or successive pulses of different ore fluids, i.e., metamorphic fluids and basinal brines, led to metal enrichment in the quartz–carbonate veins compared to the massive sulfide ores. These results underscore that even a single deposit may record several distinct mineralizing styles, such that the ultimate metal endowment may be cumulative over multiple stages.

Description: Here we show how surface sediment samples from ten locations from the Pacific Sector of the Southern Ocean and the downcore LGM to Holocene carbonate system of intermediate water sediment record PS75/104-1 offshore New Zealand. We measured foraminiferal B/Ca ratios via laser ablation-inductively coupled-mass spectrometry (LA-ICP-MS) and used the calibration of Yu et al. (2013) for Cibicidoides wuellerstorfi and Ronge et al. (under review) for C. dispars. Measurements were conducted at the GEOMAR in Kiel in 2013.

Description: Here we show the downcore LGM to Holocene carbonate system of intermediate water sediment record PS75/104-1 offshore New Zealand. We measured foraminiferal B/Ca ratios via laser ablation-inductively coupled-mass spectrometry (LA-ICP-MS) and used the calibration of Yu et al. (2013) for Cibicidoides wuellerstorfi and Ronge et al. (under review) for C. dispars. Measurements were conducted at the GEOMAR in Kiel in 2013.

Description: Here we show surface sediment samples from ten locations from the Pacific Sector of the Southern Ocean (~44°S-48°S; ~174°E-116°W). We measured foraminiferal B/Ca ratios via laser ablation-inductively coupled-mass spectrometry (LA-ICP-MS) on Cibicidoides dispars, a species that is abundant in most samples of the Pacific sector of the Southern Ocean. Measurements were conducted at the GEOMAR in Kiel in 2013.

Description: Here we show the downcore LGM to Holocene carbonate system of intermediate water sediment record PS75/104-1 offshore New Zealand. We measured foraminiferal B/Ca ratios via laser ablation-inductively coupled-mass spectrometry (LA-ICP-MS) and used the calibration of Yu et al. (2013) for Cibicidoides wuellerstorfi and Ronge et al. (under review) for C. dispars. Measurements were conducted at the GEOMAR in Kiel in 2013.