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  • 1
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    Natural hypoxic conditions do not affect the respiration rates of the cold-water coral Desmophyllum pertusum (Lophelia pertusa) living in the Angola margin (Southeastern Atlantic Ocean) (2023)
    Elsevier
    Details
    Publication Date: 2024-02-07
    Description: Highlights: • The cold-water coral Desmophyllum pertusum from reefs off Angola showed the same respiration rates at hypoxic and normoxic oxygen concentration. • The respiration rates measured are in the same order of magnitude as those previously observed for the species under normoxic conditions in other areas. Abstract: Large, well-developed and flourishing reefs dominated by the cold-water coral Desmophyllum pertusum have recently been discovered along the Angola margin in the southeastern Atlantic Ocean living under very low oxygen concentrations (0.6–1.5 mL L−1). This study assessed the respiration rates of this coral in a short-term (10 days) aquarium experiment under naturally low oxygen concentrations (1.4 ± 0.5 mL L−1) as well as under saturated oxygen concentrations (6.1 ± 0.6 mL L−1). We found no significant difference in respiration rates between the two oxygen concentrations. Furthermore, the respiration rates of D. pertusum were in the same order of magnitude as those of the same species living under normoxic conditions in other areas. This work expands the current knowledge on the metabolic activity of cold-water corals under hypoxic conditions, evidencing that low oxygen conditions are not a general limiting factor for the overall distribution of D. pertusum.
    Type: Article , PeerReviewed
    Format: text
    Format: other
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  • 2
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    Dehalogenation of α-hexachlorocyclohexane by iron sulfide nanoparticles: Study of reaction mechanism with stable carbon isotopes and pH variations (2021)
    Elsevier
    Details
    Publication Date: 2021-12-01
    Print ISSN: 0048-9697
    Electronic ISSN: 1879-1026
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Published by Elsevier
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  • 3
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    Hydrogeochemical multi-component approach to assess fluids upwelling and mixing in shallow carbonate-evaporitic aquifers (Contursi area, southern Apennines, Italy) (2023)
    Elsevier
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    Publication Date: 2023-04-04
    Description: With the aim of deepening our understanding of deep-seated fluids upwelling and mixing in large regional aquifers, we performed a hydrogeochemical study of twenty-two springs in the Contursi area (upper Sele river valley, southern Apennines) by means of the measurements of chemical-physical parameters, major ions, trace elements, and stable and radioactive isotopes. Besides, we realized two updated geo-structural cross-sections inorder to reconstruct the groundwater flowpath in the study area. The hydrogeochemical composition, as well a the water temperature allow to identify-three main groups of groundwater: Cold and Low salinity Groundwater (CLGW), Intermediate Salinity Groundwater (ISGW), and Thermal Salinity Groundwater (TSGW). The CLGW group, mostly emerging at the boundary of carbonate aquifers, is characterized by alkaline earth-bicarbonate hydrofacies. Instead, ISGW and TSGW, situated in the inner zone of the valley, show gradually a hydrogeochemical evolution towards sodium-chloride type hydrofacies domain with the highest salinity value. Stable isotope (δ18O-δD) of CLGW reveal the local meteoric origin of groundwater, while isotopic signatures of ISGW and TSGW is associated with the deep fluids inflow. CLGW hydrogeochemistry is clearly related to dissolution of carbonate rocks. On the other hand, for ISGW and TSGW an additional contribution from evaporitic rocks is supported by saturation indices values (gypsum and anhydrite) and validated by isotopic signature of dissolved sulphate (δ34S-δ18O). The application of two models based on tritium data (i.e., the piston-flow and well-mixed reservoir) attributes longer and deeper groundwater flowpaths to TSGW. Through geothermometric calculations (e,g., K-Mg and SiO2-quartz), the equilibrium temperature of deep fluids reservoir is also extrapolated (i.e., 75–96 ◦C). The results of the adopted hydrogeochemical multi-component approach allowed us to propose an interpretative model of groundwater flowpath for the Contursi area, where deep-seated tectonic discontinuities play a significant role for the upwelling of saline deep thermal fluids in shallow aquifers.
    Description: Published
    Description: 129258
    Description: 9T. Geochimica dei fluidi applicata allo studio e al monitoraggio di aree sismiche
    Description: JCR Journal
    Keywords: fluids ; earthquakes ; crust ; geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
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    A site-specific earthquake ground response analysis using a fault-based approach and nonlinear modeling: the Case Pente site (Sulmona, Italy) (2022)
    Elsevier
    Details
    Publication Date: 2023-01-17
    Description: In this paper we present the ground response analyses (GRA) of a site where an industrial facility is planned. Because of its location on an active normal fault system known as a relevant seismic gap, the Mt. Morrone Fault system (MMF), and at the edge of a basin filled with slow velocity continental deposits, a inter-disciplinary and non-standard approach has been applied to assess the seismic input of the dynamic numerical analyses. It includes geological, seismological, geotechnical and engineering contributions. Two fault scenarios, MMF1 and MMF2, were considered and scenario-based (SSHA) and probabilistic (time-dependent, TD, and time-independent, TI) seismic hazard (PSHA) analyses were implemented. Comparison among the spectra corresponding to the 90th percentile of the SSHA statistical distribution and the PSHA average ones, shows that the MMF2 has values similar to the TD model. The SSHA 90th percentile distribution was selected as target spectra to retrieve the seismic input for GRA. Nonlinear numerical simulations of seismic wave propagation were implemented to derive surface ground motion parameters. GRA acceleration response spectra and their PGA are notably higher, and thus on the safety site, than those obtained following the Italian code approach for seismic resistant buildings. These results confirm that a scenario-based methodology can better capture the shaking effect in near-field conditions, avoiding possibly unconservative underestimations of the seismic actions and in view of a more robust performance-based approach used by engineers for either new design and/or assessment/retrofit purposes of the built environment.
    Description: Published
    Description: 106970
    Description: 5T. Sismologia, geofisica e geologia per l'ingegneria sismica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
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    Regulation of deep carbon degassing by gas-rock-water interactions in a seismic region of Southern Italy (2024)
    Elsevier
    Details
    Publication Date: 2024-01-08
    Description: This study is focused on fluids characterization and circulations through the crust of the Irpinia region, an active seismic zone in Southern Italy, that has experienced several high-magnitude earthquakes, including a catastrophic one in 1980 (M = 6.9 Ms). Using isotopic geochemistry and the carbon‑helium system in free and dissolved volatiles in water, this study aims to explore the processes at depth that can alter pristine chemistry of these natural fluids. Gas-rock-water interactions and their impact on CO2 emissions and isotopic composition are evaluated using a multidisciplinary model that integrates geochemistry and regional geological data. By analyzing the He isotopic signature in the natural fluids, the release of mantle-derived He on a regional scale in Southern Italy is verified, along with significant emissions of deep-sourced CO2. The proposed model, supported by geological and geophysical constraints, is based on the interactions between gas, rock, and water within the crust and the degassing of deep-sourced CO2. Furthermore, this study reveals that the Total Dissolved Inorganic Carbon (TDIC) in cold waters results from mixing between a shallow and a deeper carbon endmember that is equilibrated with carbonate lithology. In addition, the geochemical signature of TDIC in thermal carbon-rich water is explained by supplementary secondary processes, including equilibrium fractionation between solid, gas, and aqueous phases, as well as sinks such as mineral precipitation and CO2 degassing. These findings have important implications for developing effective monitoring strategies for crustal fluids in different geological contexts and highlight the critical need to understand gas-water-rock interaction processes that control fluid chemistry at depths that can affect the assessment of the CO2 flux in atmosphere. Finally, this study highlights that the emissions of natural CO2 from the seismically active Irpinia area are up to 4.08·10+9 mol·y-1, which amounts is in the range of worldwide volcanic systems.
    Description: Published
    Description: 165367
    Description: OST3 Vicino alla faglia
    Description: OST5 Verso un nuovo Monitoraggio
    Description: JCR Journal
    Keywords: CO(2) output; Carbon isotopes; Degassing; Earthquakes; Noble gases; Precipitation ; 04.04 Solid Earth ; 01.01. Atmosphere ; 03.01. General ; 03.02. Hydrology ; 04.06. Seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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