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  • 2020-2024  (28)
  • 1980-1984  (29)
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  • 1
    Call number: 94.0138
    In: Dissertation / Eidgenössische Technische Hochschule Zürich
    Pages: 253 S.
    Series Statement: Dissertation / Eidgenössische Technische Hochschule Zürich 7612
    Classification:
    Regional Geology
    Language: German
    Branch Library: GFZ Library
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  • 2
    Monograph available for loan
    Monograph available for loan
    Berlin : Verl. Technik
    Associated volumes
    Call number: G 8187
    In: Reihe Automatisierungstechnik
    Type of Medium: Monograph available for loan
    Pages: 76 S. : graph. Darst.
    Edition: 1. Aufl.
    Series Statement: Reihe Automatisierungstechnik 197
    Location: Upper compact magazine
    Branch Library: GFZ Library
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  • 3
    Publication Date: 2023-06-21
    Description: The GPS satellite transmitter antenna phase center offsets (PCOs) can be estimated in a global adjustment by constraining the ground station coordinates to the current International Terrestrial Reference Frame (ITRF). Therefore, the derived PCO values rest on the terrestrial scale parameter of the frame. Consequently, the PCO values transfer this scale to any subsequent GNSS solution. A method to derive scale-independent PCOs without introducing the terrestrial scale of the frame is the prerequisite to derive an independent GNSS scale factor that can contribute to the datum definition of the next ITRF realization. By fixing the Galileo satellite transmitter antenna PCOs to the ground calibrated values from the released metadata, the GPS satellite PCOs in the z-direction (z-PCO) and a GNSS-based terrestrial scale parameter can be determined in GPS + Galileo processing. An alternative method is based on the gravitational constraint on low earth orbiters (LEOs) in the integrated processing of GPS and LEOs. We determine the GPS z-PCO and the GNSS-based scale using both methods by including the current constellation of Galileo and the three LEOs of the Swarm mission. For the first time, direct comparison and crosscheck of the two methods are performed. They provide mean GPS z-PCO corrections of −186 ± 25 mm and −221 ± 37 mm with respect to the IGS values and +1.55 ± 0.22 ppb (parts per billion) and +1.72 ± 0.31 in the terrestrial scale with respect to the IGS14 reference frame. The results of both methods agree with each other with only small differences. Due to the larger number of Galileo observations, the Galileo-PCO-fixed method leads to more precise and stable results. In the joint processing of GPS + Galileo + Swarm in which both methods are applied, the constraint on Galileo dominates the results. We discuss and analyze how fixing either the Galileo transmitter antenna z-PCO or the Swarm receiver antenna z-PCO in the combined GPS + Galileo + Swarm processing propagates to the respective freely estimated z-PCO of Swarm and Galileo.
    Description: Chinese Government Scholarship http://dx.doi.org/10.13039/501100010890
    Description: Helmholtz-Zentrum Potsdam Deutsches GeoForschungsZentrum - GFZ (4217)
    Keywords: ddc:526 ; GNSS ; PCO ; Galileo ; Terrestrial scale ; LEOs
    Language: English
    Type: doc-type:article
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  • 4
    Publication Date: 2023-06-16
    Description: The use of the GLONASS legacy signals for real-time kinematic positioning is considered. Due to the FDMA multiplexing scheme, the conventional CDMA observation model has to be modified to restore the integer estimability of the ambiguities. This modification has a strong impact on positioning capabilities. In particular, the ambiguity resolution performance of this model is clearly weaker than for CDMA systems, so that fast and reliable full ambiguity resolution is usually not feasible for standalone GLONASS, and adding GLONASS data in a multi-GNSS approach can reduce the ambiguity resolution performance of the combined model. Partial ambiguity resolution was demonstrated to be a suitable tool to overcome this weakness (Teunissen in GPS Solut 23(4):100, 2019). We provide an exhaustive formal analysis of the positioning precision and ambiguity resolution capabilities for short, medium, and long baselines in a multi-GNSS environment with GPS, Galileo, BeiDou, QZSS, and GLONASS. Simulations are used to show that with a difference test-based partial ambiguity resolution method, adding GLONASS data improves the positioning performance in all considered cases. Real data from different baselines are used to verify these findings. When using all five available systems, instantaneous centimeter-level positioning is possible on an 88.5 km baseline with the ionosphere weighted model, and on average, only 3.27 epochs are required for a long baseline with the ionosphere float model, thereby enabling near instantaneous solutions.
    Description: Helmholtz-Zentrum Potsdam Deutsches GeoForschungsZentrum - GFZ (4217)
    Description: https://saegnss2.curtin.edu/ldc/
    Description: ftp://cddis.gsfc.nasa.gov/gnss/data/
    Description: ftp://ftp.gfz-potsdam.de/GNSS/products/mgex/
    Keywords: ddc:526 ; RTK ; GLONASS FDMA ; Integer ambiguity resolution ; Partial fixing ; Difference test ; Best integer equivariant estimation ; Multi-GNSS
    Language: English
    Type: doc-type:article
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  • 5
    Publication Date: 2024-04-20
    Description: 79 potential endocrine disrupting chemicals (EDCs) were investigated in 56 effluent samples from 52 European wastewater treatment plants (WWTPs). The samples were collected between August 2017 and April 2019, using on-site large volume solid phase extraction (LVSPE) (Schulze et al., 2017). Chemical target analysis by liquid chromatography high-resolution and tandem mass spectrometry (LC-HRMS and LC-MS/MS, respectively) resulted in 56 detected compounds. Different capacities and conventional treatment technologies, as well as two advanced treatment technologies are included. One sample was taken at a WWTP with activated carbon treatment. Three WWTPs applying ozonation were sampled before and after this treatment step, providing two samples each. One of these WWTPs had already been sampled before the upgrade, resulting in a total of 56 (52+4) samples. More information can be found in Finckh et al. (2022). The two main objectives of this study were (i) to compare three different receptor-based estrogenicity assays (ERα-GeneBLAzer, p-YES, ERα-CALUX®), and (ii) to investigate a combined approach of chemical target analysis and receptor-based testing for estrogenicity, glucocorticogenic activity, androgenicity and progestagenic activity (ERα-, GR-, AR- and PR-GeneBLAzer assays, respectively) in treated wastewater.
    Keywords: advanced treatment technologies; androgens; chemical analysis; chemical concentration; EDC; effect-based analysis; endocrine disrupting chemicals; estrogens; Europe; glucocorticoids; LC-HRMS; LC-MS/MS; organic micropollutants; progestagens; receptor-based analysis; treated wastewater; wastewater treatment plant; water quality; WWTP
    Type: Dataset
    Format: application/vnd.openxmlformats-officedocument.spreadsheetml.sheet, 42 kBytes
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  • 6
    Publication Date: 2024-04-20
    Description: 499 emerging chemicals (ECs) were investigated in 56 effluent samples from 52 European wastewater treatment plants (WWTPs). The samples were collected between August 2017 and April 2019, using on-site large volume solid phase extraction (LVSPE) (Schulze et al., 2017). Chemical target screening by liquid chromatography high-resolution mass spectrometry (LC-HRMS) resulted in 366 detected compounds. Different capacities and conventional treatment technologies, as well as two advanced treatment technologies are included. One sample was taken at a WWTP with activated carbon (AC) treatment. Three WWTPs applying ozonation were sampled before and after this treatment step, providing two samples each. One of these WWTPs had already been sampled before the upgrade, resulting in a total of 56 (52+4) samples. More information can be found in Finckh et al. (2022). The two main objectives were (1) to extend our knowledge on chemicals occurring in treated wastewater, and (2) to identify and prioritize compounds of concern based on three different risk assessment approaches for the identification of consensus mixture risk drivers of concern.
    Keywords: advanced treatment technologies; chemical concentration; chemicals of emerging concern; chemical target screening; emerging chemicals; emerging contaminants; emerging pollutants; Europe; LC-HRMS; liquid chromatography high-resolution mass spectrometry; organic micropollutants; wastewater treatment plant
    Type: Dataset
    Format: application/vnd.openxmlformats-officedocument.spreadsheetml.sheet, 287.5 kBytes
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  • 7
    Publication Date: 2024-04-20
    Description: Plant protection products in the environment are partly responsible for the progressive loss of biodiversity. The mostly insufficient ecological status of surface waters is often explained by habitat degradation and excessive nutrient input. But what role do plant protection products play in this context? The Kleingewässermonitoring (KgM) project provides a worldwide unique quantitative assessment of the impact of pesticides from diffuse agricultural sources on small and medium-sized streams. The dataset comprises 124 monitoring stream sections all over Germany covering a wide pollution gradient where consistent measurements were carried out in 2018 and 2019 during the major pesticide application period from April to July. These measurements include event-driven sampling to record surface rainfall-induced short-term peak concentrations in addition to regular grab sampling of pesticides and a wide range of other pollutants resulting in more than 1,000 water samples. All further relevant anthropogenic and environmental parameters reigning ecological stream quality were recorded comprehensively (morphological and stream bed structure, temperature, flow velocity, dissolved oxygen, pH, catchment land use, stream profile). The dataset also contains effect monitoring data featuring sampled invertebrate communities and bioassay analyses of water samples. The data enables an assessment of pesticide exposure and related effects as well as the analysis of complex causal relationships in streams.
    Keywords: Germany; KgM; KgM_2018; KgM_2019; Kleingewässermonitoring; MULT; Multiple investigations
    Type: Dataset
    Format: application/zip, 52.3 MBytes
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  • 8
    Publication Date: 2024-04-20
    Description: The data file contains measured environmental concentrations of organic micropollutants in European streams and additional hydrological parameters (stream order, urban discharge fraction) of the investigated sites. A total of 445 surface water samples were collected during various sampling campaigns between 2016 and 2019. Chemical target screening of 610 compounds by liquid chromatography high-resolution mass spectrometry (LC-HRMS) resulted in 504 detected compounds. The measured environmental concentrations of the detected compounds ranged from 1 ng/L to 74 µg/L (3-cyclohexyl-1,1-dimethylurea). Detection frequencies ranged from one site (0.2 %) to 339 sites (76 %). More information can be found in Finckh and Carmona et al. (2024) DOI: 10.1016/j.envint.2023.108371. The main objective of this study was to quantify and characterise chemical footprints in European streams.
    Keywords: chemical footprint; chemicals of emerging concern; chemical target screening; Europe; freshwater contamination; LC-HRMS; measured environmental concentration; organic micropollutants; risk quotient; surface water; toxic unit; treated wastewater; WWTP
    Type: Dataset
    Format: application/vnd.openxmlformats-officedocument.spreadsheetml.sheet, 319.8 kBytes
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  • 9
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 103 (1981), S. 6319-6323 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Journal of molecular evolution 15 (1980), S. 231-238 
    ISSN: 1432-1432
    Keywords: β-structure ; Poly-DL-peptides ; Kinetics of hydrolysis ; Enantiomer enrichment
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Summary It was previously shown that nuclei ofβ-sheets surrounded by unordered segments are formed in polypeptide chains built up with alternating hydrophobic and hydrophilic residues and containing both L- and D-enantiomers. It was also established that segments of residues having the same configuration tend to segregate in these nuclei when the starting composition of stereomonomers departs from the racemic mixture. Soft acidic hydrolysis of these polymers has been studied. Kinetic measurements show two pseudo first order rate constants, in agreement with the existence of two conformational species. The unordered part of the chains is hydrolyzed more rapidly, allowing the isolation of aβ-fraction enriched in one enantiomer. Thus, a plausible process of enrichment in enantiomer during prebiotic evolution has been described, which however does not explain the preference of one enantiomer over the other one.
    Type of Medium: Electronic Resource
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