ALBERT

Description: Potassium feldspars (KAlSi3O8) are ubiquitous minerals in the Earth's upper crust. This family of minerals has been the subject of numerous experimental and theoretical investigations concerning their dissolution kinetics and the mechanisms controlling chemical alteration at acid and neutral pH, and at temperatures ranging from ambient to hydrothermal conditions. On the other hand, considerably less research on the dissolution behavior of K-feldspars has been carried out at alkaline conditions, in particular at pH 〉 9 and elevated temperatures. Filling in this gap in knowledge is the major motivation for this study. More specifically, we wanted to document and understand how the K-feldspar interface structurally and chemically evolves during alteration in order to determine the mechanism of dissolution. In this study we examined interfaces of orthoclase samples that were altered in separate experiments in a Ca(OH)2-H2O solution (pH25°C 12.4) at 190 °C for 24 h. We used a combination of focused ion beam (FIB) milling and advanced analytical transmission electron microscopy (TEM) techniques to investigate the structure and chemistry of the near surface region of post-reaction grains, with particular attention being given to the fluid-solid interface. Even though each grain diminishes in volume due to dissolution, high-resolution TEM imaging indicates that the feldspar structure itself remains completely intact and crystalline, as evidenced by lattice fringes that abruptly terminate at the grain edge. Nanometer-scale chemical composition measurements and mapping by TEM-EDXS (energy dispersive X-ray spectroscopy) and EFTEM (energy filtered TEM) show that the chemistry of the parent feldspar also remains unchanged at the interface. In particular, there is no evidence for the incursion of Ca from the fluid solvent into the structure, either by interdiffusion or by a replacement process. Taken together, the TEM observations point to a sharp chemical reaction front characterized by the congruent (i.e. stoichiometric) release of all elements from the feldspar structure. Nanometer-scale measurements by high resolution analytical TEM also reveal that a surface alteration layer (SAL) of amorphous material forms in situ at the expense of the feldspar structure. The interface demarcates a spatially coincident and nm-sharp chemical and structural discontinuity between the parent feldspar and the amorphous phase. The amorphous SAL has a variable thickness, from under 10 nm up to ~200 nm. This is likely one of the first observed occurrences of a significant surface amorphous layer on feldspar due to alteration in an alkaline solvent. The lack of a gap between the two phases points to an interfacial dissolution-reprecipitation process that continuously operates during hydrothermal alteration, and mostly likely right from the onset of contact with the fluid. After the initial formation of the amorphous layer, a 1–2 μm-thick porous amalgam of secondary crystalline phases comprised of calcite, tobermorite, and hydrogrossular, as well as other minor phases, precipitated over the SAL. These authigenic crystalline minerals formed during the experiment (hydrothermal alteration, followed by fluid loss due to evaporation) by a classical thermodynamically-controlled precipitation process as the reactor bulk fluid became increasingly concentrated. We propose that a coupled interfacial dissolution-reprecipitation (CIDR) mechanism best explains the chemical and structural properties of the interface and the formation of an amorphous surface layer. In fact, many recent studies postulate that a CIDR process controls feldspar dissolution and the formation of SALs at acid and circumneutral pH over a wide range of temperatures. Combining these previous results with our new observations supports the idea that a unique and unifying mechanism likely controls chemical alteration of feldspars in all aqueous fluids.

Description: Tephra layers from explosive eruptions can provide valuable isochronous marker horizons for paleoenvironmental studies across large regions. East Asia and Southeast Asia are host to more than half of the Earth's subaerial volcanoes, and tephras from these volcanoes offer significant numbers of widely distributed marker layers. However, the integrated tephrostratigraphic framework of this region is less refined because only limited (crypto-) tephra sequences have been established. In this study, we present a cryptotephra sequence covering the period ∼60–50 ka in East Asia from a lacustrine sediment from Huguangyan Maar Lake, southern China. Four cryptotephra layers were identified, one of which can be correlated with the ∼53.8 ka Unnan eruption (SUn) of Sambe volcano, Japan. This tephra provides a critical isochronous marker horizon for linking paleoenvironmental records from central Japan to southern China, illustrating a consistent environmental shift during early MIS 3 across this region. The three other tephras cannot be correlated with known eruptions, but glass geochemical compositions suggest that they may be from Japan or surrounding areas, implying that they too may be widely distributed around East Asia. Importantly, two of them feature at the start of MIS 3, and thus can be potentially be used to establish the synchroneity of the onset of MIS 3 around East Asia, overcoming challenges that presently hinder the dating of early MIS 3 in this region.

Description: Drift-bounce resonance between ultralow frequency (ULF) waves and ions is essential for ion energization in the magnetosphere. Here, we present the first comprehensive study of drift-bounce resonance in the dayside outer magnetosphere, where off-equatorial magnetic field minima would strongly distort ions' bounce and drift motion. A generalized theory is proposed, in which the effects of off-equatorial minima, time-evolving fields and ion bounce motion are taken into account. In consequence of these effects, ion pitch angle distributions undergo dramatic changes. In the presence of off-equatorial minima, the time-of-flight effect of ion bounce motion forms latitude-dependent dispersions besides “paw-track shaped” structures, while evolving wave fields cause time-dependent phase shifts in “paw-tracks.” All the predicted signatures have been confirmed by 5 years of Magnetospheric Multiscale spacecraft data and numerical simulations. These results allow us to better understand the interactions between ULF waves and thermal ion species in global magnetospheric dynamics.

Description: Magnetostratigraphic investigation of sediment cores from two different water depths in the SE Black Sea based on discrete samples, and parallel U-channels in one of the cores, yielded high-resolution records of geomagnetic field variations from the past about 68 ka. Age constrains are provided by three tephra layers of known age, accelerator mass spectrometry 14C dating, and by tuning element ratios obtained from X-ray fluorescence scanning to the oxygen isotope record from Greenland ice cores. Sedimentation rates vary from a minimum of ∼5 cmka−1 in the Holocene to a maximum of ∼50 cmka−1 in glacial marine isotope stage 4. Completely reversed inclinations and declinations as well as pronounced lows in relative palaeointensity around 41 ka provide evidence for the Laschamps geomagnetic polarity excursion. In one of the investigated cores also a fragmentary record of the Mono Lake excursion at 34.5 ka could be revealed. However, the palaeomagnetic records are more or less affected by greigite, a diagenetically formed magnetic iron sulphide. By definition of an exclusion criterion based on the ratio of saturation magnetization over volume susceptibility, greigite-bearing samples were removed from the palaeomagnetic data. Thus, only 25 to 55 per cent of the samples were left in the palaeomagnetic records obtained from sediments from the shallower coring site. The palaeomagnetic record from the deeper site, based on both discrete samples and U-channels, is much less affected by greigite. The comparison of palaeomagnetic data shows that the major features of the Laschamps polarity excursion were similarly recovered by both sampling techniques. However, several intervals had to be removed from the U-channel record due to the presence of greigite, carrying anomalous directions. By comparison to discrete sample data, also some directional artefacts in the U-channel record, caused by low-pass filtering of the broad magnetometer response functions, averaging across fast directional and large amplitude changes, can be observed. Therefore, high-resolution sampling with discrete samples should be the preferred technique when fast geomagnetic field variations, such as reversals and excursions, shall be studied from sedimentary records in the very detail.

Description: Our study on the exact timing and the potential climatic, environmental, and evolutionary consequences of the Laschamps Geomagnetic Excursion has generated the hypothesis that geomagnetism represents an unrecognized driver in environmental and evolutionary change. It is important for this hypothesis to be tested with new data, and encouragingly, none of the studies presented by Picin et al. undermine our model.

Description: Geological archives record multiple reversals of Earth’s magnetic poles, but the global impacts of these events, if any, remain unclear. Uncertain radiocarbon calibration has limited investigation of the potential effects of the last major magnetic inversion, known as the Laschamps Excursion [41 to 42 thousand years ago (ka)]. We use ancient New Zealand kauri trees (Agathis australis) to develop a detailed record of atmospheric radiocarbon levels across the Laschamps Excursion. We precisely characterize the geomagnetic reversal and perform global chemistry-climate modeling and detailed radiocarbon dating of paleoenvironmental records to investigate impacts. We find that geomagnetic field minima ~42 ka, in combination with Grand Solar Minima, caused substantial changes in atmospheric ozone concentration and circulation, driving synchronous global climate shifts that caused major environmental changes, extinction events, and transformations in the archaeological record.

Description: Our paper about the impacts of the Laschamps Geomagnetic Excursion 42,000 years ago has provoked considerable scientific and public interest, particularly in the so-called Adams Event associated with the initial transition of the magnetic poles. Although we welcome the opportunity to discuss our new ideas, Hawks’ assertions of misrepresentation are especially disappointing given his limited examination of the material.

Description: Reconstructions of the geomagnetic field on long timescales are important to understand the geodynamo processes in the Earth’s core. The geomagnetic field exhibits a range of variations that vary from normal, dipole–dominated secular variation to geomagnetic excursions and reversals. These transitional events are associated with significant directional deviations and very low intensities. Here we present a new, global geomagnetic field model spanning the period 70–15 ka (GGFSS70) that includes three excursions: Norwegian–Greenland Sea, Laschamps, and Mono Lake/Auckland. The model is built from nine globally distributed, high–resolution, well–dated, sedimentary paleomagnetic records. The GGFSS70 indicates that the axial–dipole component changed sign for about 300 years in the middle of the Laschamps excursion (41.25–40.93 ka). The energy comparison at the Earth’s surface reveals that the axial–dipole energy is always higher than the non-axial-dipole except over the Laschamps. In the other two excursions, the axial-dipole is reduced by about one order of magnitude for the Norwegian–Greenland Sea excursion and less for the Mono Lake/Auckland. At the core–mantle boundary, the large–scale non-axial-dipole power is comparable to the axial-dipole power, except over the excursions when the axial-dipole decreases, though less clearly for the Mono Lake/Auckland excursion. The axial dipole moment over the 15–70 ka varies from 0 to 8 ×1022 Am2, with an average and standard deviation of 5.1±1.5 ×1022Am2. The Laschamps excursion is associated with growth and poleward movement of reversed flux patches and reversed field in the tangent cylinder at the excursion midpoint, which is not the case for the other two excursions.

Description: An accurate estimation of terrestrial water storage (TWS) is crucial for water resource management and drought monitoring. However, the uncertainties in model physics, surface parameters and meteorological data often limit the accuracy of land surface hydrological models in estimating TWS. In this study, a multi-model-based framework was developed to predict TWS in China by 2050 using a Bayesian model averaging (BMA) method and GRACE satellite observations. Compared to GRACE observations, our BMA-based TWS anomaly (TWSA) estimations reduce root mean square errors by 10–16% and increase correlation coefficients by 26–46% over semi-humid and semi-arid basins than simple arithmetical averaging for the validation period (2008–2016). At the same time, BMA shows decreasing root mean square differences (10–12%) over humid basins. The calibrated BMA weights were then applied to future projections of TWSA under two Representative Concentration Pathways (RCP): RCP 2.6 and RCP 6.0. The overall rate of TWSA for the future period (2021–2050) was detected with the same direction as that from past decades (2003–2016), but with larger decreasing values. Especially for the Haihe basin in North China, BMA-based TWSA would decrease faster by about 19% for RCP 2.6 and 26% for RCP 6.0. These results suggest a decreasing trend in future TWS over most of the basins in China due to combined effects of global warming and human activities, which suggests likely aggravated risk of water shortage and a growing need for adaptive water resources management.

Description: With the increasing pressure from population growth and economic development, northern China (NC) faces a grand challenge of water scarcity, which can be further exacerbated by climatic and societal changes. The South‐to‐North Water Diversion (SNWD) project is designed to mitigate the water scarcity in NC. However, few studies have quantified the impact of the SNWD on water scarcity within the context of climatic and societal changes and its potential effects on economic and agricultural food in the region. We used water supply stress index (WaSSI) to quantify water scarcity within the context of environmental change in NC, and developed a method to estimate the economic and agricultural impacts of the SNWD. Focuses were put on alleviating the water supply shortage and economic and agricultural benefits for the water‐receiving NC. We find that societal changes, especially economic growth, are the major contributors to water scarcity in NC during 2009–2099. To completely mitigate the water scarcity of NC, at least an additional water supply of 13 billion m3/year (comparable to the annual diversion water by SNWD Central Route) will be necessary. Although SNWD alone cannot provide the full solution to northern China's water shortage in next few decades, it can significantly alleviate the water supply stress in NC (particularly Beijing), considerably increasing the agricultural production (more than 115 Teracalories/year) and bringing economic benefits (more than 51 billion RMB/year) through supplying industrial and domestic water use. Additionally, the transfer project could have impacts on the ecological environment in the exporting regions.