ALBERT

Description: The repeated proximity of West Antarctic Ice Sheet (WAIS) ice to the eastern Ross Sea continental shelf break during past ice age cycles has been inferred to directly influence sedimentary processes occurring on the continental slope, such as turbidity current and debris flow activity; thus, the records of these processes can be used to study the past history of the WAIS. Ross Sea slope sediments may additionally provide an archive on the history and interplay of density-driven or geostrophic oceanic bottom currents with ice-sheet-driven depositional mechanisms. We investigate the upper 121 m of Hole U1525A, collected during International Ocean Discovery Program (IODP) Expedition 374 in 2018. Hole U1525A is located on the southwestern external levee of the Hillary Canyon (Ross Sea, Antarctica) and the depositional lobe of the nearby trough-mouth fan. Using core descriptions, grain size analysis, and physical properties datasets, we develop a lithofacies scheme that allows construction of a detailed depositional model and environmental history of past ice sheet-ocean interactions at the eastern Ross Sea continental shelf break/slope since ~2.4 Ma. The earliest Pleistocene interval (~2.4- ~ 1.4 Ma) represents a hemipelagic environment dominated by ice-rafting and reworking/deposition by relatively persistent bottom current activity. Finely interlaminated silty muds with ice-rafted debris (IRD) layers are interpreted as contourites. Between ~1.4 and ~0.8 Ma, geostrophic bottom current activity was weaker and turbiditic processes more common, likely related to the increased proximity of grounded ice at the shelf edge. Silty, normally-graded laminations with sharp bases may be the result of flow-stripped turbidity currents overbanking the canyon levee during periods when ice was grounded at or proximal to the shelf edge. A sandy, IRD- and foraminifera-bearing interval dated to ~1.18 Ma potentially reflects warmer oceanographic conditions and a period of stronger Antarctic Slope Current flow. This may have enhanced upwelling of warm Circumpolar Deep Water onto the shelf, leading to large-scale glacial retreat at that time. The thickest interval of turbidite interlamination was deposited after ~1 Ma, following the onset of the Mid-Pleistocene Transition, interpreted as a time when most ice sheets grew and glacial periods were longer and more extreme. Sedimentation after ~0.8 Ma was dominated by glacigenic debris flow deposition, as the trough mouth fan that dominates the eastern Ross Sea continental slope prograded and expanded over the site. These findings will help to improve estimations of WAIS ice extent in future Ross Sea shelf-based modelling studies, and provide a basis for more detailed analysis of the inception and growth of the WAIS under distinct oceanographic conditions.

Description: In this paper we analyze how oceanic circulation affects sediment deposition along a sector of the Ross Sea continental margin, between the Iselin Bank and the Hillary Canyon, and how these processes evolved since the Late Miocene. The Hillary Canyon is one of the few places around the Antarctic continental margin where the dense waters produced onto the continental shelf, mainly through brine rejection related to sea ice production, flow down the continental slope and reach the deep oceanic bottom layer. At the same time the Hillary Canyon represents a pathway for relatively warm waters, normally flowing along the continental slope within the Antarctic Slope Current, to reach the continental shelf. The intrusion of warm waters onto the continental shelf produces basal melting of the ice shelves, reduces their buttressing effect and triggers instabilities of the ice sheet that represent one of the main uncertainties in future sea level projections. For this study we use seismic, morpho-bathymetric and oceanographic data acquired in 2017 by the R/V OGS Explora. Seismic profiles and multibeam bathymetry are interpreted together with age models from two drilling sites (U1523 and U1524) of the International Ocean Discovery Program (IODP) Expedition 374. Oceanographic data, together with a regional oceanographic model, are used to support our reconstruction by showing the present-day oceanographic influence on sediment deposition. Regional correlation of the main seismic unconformities allows us to identify eight seismic sequences. Seismic profiles and multibeam bathymetry show a strong influence of bottom current activity on sediment deposition since the Early Miocene and a reduction in their intensity during the mid-Pliocene Warm Period. Oceanographic data and modelling provide evidence that the bottom currents are related to the dense waters produced on the Ross Sea continental shelf and flowing out through the Hillary Canyon. The presence of extensive mass transport deposits and detachment scarps indicate that also mass wasting participates in sediment transport. Through this integrated approach we regard the area between the Iselin Bank and the Hillary Canyon as a Contourite Depositional System (ODYSSEA CDS) that offers a record of oceanographic and sedimentary conditions in a unique setting. The hypotheses presented in this work are intended to serve as a framework for future reconstructions based on detailed integration of lithological, paleontological, geochemical and petrophysical data.

Description: Dataset: Pyrosome Total Colony Lengths

Description: Pyrosome total colony lengths from samples collected off the Oregon Coast on three cruises aboard NOAA Ship Bell M. Shimada during 2018. For a complete list of measurements, refer to the full dataset description in the supplemental file 'Dataset_description.pdf'. The most current version of this dataset is available at: https://www.bco-dmo.org/dataset/837617

Description: NSF Division of Ocean Sciences (NSF OCE) OCE-1838492

Description: Dataset: CTD

Description: CTD data collected off the Oregon Coast on three cruises aboard NOAA Ship Bell M. Shimada during 2018. For a complete list of measurements, refer to the full dataset description in the supplemental file 'Dataset_description.pdf'. The most current version of this dataset is available at: https://www.bco-dmo.org/dataset/837256

Description: NSF Division of Ocean Sciences (NSF OCE) OCE-1838492

Description: Dataset: Chlorophyll and Phaeopigment

Description: Chlorophyll and phaeopigment data collected off the Oregon Coast on two cruises aboard NOAA Ship Bell M. Shimada during 2018. For a complete list of measurements, refer to the full dataset description in the supplemental file 'Dataset_description.pdf'. The most current version of this dataset is available at: https://www.bco-dmo.org/dataset/837587

Description: NSF Division of Ocean Sciences (NSF OCE) OCE-1838492

Description: Dataset: Pyrosome Gut Pigment Contents

Description: Pyrosome gut pigment contents from samples collected off the Oregon Coast on two cruises aboard NOAA Ship Bell M. Shimada during 2018. For a complete list of measurements, refer to the full dataset description in the supplemental file 'Dataset_description.pdf'. The most current version of this dataset is available at: https://www.bco-dmo.org/dataset/837640

Description: NSF Division of Ocean Sciences (NSF OCE) OCE-1838492

Description: Dataset: Pyrosome Abundances

Description: Pyrosome abundances from samples collected off the Oregon Coast on three cruises aboard NOAA Ship Bell M. Shimada during 2018. For a complete list of measurements, refer to the full dataset description in the supplemental file 'Dataset_description.pdf'. The most current version of this dataset is available at: https://www.bco-dmo.org/dataset/837652

Description: NSF Division of Ocean Sciences (NSF OCE) OCE-1838492

Description: Boron isotope ratios – as measured in marine calcium carbonate – are an established tracer of past seawater and calcifying fluid pH, and thus a powerful tool for probing marine calcifier physiology and reconstructing past atmospheric CO2 levels. For such applications, understanding the inorganic baseline upon which foraminiferal vital effects or coral pH upregulation are superimposed should be an important prerequisite. Yet, investigations into boron isotope fractionation in synthetic CaCO3 polymorphs have often reported variable and even conflicting results, implying our understanding of the pathways of boron incorporation into calcium carbonate is incomplete. Here we address this topic with experimental data from synthetic calcite and aragonite precipitated across a range of pH in the presence of both Mg and Ca. We observe coherent patterns in B/Ca and Na/Ca ratios that, we suggest, point to paired substitution of Na and B into the carbonate lattice to achieve local charge balance. In addition, we confirm the results of previous studies that the boron isotope composition of inorganic aragonite precipitates closely reflects that of aqueous borate ion, but that inorganic calcites display a higher degree of scatter, and diverge from the boron isotope composition of aqueous borate ion at low pH. With reference to the simultaneous incorporation of other trace and minor elements, we put forward possible explanations for the observed variability in the concentration and isotopic composition of boron in synthetic CaCO3. In particular, we highlight the potential importance of interface electrostatics in driving variability in our own and published synthetic carbonate datasets. Importantly for palaeo-reconstruction, however, these electrostatic effects are unlikely to play as important a role during natural precipitation of biogenic carbonates.