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  • 2020-2022  (3)
  • 1955-1959  (1)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Fresenius' Zeitschrift für analytische Chemie 162 (1958), S. 345-356 
    ISSN: 1618-2650
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Zusammenfassung Es wird ein papierchromatographisches Verfahren zur quantitativen Bestimmung des von Oxydkathoden abdampfenden Bariums und Strontiums angegeben. Unter den bekannten Lösungsmittelgemischen eignet sich Salzsäure-Methanol-Wasser am besten für die papierchromatographische Trennung der Abdampfprodukte. Die günstigsten Bedingungen zur Anfärbung des Chromatogramms mit Natriumrhodizonat werden angegeben. Die Chromatogramme werden bei 510 mμ, d. h. im Absorptionsmaximum des Strontiumrhodizonats bzw. in der Nähe des Absorptionsmaximums des Bariumrhodizonats photometriert. Die Auswertung ergibt eine gute Proportionalität zwischen den Barium-bzw. Strontiumkonzentrationen und den Extinktionsflächenwerten.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2021-09-07
    Description: Carbon dioxide is the most abundant, non-condensable gas in volcanic systems, released into the atmosphere through either diffuse or advective fluid flow. The emission of substantial amounts of CO2 at Earth’s surface is not only controlled by volcanic plumes during periods of eruptive activity or fumaroles, but also by soil degassing along permeable structures in the subsurface. Monitoring of these processes is of utmost importance for volcanic hazard analyses, and is also relevant for managing geothermal resources. Fluid-bearing faults are key elements of economic value for geothermal power generation. Here, we describe for the first time how sensitively and quickly natural gas emissions react to changes within a deep hydrothermal system due to geothermal fluid reinjection. For this purpose, we deployed an automated, multi-chamber CO2 flux monitoring system within the damage zone of a deep-rooted major normal fault in the Los Humeros Volcanic Complex (LHVC) in Mexico and recorded data over a period of five months. After removing the atmospheric effects on variations in CO2 flux, we calculated correlation coefficients between residual CO2 emissions and reinjection rates, identifying an inverse correlation of ρ = -0.51 to -0.66. Our results indicate that gas emissions respond to changes in reinjection rates within 24 hours, proving an active hydraulic communication between the hydrothermal system and Earth’s surface. This finding is a promising indication not only for geothermal reservoir monitoring but also for advanced long-term volcanic risk analysis. Response times allow for estimation of fluid migration velocities, which is a key constraint for conceptual and numerical modelling of fluid flow in fracture-dominated systems.
    Language: English
    Type: info:eu-repo/semantics/workingPaper
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  • 3
    Publication Date: 2021-09-16
    Description: Carbon dioxide is the most abundant, non-condensable gas in volcanic systems, released into the atmosphere through either diffuse or advective fluid flow. The emission of substantial amounts of CO2 at Earth’s surface is not only controlled by volcanic plumes during periods of eruptive activity or fumaroles, but also by soil degassing along permeable structures in the subsurface. Monitoring of these processes is of utmost importance for volcanic hazard analyses, and is also relevant for managing geothermal resources. Fluid-bearing faults are key elements of economic value for geothermal power generation. Here, we describe for the first time how sensitively and quickly natural gas emissions react to changes within a deep hydrothermal system due to geothermal fluid reinjection. For this purpose, we deployed an automated, multi-chamber CO2 flux monitoring system within the damage zone of a deep-rooted major normal fault in the Los Humeros Volcanic Complex (LHVC) in Mexico and recorded data over a period of five months. After removing the atmospheric effects on variations in CO2 flux, we calculated correlation coefficients between residual CO2 emissions and reinjection rates, identifying an inverse correlation of ρ = − 0.51 to − 0.66. Our results indicate that gas emissions respond to changes in reinjection rates within 24 h, proving an active hydraulic communication between the hydrothermal system and Earth’s surface. This finding is a promising indication not only for geothermal reservoir monitoring but also for advanced long-term volcanic risk analysis. Response times allow for estimation of fluid migration velocities, which is a key constraint for conceptual and numerical modelling of fluid flow in fracture-dominated systems.
    Type: info:eu-repo/semantics/article
    Format: application/pdf
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  • 4
    Publication Date: 2021-01-15
    Type: info:eu-repo/semantics/conferenceObject
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