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  • 2020-2022  (11)
  • 1980-1984  (5)
  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : International Union of Crystallography (IUCr)
    Acta crystallographica 40 (1984), S. 580-587 
    ISSN: 1600-5724
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: A periodic lattice in \bb En is associated with an n-grid and its dual, and with a point symmetry group G. Given a subgroup H of G, a subspace \bb Em, m 〈 n, of \bb En, invariant under H, is chosen and a projection of the n-grid from \bb En to \bb Em is defined. The translational and point symmetries of the projected n-grid are analyzed. A projection of the cubic n-grid from \bb En to \bb En-1 based on H = S(n) yields a periodic n-grid. A projection of the cubic 12-grid from \bb E12 to \bb E3 based on H = A(5) yields a non-periodic 12-grid. This 12- grid is characterized by three real numbers and from its projection has a well defined orientation. The dual to this 12-grid yields a generalization of the non-periodic Penrose patterns from two to three dimensions.
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  • 2
    ISSN: 1432-1866
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract The results are given of textural and compositional investigations carried out on carbonate materials outcropping in various localities in northwestern Sicily where fluorite, barite and calcite mineralizations of hydrothermal origin occur. Observation of the textural features indicate variations in the degree of calcite recrystallization and silicification that appear to be more marked in rocks that show more evident effects of mineralization. The geochemical behaviour of the minor elements indicate variations in chemical composition (increase of Mn, Fe, and Sr and removal of Mg) as a result of interactions between mineralizing fluids and host-rocks. Comparison between the isotopic compositions of oxygen and carbon in mineralized and unmineralized limestones shows that isotopic exchange took place between CaCO3 and hydrothermal fluids. The values obtained support relatively short limestone/water contact times and moderate temperature values. It is suggested that the ore-forming solutions were essentially heated meteoric waters. Precipitation of the fluorite was caused by temperature decrease, reaction with Ca-rich wall rock, and increase in pH of initially rather acid hydrothermal solutions.
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  • 3
  • 4
    Publication Date: 2020-04-01
    Description: Context. Realistic synthetic observations of theoretical source models are essential for our understanding of real observational data. In using synthetic data, one can verify the extent to which source parameters can be recovered and evaluate how various data corruption effects can be calibrated. These studies are the most important when proposing observations of new sources, in the characterization of the capabilities of new or upgraded instruments, and when verifying model-based theoretical predictions in a direct comparison with observational data. Aims. We present the SYnthetic Measurement creator for long Baseline Arrays (SYMBA), a novel synthetic data generation pipeline for Very Long Baseline Interferometry (VLBI) observations. SYMBA takes into account several realistic atmospheric, instrumental, and calibration effects. Methods. We used SYMBA to create synthetic observations for the Event Horizon Telescope (EHT), a millimetre VLBI array, which has recently captured the first image of a black hole shadow. After testing SYMBA with simple source and corruption models, we study the importance of including all corruption and calibration effects, compared to the addition of thermal noise only. Using synthetic data based on two example general relativistic magnetohydrodynamics (GRMHD) model images of M 87, we performed case studies to assess the image quality that can be obtained with the current and future EHT array for different weather conditions. Results. Our synthetic observations show that the effects of atmospheric and instrumental corruptions on the measured visibilities are significant. Despite these effects, we demonstrate how the overall structure of our GRMHD source models can be recovered robustly with the EHT2017 array after performing calibration steps, which include fringe fitting, a priori amplitude and network calibration, and self-calibration. With the planned addition of new stations to the EHT array in the coming years, images could be reconstructed with higher angular resolution and dynamic range. In our case study, these improvements allowed for a distinction between a thermal and a non-thermal GRMHD model based on salient features in reconstructed images.
    Print ISSN: 0004-6361
    Electronic ISSN: 1432-0746
    Topics: Physics
    Published by EDP Sciences
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  • 5
    Publication Date: 2020-03-01
    Description: Aims. The Seeds Of Life In Space IRAM/NOEMA large program aims at studying a set of crucial complex organic molecules in a sample of sources with a well-known physical structure that covers the various phases of solar-type star formation. One representative object of the transition from the prestellar core to the protostar phases has been observed toward the very low luminosity object (VeLLO) L1521F. This type of source is important to study to link prestellar cores and Class 0 sources and also to constrain the chemical evolution during the process of star formation. Methods. Two frequency windows (81.6–82.6 GHz and 96.65–97.65 GHz) were used to observe the emission from several complex organics toward the L1521F VeLLO. These setups cover transitions of ketene (H2CCO), propyne (CH3CCH), formamide (NH2CHO), methoxy (CH3O), methanol (CH3OH), dimethyl ether (CH3OCH3), and methyl formate (HCOOCH3). Results. Only two transitions of methanol (A+, E2) have been detected in the narrow window centered at 96.7 GHz (with an upper limit on E1) in a very compact emission blob (~7′′ corresponding to ~1000 au) toward the northeast of the L1521F protostar. The CS 2–1 transition is also detected within the WideX bandwidth. Consistently with what has been found in prestellar cores, the methanol emission appears ~1000 au away from the dust peak. The location of the methanol blob coincides with one of the filaments that have previously been reported in the literature. The excitation temperature of the gas inferred from methanol is (10 ± 2) K, while the H2 gas density (estimated from the detected CS 2–1 emission and previous CS 5–4 ALMA observations) is a factor 〉25 higher than the density in the surrounding environment (n(H2) ≥ 107 cm−3). Conclusions. Based on its compactness, low excitation temperature, and high gas density, we suggest that the methanol emission detected with NOEMA is (i) either a cold and dense shock-induced blob that formed recently (≤ a few hundred years) by infalling gas or (ii) a cold and dense fragment that may just have been formed as a result of the intense gas dynamics within the L1521F VeLLO system.
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    Electronic ISSN: 1432-0746
    Topics: Physics
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  • 6
    Publication Date: 2020-02-28
    Description: Using the IRAM NOrthern Extended Millimeter Array (NOEMA), we conducted a program to measure redshifts for 13 bright galaxies detected in the Herschel Astrophysical Large Area Survey with S500 μm ≥ 80 mJy. We report reliable spectroscopic redshifts for 12 individual sources, which are derived from scans of the 3 and 2 mm bands, covering up to 31 GHz in each band, and are based on the detection of at least two emission lines. The spectroscopic redshifts are in the range 2.08 〈  z 〈  4.05 with a median value of z = 2.9 ± 0.6. The sources are unresolved or barely resolved on scales of 10 kpc. In one field, two galaxies with different redshifts were detected. In two cases the sources are found to be binary galaxies with projected distances of ∼140 kpc. The linewidths of the sources are large, with a mean value for the full width at half maximum of 700 ± 300 km s−1 and a median of 800 km s−1. We analyze the nature of the sources with currently available ancillary data to determine if they are lensed or hyper-luminous (LFIR 〉  1013 L⊙) galaxies. We also present a reanalysis of the spectral energy distributions including the continuum flux densities measured at 3 and 2 mm to derive the overall properties of the sources. Future prospects based on these efficient measurements of redshifts of high-z galaxies using NOEMA are outlined, including a comprehensive survey of all the brightest Herschel galaxies.
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    Electronic ISSN: 1432-0746
    Topics: Physics
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  • 7
    Publication Date: 2020-03-01
    Description: Context. It is nowadays clear that a rich organic chemistry takes place in protostellar regions. However, the processes responsible for it, that is, the dominant formation routes to interstellar complex organic molecules, are still a source of debate. Two paradigms have been evoked: the formation of these molecules on interstellar dust mantles and their formation in the gas phase from simpler species previously synthesised on the dust mantles. Aims. In the past, observations of protostellar shocks have been used to set constraints on the formation route of formamide (NH2CHO), exploiting its observed spatial distribution and comparison with astrochemical model predictions. In this work, we follow the same strategy to study the case of acetaldehyde (CH3CHO). Methods. To this end, we used the data obtained with the IRAM-NOEMA interferometer in the framework of the Large Program SOLIS to image the B0 and B1 shocks along the L1157 blueshifted outflow in methanol (CH3OH) and acetaldehyde line emission. Results. We imaged six CH3OH and eight CH3CHO lines which cover upper-level energies up to ~30 K. Both species trace the B0 molecular cavity as well as the northern B1 portion, that is, the regions where the youngest shocks (~1000 yr) occurred. The CH3OH and CH3CHO emission peaks towards the B1b clump, where we measured the following column densities and relative abundances: 1.3 × 1016 cm−2 and 6.5 × 10−6 (methanol), and 7 × 1013 cm−2 and 3.5 × 10−8 (acetaldehyde). We carried out a non-LTE (non-Local Thermodinamic Equilibrium) Large Velocity Gradient (LVG) analysis of the observed CH3OH line: the average kinetic temperature and density of the emitting gas are Tkin ~ 90 K and nH2 ~ 4 × 105 cm−3, respectively. The CH3OH and CH3CHO abundance ratio towards B1b is 190, varying by less than a factor three throughout the whole B0–B1 structure. Conclusions. Comparison of astrochemical model predictions with the observed methanol and acetaldehyde spatial distribution does not allow us to distinguish whether acetaldehyde is formed on the grain mantles or in the gas phase, as its gas-phase formation, which is dominated by the reaction of ethyl radical (CH3CH2) with atomic oxygen, is very fast. Observations of acetaldehyde in younger shocks, for example those of ~102 yr old, and/or of the ethyl radical, whose frequencies are not presently available, are necessary to settle the issue.
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    Electronic ISSN: 1432-0746
    Topics: Physics
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  • 8
    Publication Date: 2020-08-01
    Description: Context. The interstellar complex organic molecules (iCOMs) are C-bearing molecules containing at least six atoms; two main proposals for their formation are suggested: a direct formation in the icy mantle of the dust grains and formation through the reaction in gas phase of released grain mantle species. The shocked gas along outflows driven by low-mass protostars is a unique environment to study how the iCOMs can be formed as the composition of the dust mantles is sputtered into the gas phase. Aims. The chemical richness in shocked material associated with low-mass protostellar outflows has been so far studied in the prototypical L1157 blue-shifted outflow to investigate the iCOM formation routes. To understand whether the case of L1157-B1 is unique, we imaged and studied the IRAS 4A outflows in the NGC 1333 star forming region. Methods. We used the NOrthern Extended Millimeter Array interferometer as part of the IRAM Seeds Of Life in Space (SOLIS) Large Program to image the large-scale bipolar outflows driven by the IRAS 4A system in the 3 mm band, and we compared the observation with the GRAINOBLE+ astrochemical model. Results. We report the first detection, in the IRAS 4A outflows, of several iCOMs: six lines of methanol (CH3OH), eight of acetaldehyde (CH3CHO), one of formamide (NH2CHO), and four of dimethyl ether (CH3OCH3), all sampling upper excitation energy up to ~30 K. We found a significant chemical differentiation between the southeast outflow driven by the IRAS 4A1 protostar, showing a richer molecular content, and the north–southwest one driven by the IRAS 4A2 hot corino. The CH3OH/CH3CHO abundance ratio is lower by a factor of ~4 in the former; furthermore, the ratio in the IRAS 4A outflows is lower by a factor of ~10 with respect to the values found in different hot corinos. Conclusions. After L1157-B1, the IRAS 4A outflow is now the second outflow to show an evident chemical complexity. Given that CH3OH is a grain surface species, the astrochemical gas-phase model run with GRAINOBLE+ reproduced our observation assuming that acetaldehyde is formed mainly through the gas-phase reaction of the ethyl radical (CH3CH2) and atomic oxygen. Furthermore, the chemical differentiation between the two outflows suggests that the IRAS 4A1 outflow is likely younger than that of the IRAS 4A2. Further investigation is needed to constrain the age of the outflow. In addition, observation of even younger shocks are necessary. In order to provide strong constraints on the CH3CHO formation mechanisms it would be interesting to observe CH3CH2, but given that its frequencies are not known, future spectroscopic studies on this species are needed.
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  • 9
    Publication Date: 2020-08-01
    Description: Context. Contrary to what is expected from models of Galactic chemical evolution, the isotopic fractionation of silicon (Si) in the Galaxy has recently been found to be constant. This finding calls for new observations, also at core scales, to re-evaluate the fractionation of Si. Aims. L1157-B1 is one of the outflow-shocked regions along the blue-shifted outflow that is driven by the Class 0 protostar L1157-mm. It is an ideal laboratory for studying the material ejected from the grains on very short timescales because its chemical composition is representative of the composition of the grains. Methods. We imaged 28SiO, 29SiO, and 30SiO J = 2–1 emission towards L1157-B1 and B0 with the NOrthern Extended Millimeter Array (NOEMA) interferometer as part of the Seeds of Life in Space (SOLIS) large project. We present here a study of the isotopic fractionation of SiO towards L1157-B1. Furthermore, we used the high spectral resolution observations on the main isotopologue, 28SiO, to study the jet impact on the dense gas. We here also present single-dish observations obtained with the IRAM 30 m telescope and Herschel-HIFI. We carried out a non-local thermal equilibrium analysis using a large velocity gradient code to model the single-dish observations. Results. From our observations we can show that (i) the 2–1 transition of the main isotopologue is optically thick in L1157-B1 even at high velocities, and (ii) the [29SiO/30SiO] ratio is constant across the source, and consistent with the solar value of 1.5. Conclusions. We report the first isotopic fractionation maps of SiO in a shocked region and show the absence of a mass-dependent fractionation in 29Si and 30Si across L1157-B1. A high-velocity bullet in 28SiO has been identified, showing the signature of a jet impacting on the dense gas. With the dataset presented in this paper, both interferometric and single-dish, we were able to study the gas that is shocked at the B1a position and its surrounding gas in great detail.
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  • 10
    Publication Date: 2020-10-01
    Description: Context. AB Aur is a Herbig Ae star that hosts a prototypical transition disk. The disk shows a plethora of features connected with planet formation mechanisms, such as spiral arms, dust cavities, and dust traps. Understanding the physical and chemical characteristics of these features is crucial to advancing our knowledge of the planet formation processes. Aims. We aim to characterize the gaseous disk around the Herbig Ae star AB Aur. A complete spectroscopic study was performed using NOEMA to determine the physical and chemical conditions with high spatial resolution. Methods. We present new NOrthern Extended Millimeter Array (NOEMA) interferometric observations of the continuum and 12CO, 13CO, C18O, H2CO, and SO lines obtained at high resolution. We used the integrated intensity maps and stacked spectra to derive reliable estimates of the disk temperature. By combining our 13CO and C18O observations, we computed the gas-to-dust ratio along the disk. We also derived column density maps for the different species and used them to compute abundance maps. The results of our observations were compared with a set of Nautilus astrochemical models to obtain insight into the disk properties. Results. We detected continuum emission in a ring that extends from 0.6′′ to ~2.0′′, peaking at 0.97′′ and with a strong azimuthal asymmetry. The molecules observed show different spatial distributions, and the peaks of the distributions are not correlated with the binding energy. Using H2CO and SO lines, we derived a mean disk temperature of 39 K. We derived a gas-to-dust ratio that ranges from 10 to 40 along the disk. Abundance with respect to 13CO for SO (~2 × 10−4) is almost one order of magnitude greater than the value derived for H2CO (1.6 × 10−5). The comparison with Nautilus models favors a disk with a low gas-to-dust ratio (40) and prominent sulfur depletion. Conclusions. From a very complete spectroscopic study of the prototypical disk around AB Aur, we derived, for the first time, the gas temperature and the gas-to-dust ratio along the disk, providing information that is essential to constraining hydrodynamical simulations. Moreover, we explored the gas chemistry and, in particular, the sulfur depletion. The derived sulfur depletion is dependent on the assumed C/O ratio. Our data are better explained with C/O ~ 0.7 and S/H = 8 × 10−8.
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    Topics: Physics
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