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  • 1965-1969  (3)
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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 371 (1969), S. 281-288 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: SbCl3 forms with SO3 the two adducts SbCl3 · OSO2 and SbCl3 · 2 OSO2 in which the SO3 coordinates the antimony through oxygen. SbCl3 · 2 OSO2 decomposes in vacuo into SO3 and SbCl3 and SbCl3 · OSO2. Oxidation of these adducts by means of liquid chlorine yields SbCl4OSO2Cl and SbCl4OSO2Cl · OSO2 resp. SbCl4S2O6Cl. SbCl4OSO2Cl is isomeric with the adduct SbCl5 · OSO2 and Decomposes thermally into (SbCl4)2SO4 and SO2Cl2.
    Notes: SbCl3 bildet mit SO3 die beiden Additionsverbindungen SbCl3 · OSO2 udn SbCl3 · 2OSO2, in denen das SO3 über Sauerstoffatome am Antimon koordiniert ist. SbCl3 · 2OSO2 zersetzt sich im Vakuum in SO3 und SbC3 · OSO2. Durch Oxydation der SbCl3 - SO3-Addukte mit flüssigem Chlor werden SbCl4OSO2Cl und SbCl4OSO2Cl · OSO2 bzw. SbCl2S2O6Cl erhalten. SbCl4OSO2Cl ist isomer zum SbCl5 · OSO2-Addukt und liefert bei der thermischen Zersetzung (SbCl4)2SO4 und SO2Cl2.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The reaction of SbCl5 with SO3 and HSO3Cl, respectively, yields the adduct SbCl5 · OSO2 as a primary product in which the SO3 coordinates the antimony through an oxygen atom.With excess SO3, SbCl5 · OSO2 reacts to (SbCl4)2SO4 and S2O5Cl2.
    Notes: Bei der Reaktion von SbCl5 mit SO3 bzw. HSO3Cl entsteht primär stets SbCl5 · OSO2 Es hat die Konstitution eines Adduktes, in dem das SO3 koordinativ über ein Sauerstoffatom an das Antimon gebunden ist. Mit überschüssigem SO3 reagiert SbCl5 · OSO2 weiter unter Bildung von (SbCl4)2SO4 und S2O5Cl2.
    Additional Material: 2 Tab.
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 371 (1969), S. 289-294 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: AsCl3 reacts at 60 - 70°C with SO3 forming AsCl4 whose thermal decomposition yields AsCl3, SO3 and basic arenic(III) sulphates. At room temrature, in AsCl3 - SO3 mixtures the compound AsCl3 · OSo2 occurs, probably in equilibrium with AsCl2OSo2Cl.
    Notes: AsCl3 regiert bei 60-70°C mit SO3 unter bildung von AsCiSO4, dessen thermishce Zersetzung AsCl3, SO3 und basische Arsen(III)-sulfate liefert. Bei Raumtemperatur liegt in AsCl3 - SO3-Mischungen AsCl3 · OSO2, wahrsheinlich im Gleichgewicht mit AsCl2OSO2Cl, vor.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
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