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  • American Meteorological Society  (6)
  • Geological Society of London  (5)
  • Copernicus  (4)
  • Nature Publishing Group
  • 2015-2019  (15)
  • 2000-2004
  • 1975-1979
  • 2016  (15)
  • 1
    Publication Date: 2016-03-02
    Description: The Carboniferous Bowland Shale of northern England has drawn considerable attention because it has been estimated to have 1329 trillion cubic feet hydrocarbons in-place (gas and liquids) resource potential (Andrews 2013). Here we report on the oil and gas generation characteristics of three selected Bowland Shale whole-rock samples taken from cores and their respective kerogen concentrates. Compositional kinetics and phase properties of the primary and secondary fluids were calculated through the PhaseKinetics and GOR-Fit approaches and PVT modelling software. The three Bowland Shale samples contain immature, marine type II kerogen. Pyrolysate compositions imply primary generation of paraffinic–naphthenic–aromatic (PNA) oil with low contents of wax and sulphur. Bulk kinetic parameters have many similarities to those of productive American Palaeozoic marine shale plays. The secondary gas generation potential of Bowland Shale is greater than the primary gas potential although it requires a 10 kcal mol –1 higher activation energy to achieve peak production. Primary oil, primary gas and secondary gas reach their maximum generation at 137, 150 and 200°C respectively for a 3°C Ma –1 heating rate. Different driving forces of expulsion including the generation of hydrocarbon and overpressure caused by phase separation during sequential periods of subsidence and uplift could be inferred.
    Print ISSN: 0016-7649
    Topics: Geosciences
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  • 2
    Publication Date: 2016-04-15
    Description: The Carboniferous Bowland Shale of northern England has drawn considerable attention because it has been estimated to have 1329 trillion cubic feet hydrocarbons in-place (gas and liquids) resource potential (Andrews 2013). Here we report on the oil and gas generation characteristics of three selected Bowland Shale whole-rock samples taken from cores and their respective kerogen concentrates. Compositional kinetics and phase properties of the primary and secondary fluids were calculated through the PhaseKinetics and GOR-Fit approaches and PVT modelling software. The three Bowland Shale samples contain immature, marine type II kerogen. Pyrolysate compositions imply primary generation of paraffinic–naphthenic–aromatic (PNA) oil with low contents of wax and sulphur. Bulk kinetic parameters have many similarities to those of productive American Palaeozoic marine shale plays. The secondary gas generation potential of Bowland Shale is greater than the primary gas potential although it requires a 10 kcal mol –1 higher activation energy to achieve peak production. Primary oil, primary gas and secondary gas reach their maximum generation at 137, 150 and 200°C respectively for a 3°C Ma –1 heating rate. Different driving forces of expulsion including the generation of hydrocarbon and overpressure caused by phase separation during sequential periods of subsidence and uplift could be inferred.
    Print ISSN: 0016-7649
    Topics: Geosciences
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  • 3
    Publication Date: 2016-09-19
    Print ISSN: 0027-0644
    Electronic ISSN: 1520-0493
    Topics: Geography , Geosciences , Physics
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  • 4
    Publication Date: 2016-10-01
    Description: For climate services to be relevant and informative for users, scientific data definitions need to match users’ perceptions or beliefs. This study proposes and tests novel yet simple methods to compare beliefs of timing of recurrent climatic events with empirical evidence from multiple historical time series. The methods are tested by applying them to the onset date of the monsoon in Bangladesh, where several scientific monsoon definitions can be applied, yielding different results for monsoon onset dates. It is a challenge to know which monsoon definition compares best with people’s beliefs. Time series from eight different scientific monsoon definitions in six regions are compared with respondent beliefs from a previously completed survey concerning the monsoon onset. Beliefs about the timing of the monsoon onset are represented probabilistically for each respondent by constructing a probability mass function (PMF) from elicited responses about the earliest, normal, and latest dates for the event. A three-parameter circular modified triangular distribution (CMTD) is used to allow for the possibility (albeit small) of the onset at any time of the year. These distributions are then compared to the historical time series using two approaches: likelihood scores, and the mean and standard deviation of time series of dates simulated from each belief distribution. The methods proposed give the basis for further iterative discussion with decision-makers in the development of eventual climate services. This study uses Jessore, Bangladesh, as an example and finds that a rainfall definition, applying a 10 mm day−1 threshold to NCEP–NCAR reanalysis (Reanalyis-1) data, best matches the survey respondents’ beliefs about monsoon onset.
    Print ISSN: 1948-8327
    Electronic ISSN: 1948-8335
    Topics: Geosciences , Physics
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  • 5
    Publication Date: 2016-09-01
    Description: A simple model of an internal wave advected by an oscillating barotropic flow suggests flaws in standard approaches to estimating properties of the internal tide. When the M2 barotropic tidal current amplitude is of similar size to the phase speed of the M2 baroclinic tide, spectral and harmonic analysis techniques lead to erroneous estimates of the amplitude, phase, and energy in the M2 internal tide. In general, harmonic fits and bandpass or low-pass filters that attempt to isolate the lowest M2 harmonic significantly underestimate the strength of M2 baroclinic energy fluxes in shelf seas. Baroclinic energy flux estimates may show artificial spatial variability, giving the illusion of sources and sinks of energy where none are actually present. Analysis of previously published estimates of baroclinic energy fluxes in the Celtic Sea suggests this mechanism may lead to values being 25%–60% too low.
    Print ISSN: 0022-3670
    Electronic ISSN: 1520-0485
    Topics: Geosciences , Physics
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  • 6
    Publication Date: 2016-09-23
    Description: This study describes a systematic approach to selecting optimal statistical recalibration methods and hindcast designs for producing reliable probability forecasts on seasonal-to-decadal time scales. A new recalibration method is introduced that includes adjustments for both unconditional and conditional biases in the mean and variance of the forecast distribution and linear time-dependent bias in the mean. The complexity of the recalibration can be systematically varied by restricting the parameters. Simple recalibration methods may outperform more complex ones given limited training data. A new cross-validation methodology is proposed that allows the comparison of multiple recalibration methods and varying training periods using limited data. Part I considers the effect on forecast skill of varying the recalibration complexity and training period length. The interaction between these factors is analyzed for gridbox forecasts of annual mean near-surface temperature from the CanCM4 model. Recalibration methods that include conditional adjustment of the ensemble mean outperform simple bias correction by issuing climatological forecasts where the model has limited skill. Trend-adjusted forecasts outperform forecasts without trend adjustment at almost 75% of grid boxes. The optimal training period is around 30 yr for trend-adjusted forecasts and around 15 yr otherwise. The optimal training period is strongly related to the length of the optimal climatology. Longer training periods may increase overall performance but at the expense of very poor forecasts where skill is limited.
    Print ISSN: 0894-8755
    Electronic ISSN: 1520-0442
    Topics: Geography , Geosciences , Physics
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  • 7
    Publication Date: 2016-09-21
    Description: The inclusion of carbon cycle processes within CMIP5 Earth system models provides the opportunity to explore the relative importance of differences in scenario and climate model representation to future land and ocean carbon fluxes. A two-way analysis of variance (ANOVA) approach was used to quantify the variability owing to differences between scenarios and between climate models at different lead times. For global ocean carbon fluxes, the variance attributed to differences between representative concentration pathway scenarios exceeds the variance attributed to differences between climate models by around 2025, completely dominating by 2100. This contrasts with global land carbon fluxes, where the variance attributed to differences between climate models continues to dominate beyond 2100. This suggests that modeled processes that determine ocean fluxes are currently better constrained than those of land fluxes; thus, one can be more confident in linking different future socioeconomic pathways to consequences of ocean carbon uptake than for land carbon uptake. The contribution of internal variance is negligible for ocean fluxes and small for land fluxes, indicating that there is little dependence on the initial conditions. The apparent agreement in atmosphere–ocean carbon fluxes, globally, masks strong climate model differences at a regional level. The North Atlantic and Southern Ocean are key regions, where differences in modeled processes represent an important source of variability in projected regional fluxes.
    Print ISSN: 0894-8755
    Electronic ISSN: 1520-0442
    Topics: Geography , Geosciences , Physics
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  • 8
    Publication Date: 2016-01-29
    Description: Predictability estimates of ensemble prediction systems are uncertain because of limited numbers of past forecasts and observations. To account for such uncertainty, this paper proposes a Bayesian inferential framework that provides a simple 6-parameter representation of ensemble forecasting systems and the corresponding observations. The framework is probabilistic and thus allows for quantifying uncertainty in predictability measures, such as correlation skill and signal-to-noise ratios. It also provides a natural way to produce recalibrated probabilistic predictions from uncalibrated ensembles forecasts. The framework is used to address important questions concerning the skill of winter hindcasts of the North Atlantic Oscillation for 1992–2011 issued by the Met Office Global Seasonal Forecast System, version 5 (GloSea5), climate prediction system. Although there is much uncertainty in the correlation between ensemble mean and observations, there is strong evidence of skill: the 95% credible interval of the correlation coefficient of [0.19, 0.68] does not overlap zero. There is also strong evidence that the forecasts are not exchangeable with the observations: with over 99% certainty, the signal-to-noise ratio of the forecasts is smaller than the signal-to-noise ratio of the observations, which suggests that raw forecasts should not be taken as representative scenarios of the observations. Forecast recalibration is thus required, which can be coherently addressed within the proposed framework.
    Print ISSN: 0894-8755
    Electronic ISSN: 1520-0442
    Topics: Geography , Geosciences , Physics
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  • 9
    Publication Date: 2016-01-15
    Description: This paper discusses how epistemic uncertainties are considered in a number of different natural hazard areas including floods, landslides and debris flows, dam safety, droughts, earthquakes, tsunamis, volcanic ash clouds and pyroclastic flows, and wind storms. In each case it is common practice to treat most uncertainties in the form of aleatory probability distributions but this may lead to an underestimation of the resulting uncertainties in assessing the hazard, consequences and risk. It is suggested that such analyses might be usefully extended by looking at different scenarios of assumptions about sources of epistemic uncertainty, with a view to reducing the element of surprise in future hazard occurrences. Since every analysis is necessarily conditional on the assumptions made about the nature of sources of epistemic uncertainty it is also important to follow the guidelines for good practice suggested in the companion Part 1 by setting out those assumptions in a condition tree.
    Electronic ISSN: 2195-9269
    Topics: Geography , Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 10
    Publication Date: 2016-08-29
    Description: A decline in damaging European windstorms has led to a reduction in insured losses in the 21st century. This decline is explored by identifying a damaging windstorm characteristic and investigating how and why this characteristic has changed in recent years. This novel exploration is based on 6103 high-resolution model-generated historical footprints (1979–2014), representing the whole European domain. The footprint of a windstorm is defined as the maximum wind gust speed to occur at a set of spatial locations over the duration of the storm. The area of the footprint exceeding 20 ms−1 over land, A20, is shown to be a good predictor of windstorm damage. This damaging characteristic has decreased in the 21st century, due to a statistically significant decrease in the relative frequency of windstorms exceeding 20 ms−1 in north-western Europe, although an increase is observed in southern Europe. This is explained by a decrease in the quantiles of the footprint wind gust speed distribution above approximately 18 ms−1 at locations in this region. In addition, an increased variability in the number of windstorm events is observed in the 21st century. Much of the change in A20 is explained by the North Atlantic Oscillation (NAO). The correlation between winter total A20 and winter-averaged mean sea-level pressure resembles the NAO pattern, shifted eastwards over Europe, and a strong positive relationship (correlation of 0.715) exists between winter total A20 and winter-averaged NAO. The shifted correlation pattern, however, suggests that other modes of variability may also play a role in the variation in windstorm losses.
    Print ISSN: 1561-8633
    Electronic ISSN: 1684-9981
    Topics: Geography , Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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