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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 1998 (1998), S. 1585-1587 
    ISSN: 1434-1948
    Keywords: Metallodisilanes ; Oxofunctionalization ; Metallodisilandiols ; Silanetriols ; Metallosiloxanes ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Reaction of the ferriodisilanes C5R5(OC)2Fe-Si2H5 [R = H (1a), Me (1b)] with dimethyldioxirane leads to selective insertion of oxygen into the α-Si-H bonds to yield the ferriodihydroxydisilanes C5R5(OC)2Fe-Si(OH)2-SiH3[R = H (2a), Me (2b)]. Another access to yield 2a is opened by hydrolysis of the dichloro(ferrio)disilane Cp(OC)2Fe-SiCl2-SiH3 (3a). Treatment of the pentachloro(metallo)disilanes C5H5(OC)2Fe-Si2Cl5 (4a) and C5Me5(OC)2Ru-Si2Cl5 (4b) with water results in regiospecific hydroxylation of the β-silicon atom to generate metallodisilanetriols C5R5(OC)2M-SiCl2-Si(OH)3 [M = Fe, R = H (5a); M = Ru, R = Me (5b)]. Controlled condensation of 5b with Me2Si(H)Cl leads to the novel rutheniosiloxane C5Me5(OC)2Ru-SiCl2-Si(OSiMe2H)3 (6).
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Solid state phenomena Vol. 63-64 (Dec. 1998), p. 115-122 
    ISSN: 1662-9779
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 287-288 (Aug. 1998), p. 269-270 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1432-0517
    Keywords: Key words Atomic absorption spectrometry/electrothermal atomisation ; Grinding machines ; Trace elements ; Uncertainty ; Variance components
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract  Chemical analyses of trace elements are affected by relatively high analytical errors due to the different steps of the laboratory procedures: samples grinding, mineralisation and instrumental measurements. In the present communication, the influence of the grinding phase on the global uncertainty of Pb, Cd, Ni and Cr determinations in plant samples by the classical method of atomic absorption spectrometry/electrothermal atomisation (AAS-ETA) after dry ashing is quantified. Two grinding machines, a planetary mill with balls and jars of agate versus a stainless steel grinder were compared by analysing leaf samples of cucumber, strawberry, kiwivines, apple trees and grapevines from agricultural experimental plots under controlled conditions. Variance components due to the difference between grinding methods and experimental plots were estimated. Further, the simultaneous effects of the grinding methods on all considered metals have been evaluated by analysis of variance. With the stainless steel grinder, on average, higher levels of the considered heavy metals were obtained (up to 67% of the mean values). On average, the increments were similar for metals contained in steel (Ni and Cr) and those not contained (Pb and Cd). The true causes of these differences need further investigation to determine whether the higher metal detection is due to possible contamination, to a different grinding quality or to other reasons. Finally, the grinding methods did not seem to affect the combined uncertainty of the analyses.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    European journal of clinical pharmacology 54 (1998), S. 273-274 
    ISSN: 1432-1041
    Keywords: Key words Hydrochlorothiazide ; Voglibose
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Medicine
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 0949-2925
    Keywords: Schlüsselwörter: Elektronische Bibliothek, Internet, Informationsvermittlung, Abrechnung ; Key words: Digital library, internet, information brokering, accounting ; CR Subject Classifications: H.3.5, H.3.6
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science
    Description / Table of Contents: Abstract. The objective of the MeDoc project was the conception of a full-text based publication and reference service for computer science literature, its prototypical implementation and evaluation. The service shall enhance information exchange and supply researchers with literature more easily. Therefore an internet based system was developed that allows for searching, browsing, delivering and storing documents and supports searching in heterogeneous, distributed information systems. Part of the documents offered via the MeDoc service are billable. This article describes the functionality and architecture of the MeDoc system.
    Notes: Zusammenfassung. Ziele des MeDoc-Projektes waren die Konzeption, prototypische Entwicklung und Erprobung volltextbasierter Informations- und Publikationsdienste für die Informatik, um den Informationsaustausch und die Literaturversorgung in der Wissenschaft effektiver gestalten zu können. Dazu wurde im Rahmen des Projektes ein internet-basiertes System entwickelt, in dem Informatik & Fachinformation im Volltext gespeichert, recherchiert, abgerufen und gelesen werden kann und das die Suche nach Informatik-Literatur in heterogenen, verteilten Informationsquellen im Internet unterstützt. Das Informationsangebot ist dabei teilweise kostenpflichtig. In diesem Artikel werden Ziele, Funktionalität und Architektur des MeDoc-Systems beschrieben.
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  • 7
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 287-288 (Aug. 1998), p. 455-458 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 264-268 (Feb. 1998), p. 171-174 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd.
    Journal of metamorphic geology 16 (1998), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: To constrain the tectonic history of the Pan-African belt in Tanzania, we have studied the P–T  evolution of granulites from northern and eastern Tanzania representative for a large part of the southern Pan-African belt of East Africa (e.g. Pare, Usambara, Ukaguru and Uluguru Mountains). Thermobarometry (conventional and multireaction equilibria) on enderbites and metapelites gives 9.5–11 kbar and 810±40 °C during peak metamorphism at 650–620 Ma. This is consistent with the occurrence of both sillimanite and kyanite in metapelites and of the high-P granulite facies assemblage garnet–clinopyroxene–quartz in mafic rocks. Peak metamorphic conditions are surprisingly similar over a very large area with N-S and E-W extents of about 700 and 200 km respectively. The prograde metamorphic evolution in the entire area started in the kyanite field but evolved mainly within the sillimanite stability field. The retrograde P–T  evolution is characterized by late-stage kyanite in metapelites and garnet–clinopyroxene coronas around orthopyroxene in meta-igneous rocks. This is in agreement with thermobarometric results and isotopic dating, indicating a period of nearly isobaric and slow cooling prior to tectonic uplift. The anticlockwise P–T  path could have resulted from magmatic underplating and loading of the lower continental crust which caused heating and thickening of the crust. Substantial postmetamorphic crustal thickening of yet unknown age (presumably after 550 Ma) led subsequently to the exhumation of high-P granulites over a large area. The results are consistent with formation of the Pan-African granulites at an active continental margin where tonalitic intrusions caused crustal growth and heating 70–100 Ma prior to continental collision. The P–T–t path contradicts recent geodynamic models which proposed tectonic crustal thickening due to continental collision between East and West Gondwana as the cause of granulite formation in the southern part of the Pan-African belt.
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  • 10
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd.
    Journal of metamorphic geology 16 (1998), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Relict eclogites and associated high-pressure rocks are present in the Eastern Segment of the SW Swedish gneiss region (the tectonic counterpart of the Parautochthonous Belt of the Canadian Grenville). These rocks give evidence of Sveconorwegian eclogite facies metamorphism and subsequent pervasive reworking and deformation at granulite and amphibolite facies conditions. The best-preserved eclogite relics suggest a clockwise P–T –t history, beginning in the amphibolite facies, progressing through the eclogite facies, decompressing and partially reequilibrating through the high- and medium-pressure granulite facies, before cooling through the amphibolite facies. Textures demonstrate the former coexistence of the plagioclase-free assemblages garnet+clinopyroxene+quartz+rutile+ilmenite, garnet+clinopyroxene+ kyanite+rutile, and garnet+kyanite+quartz+rutile. The former existence of omphacite is evidenced by up to 45 vol.% plagioclase expelled as small grains within large clinopyroxene. Matrix plagioclase is secondary and occurs expelled from clinopyroxene or in fine-grained, granulite facies reaction domains formed during resorption of garnet and kyanite. Garnet shows preserved prograde growth zoning with rimward increasing pyrope content, decreasing spessartine content and decreasing Fe/(Fe+Mg) ratio, but is partly resorbed and reequilibrated at the rims. P–T estimates from microdomains with clinopyroxene+plagioclase+quartz+garnet indicate pressures of 9.5–12 kbar and temperatures of 705–795 °C for a stage of the granulite facies decompression. The preservation of the prograde zoning suggests that the rocks did not reside at these high temperatures for more than a few million years, and chemical disequilibrium and ‘frozen’ reaction textures indicate heterogeneous reaction progress and overstepping of reactions during the decompression through the granulite facies. Together these features suggest a rapid tectonic exhumation. The eclogite relics occur within a high-grade deformation zone with WNW–ESE stretching and associated oblique normal-sense, top-to-the-east (sensu lato) displacement, suggesting that extension was a main cause for the decompression and exhumation. Probable tectonic scenarios for this deformation are Sveconorwegian late-orogenic gravitational collapse or overall WNW–ESE extension.
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