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  • American Institute of Physics (AIP)  (2)
  • American Association for the Advancement of Science (AAAS)  (1)
  • Amsterdam : Elsevier
  • 1990-1994  (3)
  • 1994  (3)
  • 1
    Electronic Resource
    Electronic Resource
    Picosecond time-resolved adsorbate response to substrate heating: Spectroscopy and dynamics of CO/Cu(100) (1994)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 101 (1994), S. 1704-1716 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The response of the molecular stretch mode of CO/Cu(100) near 2086 cm−1 (ν1) to resonant infrared, and nonresonant visible and ultraviolet pumping is measured on a picosecond time scale. Fourier transform infrared measurements establish that ν1 is anharmonically coupled to the frustrated translation near 32 cm−1 (ν4), so that transient shifts in ν1 indicate population changes in ν4. The ν1 response to visible and ultraviolet pumping is characterized by a spectral shift near zero delay time, which decays with a ≈2 ps time constant to an intermediate value, which then decays on a ≈200 ps time scale. The data agree well with a model whereby ν4 couples to both the photogenerated hot electrons and to the heated phonons. The characteristic coupling times to these two heat baths are found to both be a few picoseconds.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.467792
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    A femtojoule calorimeter using micromechanical sensors (1994)
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 65 (1994), S. 3793-3798 
    Details
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: We describe a highly sensitive new type of calorimeter based on the deflection of a "bimetallic'' micromechanical sensor as a function of temperature. The temperature changes can be due to ambient changes, giving a temperature sensor or, more importantly, due to the heat absorbed by a coating on the sensor, giving a heat sensor. As an example we show the results of using the sensor as a photothermal spectrometer. The small dimensions and low thermal mass of the sensor make it highly sensitive and we demonstrate a sensitivity of roughly 100 pW. By applying a simple model of the system the ultimate sensitivity is expected to be of the order of 10 pW. The thermal response time of the cantilever can also be determined, giving an estimate of the minimum detectable energy of the sensor. This we find to be 150 fJ and again from our model, expect a minimum value of the order of 20 fJ.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.1144509
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    Paper (German National Licenses)
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  • 3
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    Ca(2+)-induced Ca2+ release in response to flash photolysis (1994)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1994-02-18
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Lamb, G D -- Fryer, M W -- Stephenson, D G -- New York, N.Y. -- Science. 1994 Feb 18;263(5149):986-8.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/8310298" target="_blank"〉PubMed〈/a〉
    Keywords: Acetates/chemistry/metabolism ; Adaptation, Physiological ; Animals ; Calcium/*metabolism ; Calcium Channels/*metabolism ; Dogs ; Electrodes ; Ethylenediamines/chemistry/metabolism ; Myocardium/*metabolism ; Photolysis
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
    Published by American Association for the Advancement of Science (AAAS)
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