ISSN:
1434-4475
Keywords:
Sulphamoyl chloride, reaction withn-alkyl hydroperoxides
;
n-Alkyl hydroperoxides, reaction with sulphamoyl chloride
;
Alkyl(sulphamoyl)peroxides, preparation and thermolysis
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The novel peroxides H2NSO2OOCH2 R (1 a:R=CH2CH3;1 b:R=CH2CH2CH3) are obtained by reaction of sulphamoyl chloride with the appropriate hydroperoxides in the presence of pyridine (temperature below −30 °C, solvent diethyl ether). The solvent-free liquids1 deflagrate at ca. 0 °C. Hydrolysis or ammonolysis of1 generates the hydroperoxide and sulphamic acid or sulphamide, respectively. Controlled thermolysis of1 affords sulphamic acid and carbonyl compounds, i.e. propanal andn-propyl propanoate from1 a, butanal, 2-methylpropanal andn-butyln-butyrate from1 b. These products suggest a nonradical cyclic decomposition path-way.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00798755
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