ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • Chemical Engineering  (70)
  • 1980-1984  (70)
  • 1983  (70)
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 29 (1983), S. 79-86 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The kinetics of reaction between CO2 and lime is investigated in the range of 673 to 998 K with a view to examining the effects of product layer deposition and variations in the limestone calcination atmosphere. The reaction is initially rapid and chemically controlled and goes through a sudden transition to a much slower regime controlled by diffusion in the product CaCO3 layer. The magnitude of the estimated product layer diffusivity is in the range of 10-18 to 10-21 m2/s, the corresponding activation energy is 88.9 ± 3.7 kJ/mol below 688 K and 179.2 ± 7.0 kJ/mol above that temperature, suggestive of solid state diffusion. Plausible mechanisms are discussed.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 29 (1983), S. 625-631 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The mixed oxide system of copper and tin and the active single oxide, Cu2O, were compared for reducibility of the copper ion, relative number and type of active sites, and reaction kinetics. The enhanced selectivity of the mixed oxides may result from the formation of highly selective sites at the expense of less selective sites. The reducibility of the copper ion in the mixture is influenced by the oxidation state of the tin ion. The reactant and product reaction orders are the same for both catalysts but the mixed oxides are more sensitive to inhibition by water. The catalyst composition affects the energetics of the reaction over the copper-tin oxide catalysts.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 3
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new apparatus to measure partition coefficients Ks∞ at infinite dilution up to 200 105 Pa and 423 K is described. Measurements of the systems: (1) methane-ethane-n-decane and methane-propane-n-decane at 294.25 K; and (2) methane-n-butane-n-decane at 344.25 K illustrate the reproducibility and good agreement with literature data. In addition, new data were obtained for the system methane-n-pentane-n-decane at 344.25 K up to 101 105 Pa.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 29 (1983), S. 281-289 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: By considering reaction and diffusion through a product layer and concomitant movement of pore and reaction surfaces, a general rate equation is derived for fluid-solid reactions. Application to the random pore model extends the prior results (Bhatia and Perlmutter, 1980, 1981a) to account for nonlinear concentration gradients in the product layer, by assuming that the product is deposited as overlapping cylindrical annulae. For the Petersen (1957) model, new results are derived which account for product layer diffusion. A comparison of numerical conversion-time predictions from the grain model (Szekely et al., 1976), the Petersen model, and the random pore models suggests that they are more strongly affected by the representation of the reaction surface than by that of the pore surface. The model is applied to the data of Borgwardt (1970) on the SO2-lime reaction, and the results are compared with a previous interpretation using a linear concentration gradient approximation.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 29 (1983), S. 172-173 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 29 (1983), S. 806-812 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The reaction kinetics and physical transport processes governing the thermal dehydration of solid K2CO3·3/2H2O particles were investigated. Isothermal reaction rate data were gathered using a thermogravimetric balance in which narrowly-sized K2CO3·3/2H2O crystals were dehydrated under a water vapor atmosphere at different pressures and temperatures. The magnitudes of the heat and mass transfer resistances external to and within the solid product were estimated from solutions of the relevant pseudosteady-state transport equations. In the temperature range 320 to 358 K, the vacuum dehydration of K2CO3·3/2H2O crystals smaller than 710 μm (-25 +30 mesh) are accurately modeled by the spherical shrinking-core equation for the chemical rate control regime. In the presence of water vapor, external heat transfer to the particles was sufficient to prevent significant self-cooling; heat and mass transfer resistances within the particles were negligible. The activation energy for K2CO3·3/2H2O dehydration is approximately 91 kJ/mol in vacuum; the reaction becomes extremely slow at relative pressures (P/Peq) 〉 0.35.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 7
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 4 (1983), S. 32-39 
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The fatigue behavior of injection-molded tensile bars of short-fiber-reinforced theromplastics is described and related to the fatigue behavior of the matrices and the strength of the fiber/matrix interface. A brittle matrix system based on polyphenylene sulfide is shown to behave in a similar manner to long-fiber composites. Glass-fiber reinforcement in this matrix gives fatigue sensitivity that correlaes with that of unimpregnated glass fiber strands, while carbon-fiber rein-forcement gives better fatigue resistance. A well-bonded, due-tile matrix system based on nylon 6,6 gives matrix-controlled fatigue sensitivity. Fatigue data for glass- and carbon-fiber-reinfoced nylon 6,6 superimpose on the matrix fatigue data when normalized by the ultimate tensile strength. Another ductile matrix, polyetherther ketone, is very fatigue-resistant, but its composite progressively loses its reinforcing effect in fatigue, apparently due to interface failure. A transitional matrix, polysulfone, shifts from ductile to fatigue-crack-dominated failure as the cyclic stress is reduced. Its composites show an analogous failure mode shift, and the high cycle-fatigue response is correlated with fatigue-crack-growth data.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 8
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 4 (1983), S. 40-46 
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Research in the past eight years has established the ability of polymer composites made with sufficient electrical conductivity to be suitable as shields against electromagnetic interference (EMI). A number of conductive fillers have been used to produce such composites. These include carbon black, carbon fibers, metal fibers, metal flakes, and metal-coated glass fibers. Each filler offers its own set of advantages and disadvantages. An important aspect of developing polymeric composites for EMI shielding applications is measuring their shielding ability in areliable, easy-to-use test facility. Once a reliable test has been developed, basic data relating the bulk conductivity (or surface conductivity of coatings) can be generaated. The objective of this article is to discuss the relative utility of the different types of fillers commonly used, present an analysis of the utility of different testing approaches, and show data correlating volume resistivity with shielding effectiveness.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 9
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Shear properties of laminates consisting of graphite fiber (Celion 6000, Celion 3000, and T-300) and several resins (epoxy, hot melt-bismaleimide, solvent bismaleimide, polyimide, and polystyrylpyridine (PSP)) were measured using the short-beam test. The interlaminar shear strength of epoxy composites was hightest. All other resin composites showed considerably lower shear properties. The shear strengths deereased with temperature, with the loss up to 100°C being more pronounced. The PSP composites did not show a loss in strength in the temperature range investigated (room temperature to 250°C). Boiling the composite samples in water for 24 h resuled in negligible reduction in shear strength in all cases. The interlaminar shear properties depended on the fiberresin interfacial bond, the wetting characteristics of the resin, and the resin meechanical properties. Attempts were made to determine to what extent each of these factors controlled the shear properties of the composites studies. Thus, the interfacial bond between the resin and the single fiber was determined. Results showed that the lower shear strength of polyimide, bisimides and PSP composites, as compared to epoxy resin composites, seemed to be due to their corresponding low interfacial bond strengths. The subsequent decrease in shear strength with temperature appeared to be directly correlated to the decrease in bond strength. The wettability of carbon fiber tow with all these resins was also determined. The small variations in wetting characteristics of the resin did not seem to justify the rather large differences in shear-strength properties observed.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 29 (1983), S. 167-170 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...