ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

X
feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • ASTROPHYSICS  (150)
  • Analytical Chemistry and Spectroscopy  (113)
  • 1980-1984  (263)
  • 1983  (263)
  • 1
    Electronic Resource
    Electronic Resource
    Vibrational spectroscopy at high pressures: 44 - thallous carbonate (1983)
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 14 (1983), S. 144-149 
    Details
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Raman spectra of thallous carbonate have been studied to c. 52 kbar and mid-IR spectra to 36 kbar. Details of the assignment have also been established using single-crystal IR reflectance and Raman spectroscopy. Phase transitions were found near 13 and 38 kbar on the basis of the Raman evidence, thus supporting the earlier conclusions of Meisalo and Kalliomaki based on x-ray powder and optical results. Analysis of possible space group relations between phases III (ambient) and IV showed that IV must be orthorhombic and adopt one of the D2hn groups, where n = 17, 19, 21, 25 or 28. Structural relationships between the phases are discussed.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jrs.1250140304
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 2
    facet.materialart.
    Unknown
    Observations of NGC 7027 from 5.2 to 7.5 microns - The detection of Ni II and additional dust features (1983)
    In:  Other Sources
    Details
    Publication Date: 2011-08-18
    Description: NGC 7027 was observed with a multichannel grating spectrometer from 5.2 to 7.5 microns at a spectral resolving power of 120-200. Two new dust emission features are resolved at 5.62 and 6.95 microns, and for the first time the Ni II fine-structure line at 6.64 microns is detected. It is shown that a single molecular dust constituent might account for six of the nine observed dust features between 2 and 14 microns. The strength of the Ni II line indicates either that Ni is not depleted in the neutral gas, or that the line is formed at high density.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 274; 666-670
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    NASA TECHNICAL REPORTS
  • 3
    facet.materialart.
    Unknown
    The C2H, C2, and CN electronic absorption bands in the carbon star HD 19557 (1983)
    In:  Other Sources
    Details
    Publication Date: 2011-08-18
    Description: Infrared spectrophotometry of the R-type carbon star HD 19557 is presented. Two unusual spectroscopic features are seen: a 3.1 micron band is lacking and a 2.8 micron band is present. Identifications are proposed for three previously unreported stellar absorption bands with electronic sequences of C2, CN, and C2H. The latter is proposed to be responsible for the 2.8 micron feature. The atmospheric structure of the star is studied with synthetic spectra, and an effective temperature between 2600 K and 3000 K is suggested. No SiC emission is seen at 11.3 microns, indicating that grain formation is not a viable process around the star. The lack of dust in R stars may suggest a salient difference between R and N types.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 270; July 1
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    NASA TECHNICAL REPORTS
  • 4
    facet.materialart.
    Unknown
    The grains and gas in Comet Bowell 1980b (1983)
    In:  Other Sources
    Details
    Publication Date: 2011-08-18
    Description: The importance of coordinating different types of observations of a comet is illustrated in terms of spectral data on Comet Bowell. Photometric data in 1980 indicated that OH emissions were occurring when the comet was still more than 4 AU from the sun. Further measurements were arranged with the IUE satellite, the photoelectric scanner at Cerro Tololo and the IR telescope on Mauna Kea. Several sizes of diaphragms were used in order to estimate variations with respect to aperture. Calculations were made to quantify the wavelengths observed as a function of the grains' cross-sections. The OH emission was confirmed by the spectrographic and photometric data. It is suggested that sufficient dark materials are present on the cometary surface to have enhanced the absorption of solar radiation to levels sufficient for heating and dissociating surface ice particles.
    Keywords: ASTROPHYSICS
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    NASA TECHNICAL REPORTS
  • 5
    facet.materialart.
    Unknown
    An ionization gradient across the front in M17 SW (1983)
    In:  Other Sources
    Details
    Publication Date: 2019-06-28
    Description: Measurements of forbidden Ne II lines at 12.8 microns and forbidden S IV at 10.5 microns are presented along a line through and perpendicular to the ionization front in M17 SW. These observations give evidence for ionization stratification within the front, with the most highly ionized material lying toward the east, opposite to the peak molecular emission and far-IR flux. This result supports the picture of M17 SW as a region where a molecular cloud is heated externally. The ionization equilibrium within the ridge and the nebular energetics suggest that the M17 H II region is largely excited by one or more nearby early O stars. The properties of the recently discovered radio point source in M17 are discussed.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 275; 130-134
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    NASA TECHNICAL REPORTS
  • 6
    Electronic Resource
    Electronic Resource
    Measurement of enterolactone and enterodiol, the first mammalian lignans, using stable isotope dilution and gas chromatography mass spectrometry (1983)
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 10 (1983), S. 227-235 
    Details
    ISSN: 0306-042X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Methods are described to extract and measure 2,3-bis(3-hydroxybenzyl)-γ-butyrolactone (enterolactone) and 2,3-bis(3-hydroxybenzyl)butane-1,4-diol (enterodiol) from physiological fluids. They are based on the use of stable labelled analogues of each compound as internal standards with end point assay being by gas chromatography mass spectrometry. The methods were developed to quantify enterolactone and enterodiol in experiments designed to investigate the significance and source of these compounds in man and animals. Examples of studies on human ovarian blood and investigations of their excretion in urine following dietary manipulation are described.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bms.1200100321
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 7
    Electronic Resource
    Electronic Resource
    Pulsed positive ion negative ion chemical ionization mass spectrometric applications to environmental and hazardous waste analysis (1983)
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 10 (1983), S. 369-376 
    Details
    ISSN: 0306-042X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The simultaneous acquisition of both positive ion and negative ion data under chemical ionization mass spectrometric conditions can aid in the confirmation of assignments made by electron impact gas chromatography mass spectrometry or electron capture gas chromatography. Pulsed positive ion negative ion chemical ionization mass spectrometry coupled with fused-silica capillary column gas chromatographic methods is shown to be useful in environmental and hazardous waste sample analysis. The chemical ionization conditions which maximize sensitivity and the amount of molecular ion information for the priority pollutants are presented. Replicates of response factors for these compounds show good precision. Saturation is observed about 10 ng for those pesticides which give linear responses from 50 pg to 1-10 ng.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bms.1200100606
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 8
    Electronic Resource
    Electronic Resource
    A general survey of the proton spin-lattice relaxation rates of steroids (1983)
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 21 (1983), S. 532-538 
    Details
    ISSN: 0030-4921
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The spin-lattice relaxation rates of the aromatic, alkene, hydroxyl, methine and methyl protons of 19 steroid derivatives have been measured using the null point method. A simple procedure is described whereby the R1 values of molecules which have different motional tumbling rates can be directly inter-compared, and it is shown that such ‘normalized’ relaxation data can provide novel insight concerning both the geometry and the local molecular motion of these substances in solution.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/omr.1270210903
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 9
    Electronic Resource
    Electronic Resource
    Isotopic distribution of the polyhaloorganics formed from the halogenation of haloorganics with isotopically enriched halogens (1983)
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1983), S. 462-465 
    Details
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Halogenation reactions, both brominations and chlorinations, of haloorganics lead to di- or often polyhalogenated products. A major mechanistic question concerning these reactions always remains unanswered; whether they proceed by direct substitution or whether they proceed by a process involving an elimination-readdition sequence. The question can be answered by carrying out the reactions using isotopically enriched halogen. A method of analysis has been devised, using high resolution mass spectrometry, which determines the isotopic distribution in each of the individual halogen atoms. The details of this procedure are presented in this report and examples of its use from several mechanistic investigations are presented.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/oms.1210181103
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 10
    Electronic Resource
    Electronic Resource
    The structure of decomposing [C7H7O]+ ions: Benzyl versus tropylium ion structures (1983)
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1983), S. 474-485 
    Details
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The unimolecular dissociation reactions for [C7H7O]+ ions generated by fragmentation of a series of precursor molecules have been investigated. The metastable kinetic energy values and branching ratios associated with decarbonylation and expulsion of a molecule of formaldehyde (CH2O) from the [C7H7O]+ ions are interpreted as the hydroxybenzyl and hydroxytropylium [C7H7O]+ not interconverting to a common structure on the microsecond time-scale. In addition, similar measurements on protonated benzaldehyde, methylaryloxy and phenyl methylene ether [C7H7O]+ ions are interpreted as the dominant fraction of these decomposing ions having unique structures on the microsecond time-scale. These results are supported by experimental heats of formation calculated from ionization/appearance energy measurements. The experimental heats of formation are determined as: hydroxybenzyl ions, 735 kJ mol-1; hydroxytropylium ions, 656 kJ mol-1; phenyl methylene ether ions, 640 kJ mol-1; methylaryloxy ions 803 kJ mol-1. The combination of the results reported in this paper with previously reported experimental data for stable [C7H7O]+ ions (see Ref. 1, C. J. Cassady, B. S. Freiser and D. H. Russell, Org. Mass Spectrom.) is interpreted as evidence that the relative population of benzyl versus tropylium [C7H7O]+ ion structures from a given precursor molecule is determined by isomerization of the parent ion and not by structural equilibration of the [C7H7O]+ ion.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/oms.1210181105
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...