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Toxic gas evolution from polymers: Evolution of hydrogen cyanide from polyurethanes (1977)

Jellinek, H. H. G. ; Takada, K.

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Chemistry Edition 15 (1977), S. 2269-2288

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ISSN: 0360-6376

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The thermal oxidative degradation of two aromatic and one segmented polyurethane has been studied, with special emphasis on HCN evolution over a range of temperatures and oxygen concentrations. A tentative mechanism for HCN formation has been presented. Other gaseous products were ascertained by chromatography. Infrared spectra during degradation were measured, and the extent of crosslinking was also determined. It is shown that HCN evolution can be inhibited by copper or its oxide.

Additional Material: 26 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1977.170150917

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