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  • Chemical Engineering  (57)
  • 1975-1979
  • 1970-1974  (57)
  • 1972  (57)
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  • 1975-1979
  • 1970-1974  (57)
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  • 1
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 18 (1972), S. 1268-1271 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 12 (1972), S. 101-108 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Interpenetrating polymer networks (IPN's) of polybutadiene (PB) and polystyrene (PS) were prepared using both random (containing 36% cis, 55% trans, and 9% 1,2 vinyl) PB and high-cis PB. For both series, a wide range of PB/PS compositions were synthesized. Using samples stained with osmium tetroxide, electron microscope studies revealed an irregular cellular structure of a few hundred Ångstrom diameter with the first component, PB, making up the cell walls. The size of the cells was found to depend on the PB crosslink density for the random materials. Modulus-temperature data revealed two distinct glass transitions, confirming the microscopy finding of two phases. However, the transition temperature and transition slope varied with composition, and with the microstructure of the polybutadiene, giving evidence of significant molecular mixing. Stress-strain data on the IPN's showed that materials rich in PB behave like self-reinforced elastomers. Charpy impact resistance experiments on materials rich in PS indicated values of 5 ft-lb/in. of notch, which compares well with graft-type polyblends of similar PB/PS composition. The results were interpreted in the light of the recent theoretical work of Bragaw, who considered the importance of the distances between domain boundaries with respect to crack acceleration mechanics. Although the IPN's considered herein exhibited somewhat less than the predicted optimum phase dimensions, the arrangement of the domains is different from ordinary impact resistant plastics.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 12 (1972), S. 193-198 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The rapid increase in the rate of application of thermoplastics in engineering design problems and the interest in the structural use of these materials have resulted in the requirement of comprehensive information about the behaviour of thermoplastics when subjected to cyclic loading conditions. In addition to the “total fatigue life” data already available for many materials, attempts have been made to analyse the crack initiation and steady crack growth processes and determine the effects of parameters such as mean load, frequency and crack geometry on the rate of crack propagation. The results of an investigation of these aspects of fatigue crack growth in a brittle thermoplastic, polymethylmethacrylate (PMMA), have already been reported. In this paper, the results of a test program devised to study the behaviour, at room temperature and in air, of a polycarbonate, (PC), under similar loading conditions, are presented. Fracture Mechanics concepts have been used to analyse the results. It was found that a relationship of the form ȧN = β λn already shown to predict the cyclic fatigue crack propagation rate in PMMA, is also applicable to polycarbonate. However, when the effects of frequency and loading rate were studied, it was found that after the magnitude of parameter K̇( = ΔK/half the periodic time) exceeded 4000 lbf in. -3/2 s-1, the influence of the mean level of stress intensity factor, Km, became negligible in comparison to the effect of ΔK.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 12 (1972), S. 335-339 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Recently, rotational molding engineers, concerned with warpage and uneven cooling in parts, have been “pre-cooling” the mold in forced draft air after removal from the oven and prior to water quenching to removal temperature. In this paper, we analyze some of the factors that influence the rate of heat removal from an amorphous plastic in a metal mold. We find that mold thickness and thermal diffusivity, convection heat transfer coefficient of the cooling fluid, the thermal properties of the plastic and the initial, final and “freezing” temperatures of the plastic influence this cooling rate and the corresponding rate of volumetric shrinkage. We illustrate our analysis with several examples and discuss some guidelines in detail.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 12 (1972), S. 358-363 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The birefringences of injection molded plates and the birefringence during steady, isothermal shear flow were compared for some amorphous polymers. The materials studied were a polystyrene, a “toughened” polystyrene and an acrylonitrile-butadiene-styrene copolymer. The birefringence of the plates, notably the maximum value for the average over the thickness was found to be related to the shear stress at the cavity wall that had occurred during the mold filling process. This relationship was independent of temperature. To a good approximation, it was also the same as the relationship between the flow birefringence and the shear stress at the wall in isothermal channel flow. It thus appears that the anisotropy of injection molded objects is dominated by the shear stresses during the mold filling process regardless of the temperature and of the macroscopic rate of deformation.
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 12 (1972), S. 387-395 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: A theoretical model was developed for the newly-defined delay zone of the plasticating screw extruder. The delay zone starts at the end of the solids conveying zone, i.e. at the point where the solid plug surface contacting the barrel melts and forms a film of melt up to where the steady state melting mechanism starts to operate. The model permits the film thickness and pressure profiles in this zone to be calculated. Published results were used to support the validity of the model. The results indicate that the film thickness at the end of the delay zone is several times the flight clearance. Finally, a criteria, based on the final value of the film thickness, is suggested to calculate the length of the delay zone.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 12 (1972), S. 25-29 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Dynamical mechanical relaxation spectra of a number of polyurethane-polyether block copolymers have been studied as a function of composition, temperature and frequency. At low temperatures these copolymers are characterized by a high glass-like modulus which decreases to a much lower typically elastomeric value in a narrow temperature range. The latter is a function in certain cases of the composition of the polymer. The rubbery plateau is maintained up to at least 140°C. In addition, a secondary relaxation is observed around -130°C. These observations can be interpreted in terms of an overall structure consisting of a polyether matrix containing segregated polyurethane domains, the latter serving as physical crosslinks in the system at ambient temperatures and above.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 12 (1972), S. 224-235 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: This experimental study of suspension-chlorinated linear polyethylenes (CPE), (degree of chlorination 25 to 48% Cl), covers dynamic mechancial behavior at 3.5 and 110 Hz in the temperature range - 100 to 120°C. The semicrystalline samples, with a maximum degree of crystallinity of 25%, showed the main relaxations α and β. The effect of thermal treatment was examined. In the amorphous specimens, in addition to the Tg relaxation, other low temperature damping peaks were observed. The mechancial spectra indicate structure heterogeneity and increasing stiffness with increasing chlorine substitution. For the most prominent β relaxation, the apparent activation energy was determined from the frequency shift of tan δ and E″ maxima. The effect of structure, crystallinity and frequency on Young's moduli are also discussed. For the amorphous γ ray-Crosslinked elastomeric samples the photoelastic properties were examined at near equilibrium conditions between 30° and 80°C at various degrees of crosslinking. The polarizability anisotropy of the optical link and the Mooney-Rivlin elasticity constants were determined and an attempt was made to relate the result to the specimens' structure. A compatibility study was also made for a 42% Cl, CPE/high cis polybutadiene polyblend. The damping mechanical spectra indicate a noninteracting system whose Young's moduli can be correlated with those of the pure components using a phenomenological model proposed by Takayanagi.
    Zusätzliches Material: 14 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 12 (1972), S. 272-276 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: This paper presents results obtained by the experimental technique of photoelastic stress analysis and by finite or discrete element analysis, applied to the case of buckling of a single, axially-loaded metal fiber embedded in a plastic matrix. The program was conducted utilizing a mild steel fiber embedded in an epoxy resin system. The fiber was loaded axially with an increasing compressive force until buckling occurred. Along with determination of the critical load for the fiber, the maximum shearing stress at any point in the epoxy matrix was determined using two-dimension photoelastic stress analysis. In the analytical study, the fiber was modeled by a series of bending elements and the matrix by an assemblage of constant-strain triangular elements. The total system was thus modeled by the two types of elements connected at common nodal points. The instability was solved as a standard eigenvalue problem and the stress tensor was obtained by finite element stress analysis.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 12 (1972), S. 91-100 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The mechanical properties of glass bead (30 micron diameter glass spheres) filled epoxy and polyester resins have been studied as a function of volume fraction of filler and the strength of the interfacial bond. The bonding between glass and resin was varied by chemically surface treating the glass using a silicone mold release to prevent chemical bonding at one extreme and a silane coupling agent to maximize bonding at the other extreme. Theoretical predictions of the elastic modulus and tensile strength have been made utilizing a finite element method. Excellent agreement is obtained with the experimental results. Izod impact energies have been measured for these composites as a function of filler content and interface treatment.
    Zusätzliches Material: 17 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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