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  • Chemical Engineering  (41)
  • SPACE VEHICLES
  • ASTROPHYSICS
  • Wiley-Blackwell  (41)
  • 1970-1974  (41)
  • 1970  (41)
  • 1
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 10 (1970), S. 24-31 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Flow at the entrance of a tube or channel is of interest in many polymer processes. Except for mathematical treatments at high Reynolds numbers and in creeping Newtonian flow, one must turn to empirical correlating equations and qualitative observations. These are discussed in two parts, one on pressure drop and the other on flow patterns. The discussion of pressure drop is largely a review, dealing with inertial, viscous, and elastic contributions to the pressure drop in tapered and sharp-edged entrances; also presented are new data for a viscoelastic polymer solution in tapered cone entrances. In the section on flow patterns, stress birefringent data for a very elastic solution flowing into a channel entrance show an unusual effect: stress discontinuities, not unlike “shock waves,” upstream and downstream of the entrances. This is in contrast to Newtonian and less elastic materials in which the stress patterns change gradually between the developed flow region and the entrance region.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 10 (1970), S. 193-203 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The capillary flow instability resulting in extrudate distortion has been studied for ethylene polymer melts using a molecular structure approach. It is found that the instability initiates at a critical value of elastic strain energy independent of (average) molecular weight for linear polyethylene. Once the flow breaks down, a slip interface within the melt is formed near the capillary wall, causing an abrupt increase in volumetric throughput. The velocity gradient within the melt remains continuous through the instability, however. Low molecular weight species present in the molecular weight distribution of linear polyethylene tend to suppress slip. Blends of linear and branched polyethylene exhibit instability behavior characteristic of both components throughout the entire range of composition. Results are discussed in terms of specific molecular mechanisms.
    Additional Material: 14 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 10 (1970), S. 340-344 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The cross-linked, ladderlike structure of cured pyrrones is not susceptible to forming at ordinary temperatures and pressures. At unusually high processing temperatures, of the order of 500°C, these intractable materials are observed to undergo transient flow sufficient to allow molding of the material. This observation, supported by analytical information, suggests that the flow occurs because of the breakage of covalent organic bonds and subsequent structural rearrangement of the cross-linked polymer network. This is in accord with a number of isolated reports of the pyrolytic behavior of several polymers.
    Additional Material: 10 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 10 (1970), S. 154-158 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: In injection molding certain polymers, fracture of the polymer stream sometimes occurs at the mold surface. This phenomenon has been found to be a tearing apart of the polymer surface layer accompanied by downstream slip of the flowing melt at the polymer/mold interface. Fracture occurs early in mold filling and is initiated usually at the gate to the mold cavity. Analysis of the fracture mechanism indicates that fracture is caused by: (1) high shearing stress in the melt as it fills the mold; (2) poor polymer/mold adhesion; and (3) low polymer surface cohesive strength.
    Additional Material: 15 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 10 (1970), S. 293-299 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The dynamic elastic moduli were measured on macroscopic models simulating two-phase microstructures where the second phase was present as a continuous, isotropic network. Using open-pore polymer foams with higher-moduli, infiltrating matrices, the composite moduli were found to be linear with volume fraction of the network phase. Variations of network cell size or surface area indicated that the moduli increased with increasing interfacial area, but only when interphase wetting was present and matrix contraction upon solidification occurred. Metallic foams with a lower moduli matrix produced moduli that were compatible with existing bounding theories for composites.
    Additional Material: 9 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 293-299 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The laminar, isothermal entrance region flow of the Bingham fluid in a circular pipe is studied at first by using the momentum integral method and the boundary-layer equation for the Bingham fluid. In addition to the velocity boundary layer, the existence of the shear stress boundary layer is considered. The solution is valid only near the entry because of limitation of the boundary-layer model. The Campbell-Slattery method originally devised for the Newtonian fluid is also used to analyze the Bingham entrance region flow. The results are compared with those obtained through the use of the momentum integral method and those obtained through the use of the variational method by other investigators. While the results obtained in this work appear to be generally reasonable and valid, the results by the other investigators have been found to be somewhat erroneous.
    Additional Material: 12 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 10 (1970), S. 19-23 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The kinetics of the molecular vaporization process of 21 plasticizers were investigated in detail. By both isothermal and nonisothermal kinetic methods, it was evident that 11 were quite pure single compounds, while 10 were clearly mixtures of compounds. For the single component species internal energies for vaporization and rates of volatilization are listed. The internal energies of vaporization are about one-half or less of values one can estimate from the additive factor method of Small. Thus, solubility parameters based on our experimental values are low by about 30 percent. From this and previous work on linear alkanes, it is concluded that in the molecular vaporization process, the large organic molecules studied evaporate approximately as spheres and hence low values for the energy of vaporization are obtained. Consequently, the difference between our experimental energy and that estimated from solubility parameters is the energy for extending the molecule in a vacuum environment.
    Additional Material: 5 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 10 (1970), S. 66-69 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Relaxation modulus curves for narrow distribution and broad distribution polystyrenes are compared and the significant effect of molecular weight distribution on these curves is shown. An empirical three-parameter equation is shown to describe the stress relaxation behavior of narrow distribution polystyrenes. New data for high molecular weight, narrow distribution polystyrenes are presented and used to extend the applicability of previous quantitative relations for higher molecular weights. The stress relaxation technique is shown to be sensitive to the type of plasticizer used at low concentrations.
    Additional Material: 4 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 10 (1970), S. 177-184 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Increases in modulus, tensile strength, and swelling caused by reinforcing silicone rubber with silica filler were correlated with the thermoelastic parameter, fe/f. A new semiempirical equation of state, containing a generalized front factor, was derived to explain the experimental results. While the retractive force in pure gum elastomers is largely entropic in origin, reinforcement in silicone rubber-silica systems appears to arise by greatly augmenting the deformational free energy change stored in energetic modes.
    Additional Material: 8 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 10 (1970), S. 204-208 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Dynamic mill stability tests of PVC powder blends at the equiviscous temperatures were correlated with the clarity and color obtained in extrusion and blow molding of bottles. Copolymers of vinyl chloride with alkyl vinyl ether and propylene in a calcium-zinc stabilizer, impact modified formulation had better processability than a homopolymer and produced bottles having lower values of absorbance and yellowness index. Product imperfections which were evident in blow molding of dry blends, but not during milling or capillary rheometer extrusion, were found to be related to the particle size distribution and volatile content of the resin.
    Additional Material: 3 Ill.
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