ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • Chemistry  (251)
  • STRUCTURAL MECHANICS  (52)
  • ASTROPHYSICS
  • 1970-1974  (303)
  • 1970  (303)
Collection
Publisher
Years
  • 1970-1974  (303)
Year
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 293-299 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The laminar, isothermal entrance region flow of the Bingham fluid in a circular pipe is studied at first by using the momentum integral method and the boundary-layer equation for the Bingham fluid. In addition to the velocity boundary layer, the existence of the shear stress boundary layer is considered. The solution is valid only near the entry because of limitation of the boundary-layer model. The Campbell-Slattery method originally devised for the Newtonian fluid is also used to analyze the Bingham entrance region flow. The results are compared with those obtained through the use of the momentum integral method and those obtained through the use of the variational method by other investigators. While the results obtained in this work appear to be generally reasonable and valid, the results by the other investigators have been found to be somewhat erroneous.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 2
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 21 (1970), S. 613-629 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Review of electrochemical methods of studying hydrogen embrittlement and stress corrosion crackingIn this review the authors presents the features common to both types of failure and the features by which the two types of failure are different from each other. In this context it is emphasized, that the hydrogen absorption - essential for embrittlement - can be regarded as a side reaction accompanying the particular overall reaction, and that the particular reaction conditioned and the structure of the metal play an important part. Different methods for investigating the hydrogen context and the state of the hydrogen (atomic, ionic, molecular) in the metal are described, and soo are methods for studying internal stresses due to hydrogen absorption. As to stress corrosion cracking it is shown that the processes involved are not a separate mechanical and a separate chemical one, but that the joint action of both is important. In this context it is shown, however, that this view can be considered to be established in th e case of austenitic steels only.
    Notes: Der Verfasser zeigt in diesem Übersichtsartikel die Faktoren, in denen die beiden Schadensarten übereinstimmen bzw. sich unterscheiden. Hierbei wird davon ausgegangen, daß die für die Versprödung entscheidende Wasserstoffaufnahme als eine die jeweilige Gesamtreaktion begleitende Nebenreaktion angesehen werden kann, wobei die jeweiligen Reaktionsbedingungen und das Gefüge des Metalls eine Rolle spielen. Die verschiedenen Methoden zur Untersuchung des Wasserstoffgehalts bzw. des Wasserstoffgehalts im Metall (atomar, als Ion, molekular) werden beschrieben, ebenso Methoden zur Untersuchung der durch Wasserstoff hervogerufenen inneren Spannungen. Hinsichtlich der Spannungsrißkorrosion wird gezeigt, daß es sich hierbei nicht um getrennte mechanische und chemische Vorgänge handelt, sondern daß das Zusammenwirken der beiden entscheidend ist. In diesem Zusammenhang wird allerdings darauf hingewiesen, das diese Ansicht nur für die austenitischen Stähle eindeutig festgestellt ist.
    Additional Material: 28 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 3
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Extended culture, a special type of semicontinuous culture, permits prolonged maintenance of a constant or programmed environment in a growing culture by a controlled addition of one or more substrates. Differences between extended culture and continuous culture data are a measure of differences in the properties of cell populations with different cell age distributions but identical steady-state environments. Both extended culture and continuous culture were used to study the growth kinetics of Candida utilis (ATCC 9226) under conditions of substrate inhibition at controlled concentrations of sodium acetate in a carbon-limited mineral salts medium supplemented with 0.01 g/1 yeast extract. Acetate concentrations ranged from 1.2 g/l to 10.8 g/l (expressed as acetic acid), while yeast concentrations varied from 0.3 to 7.8 (g dry cells)/1. Rate parameters such as growth yields (Y), specific growth rates (μ), and linear growth rates (K), were calculated by computer from the data and theory presented herein. Specific growth rates as high as 0.54/hr were observed, although extended culture growth was more nearly linear than exponential in these experiments. Growth yields usually varied between 0.2 and 0.4 (g dry cells)/(g acetate), although values were as high as 0.8 for a brief period during one experiment. Growth yields at a given acetate concentration were correlated by an equation of the form 1/Y = 1/YG + m/μ. A maintenance coefficient (m) of 0.17 (g acetate)/(g dry cell-hr) was observed at acetate concentrations of 4.5 and 10. g/1. A typical maximum growth yield (YG) of 0.51 (g dry cell)/(g acetate) was obtained at 4.5 g/1 acetate, but an unusually high YG of 1.33 was found at 10. g/1 acetate. Oxygen uptake measurements are compared with these cell yield measurements. Linear growth rates in expended culture were correlated by the equation K = 0.89-0.70 (S/S0) where K has units of (g dry cell)/(l-hr), S is the instantaneous acetate concentration, and S0 is the initial acetate concentration. The extended culture kinetic data are shown to be substantially different from continuous culture kinetic data. Reason for these differences are discussed in light of diffrences in the cell age distributions, as well as possible differences in experimental conditions.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 14 (1970), S. 2905-2920 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Cotton fiber was treated with aqueous trimethylbenzylammonium hydroxide (Triton B) at concentrations over the range 25%-40%. After complete removal of the swelling agent, the samples were evaluated for the extent of swelling, strength and elongation, birefringence, moisture regain, density, crystallinity, x-ray diffraction patterns, and microfibrillar morphology. Electron-microscopical examination and other evaluation of fine structure properties revealed that the nature of swelling is intercrystalline up to 30% concentration of Triton B, and intracrystalline beyond that. Although the swelling as measured by propanol-2 retention after treatment with 30% Triton B is about twice as much as that of the control, the original structure remains almost unchanged except for some gain in strength and elongation and increase in moisture regain. At 32% Triton B concentration and beyond, rapid decrystallization takes place, accompanied by a fall in birefringence, density, and crystallinity index. X-Ray analysis showed significant loss of lateral order and partial conversion of cellulose I to cellulose II at 35% and 40% Triton B concentrations. The results indicate that, used at the critical concentration of 30%, Triton B can be a useful swelling agent for cotton fibers as it opens up the fine structure of cellulose considerably without impairing any important physical properties.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 14 (1970), S. 3049-3063 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Rate of molecular bond rupture is successfully correlated by a Griffith-type energy balance to the strain energy release rate during ozone cracking of rubber. Rate of bond rupture is determined from electron paramagnetic resonance (EPR) measurements. The rate of strain energy release is determined from stress-elongation measurements during stress relaxation, creep, and cyclic loading tests. To compare with macroscopic crack studies, it was assumed that each ruptured bond created a given amount of fracture surface. Numerical agreement could be obtained by assuming each broken bond results in the production of an area of approximately 10-13 cm2. Using the surface energy density determined from stress relaxation tests in an energy balance gives surprisingly accurate predictions of expected behavior in creep and cyclic loading tests. There is a one-to-one correspondence between the rate of crack growth (bond rupture) and rate of energy release from strain and external work in all cases. It is proposed that such correlations give credence to a Griffith-type approach to environmental cracking which it did not have previously.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 6
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The mass spectra of hexanal, heptanal and nonanal variously labeled with deuterium confirm γ-hydrogen migration and β cleavage as the mechanism leading to [C2H4O]+· and [M — C2H4O]+·, although the data on the latter are complicated by contributions from other, related paths. In addition, they show that three other major primary decomposition products, [M — C2H4]+·, [M — H2O]+· and [C3H5O]+, all arise in large part by processes involving γ-hydrogen migration to the oxygen atom. The ethylene lost to yield the first of these products consists of the α and β methylene groups. The loss of ethylene most likely occurs by way of a cyclobutanol intermediate, which, via alternative reaction paths, may well contribute to the yields of the other two products as well. These findings further extend the range of parallelism between photochemical and electron-impact-induced reactions.
    Additional Material: 8 Tab.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 7
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 3 (1970), S. 1255-1258 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Evidence suggesting elimination of carbon dioxide as a decomposition path for tris(1-phenyl-4,4,4-trifluoro-1,3-butandionato) iron (III) [Fe(btac)3] and tris (1-thienyl-4,4,4-trifluoro-1,3, butandionato) iron (III) [Fe(ttac)3] is presented and discussed. A mechanism is proposed for this reaction. Other examples of CO2 elimination are observed for substituted phenyl Fe(btac)3, tris(1-cyclopropyl-4,4,4-trifluoro-1,3-butandionato) iron (III) and Co(III) (btac)3.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 8
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 4 (1970), S. 237-240 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: This paper describes the mass spectra of some di-trimethylsilyl derivatives of aromatic amines. Numerous doubly-charged ions of low relative intensity are found in all spectra. An intense doubly-charged ion is found at m/e [M - 30]/2, whereas the singly-charged counterpart is very small in all cases.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 9
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 4 (1970), S. 353-359 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The study of 19-substituted derivatives of α and β3-fluoro 17β acetoxy 5-androstene shows important differences in the fragmentation pattern according to the substitution and to the stereochemistry of the fluorine.
    Notes: L'étude de dérivés substitués en 19 des fluoro-3 α et β acétoxy-17β androsténe-5 montre des différences importantes dans la fragmentation selon la substitution et selon la stéréochimie du fluor.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 10
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 4 (1970), S. 343-352 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: A series of 6-β substituted derivatives of α and β 3-fluoro 17β-hydroxy (or acetoxy)-5(10) estrene were studied by mass spectrography. The influence of the substitution as also the stereochemistry of fluorine were discussed.
    Notes: Une série de dérivés substitués en 6β des fluoro-3α et β hydroxy ou acétoxy-17β estrénes-5(10) a été étudiée par spéctrographie de masse. L'influence de la substitution ainsi que la stéréochimie du fluor ont été discutées.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...