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  • Polymer and Materials Science  (120)
  • 1960-1964  (120)
  • 1964  (120)
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 8 (1964), S. 1607-1617 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: By means of interfacial polycondensation, ultrathin coatings of polyamides, polyurethanes, polyureas, polyesters, polycarbonates, and various copolymers can be formed on the surface of a substrate. If the substrate contains reactive groups (such as —NH2, —OH, —NCO, —COCl, etc.), graft polymer is formed. The graft polymer is not removed by extensive extraction with good solvents for the polymer. In contrast, if wool is used as a substrate and is acetylated prior to the polymerization (to block the grafting sites), the thin coating of polymer is readily extracted. Digestion of the treated wool with enzymes that react with the wool, but not with the grafted coating, permits a characterization of the grafted polymer; amino acid analysis of the residue from the enzyme digestion provides evidence that the grafting sites on the wool are probably the free amino and hydroxyl groups located in the N-terminal amino acids or internal amino acids containing these groups in their side chain.
    Additional Material: 12 Tab.
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 8 (1964), S. 1985-1989 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A new method for hydroxyl analysis is described in which excess toluene diisocyanate is reacted with a hydroxy compound, preferably in the presence of a catalyst, and the unreacted isocyanate is determined with dibutylamine reagent. The method is particularly applicable to polyethers intended for urethane foam preparation. It is rapid, is accurate, and has the added advantage of including such impurities as would be expected to consume isocyanate during a foam preparation.
    Additional Material: 1 Tab.
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 8 (1964), S. 2239-2247 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This work is a continuation in these laboratories of the study of the source of undesirable optical properties of molded cellulose acetate. The origin, mechanism of formation, and structure of the colored compounds formed upon heating cellulose acetate in the presence of plasticizer were studied. Extraction of heated mixtures gave evidence indicating the colored compounds are intermediates containing a conjugated carbonyl group. Efforts to fractionate and isolate color-causing fractions were defeated by the well-known solvent inclusion difficulties and upset of the little-understood salt balance in the sample. The effects of additives known to degrade cellulose acetate were determined by heating mixtures of these materials with cellulose acetate dissolved in excess plasticizer. Acidic compounds caused the expected severe degradation and color formation. Air oxidation and free radical initiators had very little effect compared to the acidic materials. Inhibitors of the action of acidic compounds (neutralizers) and of oxidative degradation were studied.
    Additional Material: 7 Tab.
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  • 4
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The kinetics of the depolymerization of native dextran in dilute hydrochloric acid at different temperatures has been followed by measurements of M̄w, M̄n, [η], 〈ρ2〉1/2, and S. The data allow the correlation of the various parameters of the total hydrolyzate at various degrees of depolymerization. At a first approximation the results conform to a random splitting of a statistical, branched polymer.
    Additional Material: 5 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A: General Papers 2 (1964), S. 3067-3074 
    ISSN: 0449-2951
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Equal radiation yields of hydrogen are obtained from bulk polyethylene and thin films of solution crystallized polyethylene, with a G value of 4.6. The corresponding value for very thick mats of the solution crystallized material is 3.4. Reasoning from material balance considerations indicates that the yield of radiation-induced crosslinking for bulk and thin films is about twice that for thick mats of polyethylene. It is suggested that thin films and thick mats differ only in fold surface contact, and that crosslinking is preferential at the folds. The retention of xylene between fold surfaces following crystallization is compatible with the effect of irradiation on trapped solvent.
    Additional Material: 1 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A: General Papers 2 (1964), S. 45-55 
    ISSN: 0449-2951
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: 1,5-Diamino-2,4-ethylenehexamethyltrisilazane and related compounds were prepared by treating the corresponding chlorosilane intermediates with ammonia or an amine. When these monomers were heated in xylene solution at 140°C. in the presence of ammonium sulfate, linear silicon-nitrogen polymers were obtained with molecular weights in the range of 7,500-15,000. Elemental analyses, infrared spectra, and the physical properties of the polymers support the proposed structure and polymerization route.
    Additional Material: 6 Tab.
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 15 (1964), S. 27-30 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: The corrosion behaviour of cast aluminium bronzesCast aluminium bronzes are cast alloys consisting of at least 70 pC copper, with aluminium as the principal alloying material. In the form of multi-alloy aluminium bronzes, they also contain iron, nickel, manganese and silicon. They are distinguished by a number of favourable properties, including a high corrosion resistance.Special, non-standard “Inoxyda” aluminium bronzes have been subjected to corrosion tests. The results show that the choice of the alloying materials must depend on the liquid media in contact with the materials. Fullest success in technical applications can only be attained if the metal becomes covered by a dense, adhesive and non- porous protective layer, depending on the material and liquid, respectively. Each individual case must therefore be carefully innvestigated.
    Notes: Guß-Aluminiumbronzen sind Gußlegierungen aus mindestens 70% Cu und dem Hauptlegierungszusatz Aluminium. Als Guß-Mehrstoff-Aluminiumbronzen enthalten sie außerdem noch Eisen, Nickel, Mangan sowie Silicium. Eine Reihe günstiger Eigenschaften zeichnen sie aus, darunter auch gute Korrosionsbeständigkeit. Von den Normen abweichende Sonder-Aluminiumbronzen „Inoxyda“ wurden für Korrosionsversuche verwendet. Aus deren Ergebnissen geht hervor, daß die Wahl der Legierungszusätze den flüssigen Medien zu treffen ist, die mit den Werkstoffen in Berührung kommen. Die beste Bewährung bei Einsatz in deu Technik wird nur dann erreicht, wenn sich auf dem Metall jeweils eine dichte, festhaftende und porenfreie werkstoff- bzw. flüssigkeitsgebundene Schutzschicht bildet. Jeder Einzelfall ist deshalb genau zu prüfen.
    Additional Material: 5 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 15 (1964), S. 743-753 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Corrosion and acid resistant chromenickel steels with a maximum carbon content of 0.030% as a construction material for the chemical industryA report is given of studies concerning the structural stability and corrosion resistance of different austenitic corrosion and acid resistant steels, with special attention to their welding properties.Austenitic chrome-nickel steels tend to inter-crystalline corrosion after prolonged tempering at 500 to 700° C; such temperatures are encountered, inter alia, during welding.Steels with particularly low carbon content (maximum 0.030 pC, ELC steels) do not tend to inter-crystalline corrosion except after tempering periods exceeding ten hours, which do not occur during welding. Tic and NbC are not stable above 1200 to 1300°C so that, with stabilized steels, some very narrow zones along the weld will show a tendency to inter-crystalline corrosion, known as “knife edge attack”.For metallurgical reasons, the ELC steels have good weldability properties. Niobium-stabilised steels can be made brittle by niobides especially by those variants alloyed with molybdenum. Titanium-stabilised steels yield a comparatively viscous melt during welding, and may thus give rise to welding defects.ELC steels have a higher resistance to nitric acid than stabilised steelsThe mechanical strength o f ELC steels is somewhat lower than that of stabilised steels, but their strength can be improved by adding nitrogen.Some more recent varieties of ELC steels are discussed, together with examples of their application in the chemical industry.
    Notes: Studien mit Rücksicht auf die Gefügestabilität und die Korrosionsbeständigkeit von verschiedenen austenitischen rost- und säurebeständigen Stählen werden dargelegt. Spezielle Aufmerksamkeit wird den Schweißeigenschaflten der Stäble gewidmet.Austenitische Chrom-Nickel-Stable neigen zu interkristalliner Korrosion nach langdauerndem Anlassen bei 500 bis 700° C. Anlassen bei 500 bis 700° C erhält man u.a. beim Schweißen.Die extra niedriggekohlten Stähle mit max 0,030% C (ELC-Stähle) neigen nur zu interkristalliner Korrosion nach längeren Anlaßzeiten als 10 h, was aber beim Schweißen nicht vorkommt. TiC und NbC sind oberhalb 1200 bis 1300°c nicht stabil und bei stabilisierten Stählen neigen as darum sehr enge Zonen entlang der Schweißnaht zu interkristalliner Korrosion, sog. Meserlinienangriff.Die ELC-Stähle haben gute metallurgisch bedingte Schweißbarkeit. Niobstabilisierte Stähle können durch Niobide versprödert werden, besonders die molybdänlegierten Varianten. Die titanstabilisierten Stähle geben eine verhältnismäßig zähflüssige Schmelze beim Schweißen und können hierdurch Schweißfehler hervorrufen.Die ELC-Stähle sind in Salpetersäure beständiger als die stabilisierten Stähle.Die ELC-Stäble haben etwas niedrigere Festigkeit als die stabilisierten Stähle. Die Festigkeit kann durch Stickstoffzusatz noch verbessert werdenEinige neue ELC-Stäble werden dargestellt und Beispiele der Verwendung in der chemischen Industrie werden gegeben.
    Additional Material: 11 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 8 (1964), S. 489-501 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: In recent years thermosetting polymeric systems have been used extensively as binders in electrical insulation and composite plastic structures with excellent success. However, such properties as post-cure gassing, thermal stability, and high temperature bond strength have always been stumbling blocks for the insulation engineer. Experience has shown that these properties can ultimately affect the dielectric endurance of an insulation when subjected to high voltage stresses. The above-mentioned problems are generally controlled by the organic binders present in the insulation. Test methods have been developed whereby the behavior of the polymers under certain conditions can be predicted, thus increasing the effectiveness of the design engineer.
    Additional Material: 11 Ill.
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  • 10
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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