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  • Chemical Engineering  (23)
  • STRUCTURAL MECHANICS
  • ASTROPHYSICS
  • 1980-1984
  • 1970-1974
  • 1965-1969
  • 1960-1964  (24)
  • 1961  (24)
Collection
Publisher
Years
  • 1980-1984
  • 1970-1974
  • 1965-1969
  • 1960-1964  (24)
Year
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 7 (1961), S. 551-558 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effect of design and operational variables on the performance of one type of hydrogen-oxygen ion exchange membrane fuel cell has been studied. Only the results of cells based on a phenolsulfonic acid formaldehyde type of ion exchange membrane containing one type of reinforcement are described. Platinum, palladium, iridium, and rhodium are adequate electrode materials for room-temperature operation. Performance of cells with platinum gauze current collectors bonded to the cell surfaces was only slightly better than that with external contacts about 1 cm. apart.Open circuit voltages range from 0.9 to 1.1 v. (theoretical 1.23) depending on the catalyst. The typical current at 0.5 v. is 30 ma./sq. cm. Better cells have delivered 80 ma./sq. cm. at 0.5 v. Life tests indicate that these cells can be expected to deliver a minimum of about 40 amp.-hr./sq. cm., when operated in the load range 8.5 to 230 ohm sq. cm., before failure of the electrolyte owing to pinhole formation. Current efficiency is very nearly 100%. Cell performance vs. temperature in the range 0° to 85°C. shows a maximum at about 55°C.
    Additional Material: 24 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 7 (1961), S. 663-665 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In predicting interfacial area in liquid-liquid systems there are several published reports which give different results. Differences in methods of measurement of interfacial area and impeller design and location account for some of these discrepancies.For one pair of liquids, 40 parts by volume of ethylhexanol and 60 parts water, it was found that over wide ranges of impeller size to tank size ratio (0.27 to 0.67) that equal power per unit volume gave equal interfacial area per unit volume.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 73-79 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This article includes a comparison of the adhesive properties of bisphenol-A expoxides at 300°K and 76°K with respect to the molecular weight of the uncured resins. Joints of 2024 aluminum were tested at 300°K and 76°K in tensile-shear and in impact-shear, and total linear thermal contraction of the cured resins was measured between the two temperatures. Results are discussed with respect to residual joint stresses and adsorptive properties of the resins.
    Additional Material: 9 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 63-67 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A new method for measuring heat stability and temperature of degradation of thermosetting plastics is described, as well as an improved method for the determination of transition temperature into glassy or viscous state for thermosetting resins. Magnitude of elastic deformation is tied in with length of polymer chain and lattice density.
    Additional Material: 11 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 121-132 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The mechanism of formation of tubular polythene film is a complicated process, and extensive studies have shown that the properties of the film made are influenced profoundly and in a complex way both by the processing conditions used by certain design features of the equipment. Studies of the effect of the extrusion variables on the more important film properties, both optical and mechanical, are reviewed in this paper. The results are discussed in terms of the fundamental nature of polythene film, its surface, its crystalline structure and its orientation.
    Additional Material: 12 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 181-190 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Adsorption studies on powdered and planar surfaces yield significant information regarding the rate and degree of interaction between the substrate and the organic adsorbate. Investigative tools include contact angle measurement, radiotracer methods, ellipsometry, x-ray diffraction, electron diffraction, elegant infrared techniques, dynamic desorption techniques, and film balance applications.
    Additional Material: 14 Ill.
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  • 7
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A theory of design of chemical reactors is developed for two-phase fluid systems where the rates of chemical reaction are low relative to the rates of mass transfer. Equations are presented for batch, column, and continuous stirred tank operations. Experimental data on the continuous hydrolysis of acetic anhydride in a benzene-water system operating countercurrently in a pulsed-flow sieve plate column and in a packed column are analyzed in terms of the theory.
    Additional Material: 5 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 7 (1961), S. 199-202 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Glass cylinders and spheres were crushed by slow compression in a hydraulic press. In all experiments the elastic energy stored in the specimen prior to fracture was measured. In some experiments the surface area of the resultant powder was measured by gas adsorption; in others the heat generation upon fracture was measured. The latter experiments show that considerable additional energy is fed into the fracturing specimen from the press. Local stress concentrations, and hence energy level at fracture, varied widely with particle shape. Calorimetric experiments suggest that real differences in crushing effectiveness, that is new surface per unit actual work done on the specimen, do occur. These differences are not due directly to the magnitude of the energy fed in from the press but rather to the effectiveness with which the stored or feed-in energy is used.
    Additional Material: 4 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 7 (1961), S. 524-526 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 7 (1961), S. 631-634 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The liquid film coefficient is related to bubble diameter and velocity in pure water and to the physical properties of the liquid. The addition to water of organic substances which influence the surface tension and viscosity will decrease the size of the air bubble released from a diffuser and reduce the transfer of oxygen into the solution. The maximum reduction in oxygen transfer occurs in the region of maximum surface tension change. The effect of the addition of several organic substances on the oxygen transfer characteristics are shown.
    Additional Material: 9 Ill.
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