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  • Chemical Engineering  (15)
  • GENERAL  (11)
  • Inorganic Chemistry  (5)
  • Industrial Chemistry  (2)
  • 1955-1959  (33)
  • 1945-1949
  • 1955  (33)
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  • 1955-1959  (33)
  • 1945-1949
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  • 1
    Publikationsdatum: 2011-08-16
    Schlagwort(e): GENERAL
    Materialart: NACA Conf. on Aerodyn. of High Speed Aircraft; p 93-103
    Format: text
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    ISSN: 0009-286X
    Schlagwort(e): Chemistry ; Industrial Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Die Anwendung des erweiterten Korrespondenzprinzips zur Berechnung unbekannter thermischer Daten setzt die Kenntnis der kritischen Größen des betreffenden Stoffes voraus. Auf die Möglichkeit der Bestimmung des kritischen Druckes, zugleich mit dem kritischen Parameter (aus zwei Punkten der Dampfdruckkurve), sowie des kritischen Volumens (aus einem Meßwert für die Flüssigkeitsdichte) bei bekannter kritischer Temperatur wurde bereits früher (Teil I bzw. II) hingewiesen. Nun wird gezeigt, daß sich ohne Verwendung weiterer Meßergebnisse auch die bisher schwer zugängliche kritische Temperatur mit verhältnismäßig großer Genauigkeit ermitteln läßt, wenn man die Abhängigkeit des kritischen Koeffizienten vom kritischen Parameter berücksichtigt. Ein graphisches Verfahren erleichtert die praktische Durchführung dieser Bestimmung und gestattet, auch andere gemessene Daten für den gleichen Zweck auszuwerten.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Experimental information concerning the molecular transport of the lighter hydrocarbons in the gas phase is limited. For this reason a study was made of the Maxwell diffusion coefficients of n-hexane in the gas phase of the methane-n-hexane, and propane-n-hexane systems.Maxwell diffusion coefficients were determined at steady state for pressures up to 70 lb./sq. in. at temperatures between 70° and 220° F. The effects of interfacial resistance were considered and uncertainties as to the behavior at the end of the transport path were eliminated. Coefficients were reported with partial pressure and with fugacity as the potential. Fick diffusion coefficients were calculated for each component on the assumption that the gas phase was an ideal solution.These data indicated that the Maxwell hypothesis with fugacity as the potential in an ideal solution is a fair description of the transport characteristics of the lighter hydrocarbons in the gas phase at relatively low pressures. A regular decrease in the Maxwell diffusion coefficient with an increase in the molecular weight of the stagnant component was observed.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The data in the first paper of this series on the distribution of momentum and energy in nonisothermal air streams mixing in a straight duct were correlated by the methods described in the second paper. Mixing indexes were evaluated and used to correlate profiles of total momentum and stagnation temperature at various sections of the duct.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A heated jet of air from an 0.898-in. standard A.S.M.E. nozzle was discharged into a 4-in. steel duct, well insulated over its entire 10-ft. length. Air from the region surrounding the nozzle was entrained into the duct. At a number of points along the duct, radial profiles of air velocity and temperature were obtained by means of a probe which combined an impact tube and a thermocouple. The temperature at each of several points along the duct wall was indicated by thermocouples imbedded in the wall.In the experiments reported here the velocity at the jet was 585 ft./sec.; the temperature of the jet was about 220°F. and that of the entrained air was about 88°F. The total air flow rate through the duct was 0.67 lb./sec., and the heat flux was 4.9 B.t.u./sec., with the temperature of the entrained air taken as the datum.The radial and axial profiles of velocity and temperature are compared and discussed; the temperatures of the stream near the duct wall and of the duct wall itself are given. Conservation of mass and heat was checked by graphical integration of the radial profiles.
    Zusätzliches Material: 15 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: This paper concerns the kinetics of the processes that take place when a high-velocity jet of fluid mixes turbulently with a low-velocity, induced stream of the same fluid in a duct of uniform diameter. Semi-two-dimensional solutions of the equations of transport involving two empirical coefficients were obtained by application of Reichardt's hypothesis and three assumptions: (a) a negligible fraction of the flow entity (energy, mass, or momentum) is lost at the wall and the presence of the boundary layer may be ignored, (b) the static pressure is uniform over a section of the duct, and (c) the turbulence pattern is similar to that in free jets except that the duct wall limits the growth of the scale of the turbulence. A mixing index, which is a measure of the degree to which the jet stream remains unmixed with the induced stream at any point, was defined and related to the geometry of the system and the flow parameters by means of the theoretical equation, and a method of evaluating the empirical coefficients for a typical case of momentum transport was described.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 1 (1955), S. 74-77 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Various laws of corresponding states are examined briefly in this paper to show the corrections that are in common use to increase the accuracy of forecasting compressibility factors. Two trends are noticeable: (I) the use of specific compressibility charts with the results generalized for all gases either by corrections related to z (the compressibility factor at the critical point) or by the use of pseudocritical properties and (2) the use of a true generalized chart based upon averaged data. It is shown that the selection of the plot parameters affects the accuracy of the generalized chart. In recent years reduced parameters based upon kinetic theory have been proposed but for a restricted class of gases (nonpolar gases with spherically symmetrical molecules and negligible quantum effects). It is shown that the kinetic parameters are directly related to the critical constants and also that the kinetic parameter charts can be used for all gases without serious loss of accuracy.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 1 (1955), S. 118-124 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The kinetics of the catalytic and noncatalytic hydration of propylene oxide were studied in a continuous reactor. Both the catalytic and noncatalytic reaction were studied over a temperature range of 100° to 300°F. The feed ratios ranged from 2.5 to 10 lb. water/lb. propylene oxide. In the case catalytic reaction, the catalyst concentration of sulfuric acid ranged up to 0.25 wt. % of the total feed.The study showed the noncatalytic reaction to be pseudo first order with respect to propylene oxide, and an equation was found for the rate constant. The catalytic reaction was found to be pseudo second order with respect to propylene oxide, and the effect of the catalyst concentration is shown graphically.
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 1 (1955), S. 125-128 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The characteristics of five Herschel-type Venturi tubes with throat diameters ranging from 0.073 to 0.359 in, and throat-to-pipe - diameter ratios from 0.0882 to 0.4340 have been investigated.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The absorption and subsequent liquid-phase reaction of oxygen was studied with two types of dispersion apparatus, the Venturi atomizer and the fritted-glass disperser. The systems studied in both devices included the absorption of atmospheric oxygen by catalyzed sodium sulfite solutions and the simultaneous absorption of atmospheric oxygen with nitrogen dioxide and with sulfur dioxide by water.Very large values of the liquid-film mass transfer coefficient for oxygen absorption were measured in the atomization zone of the Venturi atomizer. Over-all recovery efficiencies were less than 2.3% for nitrogen dioxide but reached as much as 22% for sulfur dioxide. Oxidation efficiencies for sodium sulfite solutions ranged up to 80%, depending on the operating conditions.The fritted-glass disperser gave recovery efficiencies of nitrogen dioxide as high as 90% from air containing 10% of the gas. The recovery efficiency decreased at low concentrations of nitrogen dioxide for both the Venturi atomizer and the fritted-glass disperser.
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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