ALBERT

Description: This article shows the research carried out by the authors focused on how the shape of structural reinforced concrete elements treated with electrochemical chloride extraction can affect the efficiency of this process. Assuming the current use of different anode systems, the present study considers the comparison of results between conventional anodes based on Ti-RuO2 wire mesh and a cement-based anodic system such as a paste of graphite-cement. Reinforced concrete elements of a meter length were molded to serve as laboratory specimens, to closely represent authentic structural supports, with circular and rectangular sections. Results confirm almost equal performances for both types of anode systems when electrochemical chloride extraction is applied to isotropic structural elements. In the case of anisotropic ones, such as rectangular sections with no uniformly distributed rebar, differences in electrical flow density were detected during the treatment. Those differences were more extreme for Ti-RuO2 mesh anode system. This particular shape effect is evidenced by obtaining the efficiencies of electrochemical chloride extraction in different points of specimens.

Description: The Holocene, Ahead of Print. 〈br/〉

Description: The Holocene, Volume 29, Issue 2, Page 300-312, February 2019. 〈br/〉

Description: Central Chile is heavily exploited for mineral and water resources, with agriculture and large urban populations all creating intensive landscape use. Few records of past environmental and climate change are available that afford a broader context. To aid in this assessment, we present a 700-year reconstruction from Laguna del Maule (LdM) in the high Andes of central Chile based on sedimentological, geochemical, diatom and pollen analyses. The age model is based on 210 Pb/ 137 Cs and 14 C dating tied into known volcanic eruptions. Sedimentology consists of organic-rich sediments and diatom oozes with several interspersed volcanic-rich facies and two tephra deposits. Sediment geochemistry exhibits increased productivity (high Br/Ti, biosilica) and more dominant oxic conditions (high Fe/Mn) from AD 1300 to 1400 and from AD 1650 to 1850, likely during periods of relatively lower lake levels and better development of littoral environments. However, during this later period, high elevation vegetation was dominant, indicative of regional cooler/wetter conditions. In contrast, sediments deposited from AD 1850 to 1930 evidence decreased productivity and increased anoxic lake bottom conditions. The ‘Little Ice Age’ (LIA) in LdM is characterized by significant variations in lake dynamics and hydrology with cooler/wetter conditions (AD 1570–1700), major environmental changes in the 18th century and ending at ca. AD 1850. LdM record documents the impact of the LIA in the southern hemisphere and stresses the global nature of this climate period. Large changes in lake dynamics and diatoms assemblages during the 20th century could be related to anthropogenic impacts, but recent changes in climate patterns cannot be excluded.

Description: In recent years, several researchers have shown the good performance of alkali activated slag cement and concretes. Besides their good mechanical properties and durability, this type of cement is a good alternative to Portland cements if sustainability is considered. Moreover, multifunctional cement composites have been developed in the last decades for their functional applications (self-sensing, EMI shielding, self-heating, etc.). In this study, the strain and damage sensing possible application of carbon fiber reinforced alkali activated slag pastes has been evaluated. Cement pastes with 0, 0.29 and 0.58 vol % carbon fiber addition were prepared. Both carbon fiber dosages showed sensing properties. For strain sensing, function gage factors of up to 661 were calculated for compressive cycles. Furthermore, all composites with carbon fibers suffered a sudden increase in their resistivity when internal damages began, prior to any external signal of damage. Hence, this material may be suitable as strain or damage sensor.

Description: A multiproxy study of a 7 m long sedimentary sequence from Lake La Parra (39°50.948', 1°52', 1014 m a.s.l.) supported by 11 14 C AMS and 210 Pb/ 137 Cs dates provides a robust, high-resolution hydrological and environmental variability record for the last 1600 years of the Las Torcas sinkhole Complex in the Central Iberian Range. The succession of depositional environments in Lake La Parra sinkhole is controlled by both changes in the regional water table and by the balance between sedimentary input through ephemeral creeks and in-lake production of carbonates and organic matter. Although synergetic links with climate are likely, phases of increased sediment delivery to the lake at c . ad 500–700, c . ad 1000, ad 1450–1500, ad 1550–650 and since 1700 till recent times are driven primarily by human impact in the watershed. Prior to c . ad 300, the sinkhole was dry, then became a lake at the end of the Roman Period ( ad 350) when the doline was flooded, and it has not dried out during the last 1600 years. Moderate lake levels with deposition of coarser clastic facies dominated up to the 12th century ( ad 400–1200), and relatively higher levels with deposition of laminated facies during the 13th–15th centuries ( ad 1200–1600). The pattern of palaeohydrological evolution at a centennial scale is roughly coherent with most Iberian lacustrine records; however, the ‘La Parra’ sequence indicates that increased humidity during Iberian–Roman times was restricted to southern Spain and the humid phases of the ‘Little Ice Age’ (‘LIA’) starting and ending earlier in the central Iberian Range compared with the Pyrenean Domain and southern Spain. This new sequence highlights the heterogeneity through space and time of the main dry and wet climatic periods at shorter scales, emphasizing the impact of latitudinal climate gradients on the Iberian Peninsula climate variability.

Description: The main strategy to reduce the environmental impact of the concrete industry is to reuse the waste materials. This research has considered the combination of cement replacement by industrial by-products, and natural coarse aggregate substitution by recycled aggregate. The aim is to evaluate the behavior of concretes with a reduced impact on the environment by replacing a 50% of cement by industrial by-products (15% of spent fluid catalytic cracking catalyst and 35% of fly ash) and a 100% of natural coarse aggregate by recycled aggregate. The concretes prepared according to these considerations have been tested in terms of mechanical strengths and the protection offered against steel reinforcement corrosion under carbonation attack and chloride-contaminated environments. The proposed concrete combinations reduced the mechanical performance of concretes in terms of elastic modulus, compressive strength, and flexural strength. In addition, an increase in open porosity due to the presence of recycled aggregate was observed, which is coherent with the changes observed in mechanical tests. Regarding corrosion tests, no significant differences were observed in the case of the resistance of these types of concretes under a natural chloride attack. In the case of carbonation attack, although all concretes did not stand the highly aggressive conditions, those concretes with cement replacement behaved worse than Portland cement concretes.

Description: The Marboré Cirque, which is located in the southern Central Pyrenees on the north face of the Monte Perdido Peak (42°40'0''N; 0.5°0''W; 3355 m), contains a wide variety of Holocene glacial and periglacial deposits, and those from the ‘Little Ice Age’ (‘LIA’) are particularly well developed. Based on geomorphological mapping, cosmogenic exposure dating and previous studies of lacustrine sediment cores, the different deposits were dated and a sequence of geomorphological and paleoenvironmental events was established as follows: (1) The Marboré Cirque was at least partially deglaciated before 12.7 kyr BP. (2) Some ice masses are likely to have persisted in the Early Holocene, although their moraines were destroyed by the advance of glaciers during the Mid Holocene and ‘LIA’. (3) A glacial expansion occurred during the Mid Holocene (5.1 ± 0.1 kyr), represented by a large push moraine that enclosed a unique ice mass at the foot of the Monte Perdido Massif. (4) A melting phase occurred at approximately 3.4 ± 0.2 and 2.5 ± 0.1 kyr (Bronze/Iron Ages) after one of the most important glacial advances of the Neoglacial period. (5) Another glacial expansion occurred during the Dark Age Cold Period (1.4–1.2 kyr), followed by a melting period during the Medieval Climate Anomaly. (6) The ‘LIA’ represented a clear stage of glacial expansion within the Marboré Cirque. Two different pulses of glaciation were detected, separated by a short retraction. The first pulse occurred most likely during the late 17th century or early 18th century (Maunder Minimum), whereas the second occurred between 1790 and ad 1830 (Dalton Minimum). A strong deglaciation process has affected the Marboré Cirque glaciers since the middle of the 19th century. (7) A large rock avalanche occurred during the Mid Holocene, leaving a chaotic deposit that was previously considered to be a Late Glacial moraine.

Description: Extrusion-based additive manufacturing (EBAM) or 3D printing is used to produce customized prototyped parts. The majority of the polymers used with EBAM show moisture sensitivity. However, moisture effects become more pronounced in polymers used for critical applications, such as biomedical stents, sensors, and actuators. The effects of moisture on the manufacturing process and the long-term performance of Shape Memory Polyurethane (SMPU) have not been fully investigated in the literature. This study focuses primarily on block-copolymer SMPUs that have two different hard/soft (h/s) segment ratios. It investigates the effect of moisture on the various properties via studying: (i) the effect of moisture trapping within these polymers and the consequences when manufacturing; (ii) and the effect on end product performance of plasticization by moisture. Results indicate that higher h/s SMPU shows higher microphase separation, which leads to an increase of moisture trapping within the polymer. Understanding moisture trapping is critical for EBAM parts due to an increase in void content and a decrease in printing quality. The results also indicate a stronger plasticizing effect on polymers with lower h/s ratio but with a more forgiving printing behavior compared to the higher h/s ratio.

Description: The Holocene, Volume 28, Issue 11, Page 1685-1696, November 2018. 〈br/〉