ALBERT

Note: Contents: 1 Global Distribution of Lakes / M. MEYBECK. - 1 Introduction. - 2 Background Material and Approaches to Global Lake Census. - 2.1 Data Used. - 2.2 Approaches to Global Lake Census. - 3 General Laws of Lake Distribution. - 3.1 Lake Density . - 3.2 Limnic Ratio. - 4 Distribution of Lakes of Tectonic Origin. - 5 Lakes of Glacial Origin. - 5.1 Lake Densities. - 5.2 Global Deglaciated Area. - 5.3 Total Number of Glacial Lakes. - 6 Fluvial Lakes. - 7 Global Distribution of Crater Lakes. - 8 Global Distribution of Saline Lakes. - 8.1 Coastal Lagoons. - 8.2 Salinized Lakes due to Evaporation. - 9 Global Lake Distribution. - 9.1 Extrapolation Approach. - 9.2 Lake Type Approach. - 9.3 Climatic Typology Approach. - 9.4 Lake Distribution in Endorheic Areas. - 9.5 Global Dissolved Salt Distribution in Lakes. - 10 Major Changes in Global Lake Distribution in the Geological Past. - 10.1 Lake Ages. - 10.2 Historical Changes. - 10.3 Postglacial Changes. - 11 Discussion and Conclusions. - References. - 2 Hydrological Processes and the Water Budget of Lakes / T. C. WINTER. - 1 Introduction. - 2 Hydrological System with Regard to Lakes. - 2.1 Interaction of Lakes with Atmospheric Water. - 2.2 Interaction of Lakes with Surface Water. - 2.3 Interaction of Lakes with Subsurface Water. - 2.4 Change in Lake Volume. - 3 Summary. - References. - 3 Hydrological and Thermal Response of Lakes to Climate: Description and Modeling / S. W. HOSTETLER. - 1 Introduction. - 2 Hydrological Response. - 3 The Hydrological Budget. - 4 Hydrological Models. - 5 Thermal Response. - 5.1 Energy Budget and Energy Budget Models. - 5.2 Models and Modeling. - 6 Use of Models to Link Lakes with Climate Change. - 7 Input Data Sets. - 8 Sample Applications. - 9 Summary. - References. - 4 Mixing Mechanisms in Lakes / D. M. IMBODEN and A. WÜEST. - 1 Transport and Mixing. - 2 Lakes as Physical Systems. - 3 Fluid Dynamics: Mathematical Description of Advection and Diffusion. - 3.1 Equations of Fluid Motion. - 3.2 Turbulence, Reynolds' Stress, and Eddy Diffusion. - 3.3 Vertical Momentum Equation. - 3.4 Nonlocal Diffusion and Transilient Mixing. - 4 Density and Stability of Water Column. - 4.1 Equation of State of Water. - 4.2 Potential Temperature and Local Vertical Stability. - 5 Energy Fluxes: Driving Forces Behind Transport and Mixing. - 5.1 Thermal Energy. - 5.2 Potential Energy. - 5.3 Kinetic Energy. - 5.4 Turbulent Kinetic Energy Balance in Stratified Water. - 5.5 Internal Turbulent Energy Fluxes: Turbulence Cascade. - 6 Mixing Processes in Lakes. - 6.1 Waves and Mixing. - 6.2 Mixing in the Surface Layer. - 6.3 Diapycnal Mixing. - 6.4 Boundary Mixing. - 6.5 Double Diffusion. - 6.6 Isopycnal Mixing. - 7 Mixing and Its Ecological Relevance. - 7.1 Time Scales of Mixing. - 7.2 Reactive Species and Patchiness. - 7.3 Mixing and Growth: The Search for an Ecological Steering Factor. - References. - 5 Stable Isotopes of Fresh and Saline Lakes / J. R. GAT. - 1 Introduction. - 1.1 Isotope Separatio During Evaporation. - 2 Small-Area Lakes. - 2.1 Seasonal and Annual Changes. - 2.2 Deep Freshwater Lakes. - 2.3 Transient Surface-Water Bodies. - 3 Interactive and Feedback Systems. - 3.1 Network of Surface-Water Bodies. - 3.2 Recycling of Reevaporated Moisture into the Atmosphere. - 3.3 Large Lakes. - 3.4 Large-Area Lakes with Restricted Circulation. - 4 Saline Lakes. - 4.1 Isotope Hydrology of Large Salt Lakes. - 4.2 Ephemeral Salt Lakes and Sabkhas. - 5 Isotopie Paleolimnology. - 6 Conclusions: From Lakes to Oceans. - References. - 6 Exchange of Chemicals Between the Atmosphere and Lakes / P. VLAHOS, D. MACKAY, S. J. EISENREICH, and KC. HORNBUCKLE. - 1 Introduction. - 2 Air-Water Partitioning Equilibria. - 3 Diffusion Between Water and Air. - 4 Volatilization and Absorption: Double-Resistance Approach. - 5 Factors Affecting Mass-Transfer Coefficients. - 6 Partitioning of Chemical to Paniculate Matter in Air and Water. - 6.1 Air. - 6.2 Water. - 7 Atmospheric Deposition Processes. - 7.1 Dry Deposition. - 7.2 Wet Deposition. - 8 Specimen Calculation. - 8.1 Step 1: Physicochemical Properties. - 8.2 Step 2: Mass-Transfer Coefficients. - 8.3 Step 3: Sorption in Air and Water. - 8.4 Step 4: Equilibrium Status. - 8.5 Step 5: Volatilization and Deposition Rates. - 9 Role of Air-Water Exchange in Lake Mass Balances. - 10 Case Studies. - 10.1 Mass Balance on Siskiwit Lake, Isle Royale. - 10.2 Mass Balance on Lake Superior. - 10.3 Air-Water Exchange in Green Bay, Lake Michigan. - 10.4 Air-Water Exchange in Lake Superior. - 11 Conclusions. - References. - 7 Atmospheric Depositions: Impact of Acids on Lakes / W. STUMM and J. SCHNOOR. - Abstract. - 1 Introduction: Anthropogenic Generation of Acidity. - 1.1 Genesis of Acid Precipitation. - 2 Acidity and Alkalinity: Neutralizing Capacities. - 2.1 Transfer of Acidity (or Alkalinity) from Pollution Through the Atmosphere to Ecosystems. - 3 Acidification of Aquatic and Terrestrial Ecosystems. - 3.1 Disturbance of H+ Balance from Temporal or Spatial Decoupling of the Production and Mineralization of the Biomass. - 3.2 In Situ H+ Ion Neutralization in Lakes. - 3.3 Krug and Frink Revisited. - 4 Brønsted Acids and Lewis Acids: Pollution by Heavy Metals, as Influenced by Acidity. - 4.1 Cycling of Metals. - 4.2 Pb in Soils. - 5 Impact of Acidity on Ecology in Watersheds. - 5.1 Soils. - 5.2 Lakes. - 5.3 Nitrogen Saturation of Forests. - 6 Critical Loads. - 6.1 Critical Load Maps. - 6.2 Models for Critical Load Evaluation. - 7 Case Studies. - 7.1 Chemical Weathering of Crystalline Rocks in the Catchment Area of Acidic Ticino Lakes, Switzerland. - 7.2 Watershed Manipulation Project at Bear Brooks, Maine. - 8 Summary. - References. - 8 Redox-Driven Cycling of Trace Elements in Lakes / J. HAMILTON-TAYLOR and W. DAVISON. - 1 Introduction. - 2 Major Biogeochemical Cycles and Pathways. - 3 Iron and Manganese. - 3.1 Transformations and Cycling. - 3.2 Iron and Manganese Compounds as Carrier Phases. - 4 Sediment-Water Interface. - 4.1 Diffusive Flux from Sediments. - 4.2 Evidence of Little or No Diffusive Efflux from Sediments. - 4.3 Transient Remobilization. - 4.4 Diffusive Flux into Sediments. - 5 Pathways Involving Redox Reactions Directly: Case Studies. - 5.1 Arsenic. - 5.2 Chromium. - 5.3 239,240Pu. - 5.4 Selenium 6 Pathways Involving Redox Reactions Indirectly: Case Studies. - 6.1 137Cs. - 6.2 Stable Pb, 210Pb, and 210Po. - 6.3 Zinc. - 7 Summary and Conclusions. - References. - 9 Comparative Geochemistry of Marine Saline Lakes / F. T. MACKENZIE, S. VINK, R. WOLLAST, and L. CHOU. - 1 Introduction. - 2 General Characteristics of Marine Saline Lakes. - 3 Comparative Sediment-Pore-Water Reactions. - 3.1 Mangrove Lake, Bermuda. - 3.2 Solar Lake, Sinai. - 4 Conclusions. - References. - 10 Organic Matter Accumulation Records in Lake Sediments / P. A. MEYERS and R. ISHIWATARI. - 1 Introduction. - 1.1 Significance of Organic Matter in Lake Sediments. - 1.2 Origins of Organic Matter to Lake Sediments. - 1.3 Alterations of Organic Matter During Deposition. - 1.4 Similarities and Differences Between Organic Matter in Sediments of Lakes and Oceans. - 1.5 Dating of Lake-Sediment Records. - 2 Indicators of Sources and Alterations of Total Organic Matter in Lake Sediments. - 2.1 Source Information Preserved in C/N Ratios of Sedimentary Organic Matter. - 2.2 Source Information from Carbon-Stable Isotopic Compositions. - 2.3 Source Information from Nitrogen-Stable Isotopic Compositions. - 3 Origin and Alterations of Humic Substances. - 4 Sources and Alterations of Lipid Biomarkers. - 4.1 Alteration of Lipids During Deposition. - 4.2 Changes in Sources vs Selective Diagenesis. - 4.3 Effects of Sediment Grain Size on Geolipid Compositions. - 4.4 Source Records of Alkanes in Lake Sediments. - 4.5 Preserv

Note: Contents: Part 1: The legal and institutional framework -- The environment and international society: issues, concepts and definitions -- History -- Governance: states, international organisations and non-state actors -- International law-making and regulation -- Compliance: implementation, enforcement, dispute settlement -- Part 2: Principles and rules establishing standards -- General principles and rules -- Atmospheric protection -- Climate change -- Freshwater resources -- Biological diversity -- Oceans, seas and marine living resources -- Hazardous substances and activities, and waste -- The polar regions: antarctica and the arctic -- Part 3: Techniques for implementing international principles and rules -- Environmental impact assessment -- Environmental information and technology transfer -- Liability for environmental damage -- Part 4: Linkage of international environmental law and other areas of international law -- Human rights and international humanitarian law -- International economic law: trade, investment and intellectual property -- Future developments

Note: TABLE OF CONTENTS Preface Chapter 1. The CO2-Carbonic Acid System and Solution Chemistry Basic Concepts Activity Coefficients in Solutions Influences of Temperature and Pressure The Carbonic Acid System in Seawater Calculation of the Saturation State of Seawater with Respect to Carbonate Minerals Concluding Remarks Chapter 2. Interactions Between Carbonate Minerals and Solutions Sedimentary Carbonate Minerals Basic Concepts Characteristics of Sedimentary Carbonate Minerals Solubility Behavior of Carbonate Minerals General Considerations Calcite and Aragonite Solubility Methods for the Calculation of Equilibrium Solution Composition Under Different Conditions Surface Chemistry of Carbonate Minerals Basic Principles Adsorption of Ions on Carbonate Surfaces Carbonate Dissolution and Precipitation Kinetics Basic Principles Reaction Kinetics in Simple Solutions Reaction Kinetics in Complex Solutions Concluding Remarks Chapter 3. Coprecipitation Reactions and Solid Solutions of Carbonate Minerals General Concepts Background Information Basic Chemical Considerations Coprecipitation of "Foreign" Ions in Carbonate Minerals Examples of Coprecipitation Reactions General Models for Partition Coefficients in Carbonates Magnesian Calcite General Considerations The Fundamental Problems Experimental Observations Hypothesis of a Hydrated Magnesian Calcite Stable Isotope Chemistry General Considerations Oxygen Isotopes Carbon Stable Isotopes Concluding Remarks Chapter 4. The Oceanic Carbonate System and Calcium Carbonate Accumulation in Deep Sea Sediments An Overview of Major Processes The CO2 System in Oceanic Waters The Upper Ocean The Deep Sea Saturation State of Deep Seawater with Respect to CaCO3 Sources and Sedimentation of Deep Sea Carbonates Sources Sedimentation The Distribution of CaCO3 in Deep Sea Sediments and Carbonate Lithofacies General Considerations The Distribution of CaCO3 in Surface Sediments Factors Controlling the Accumulation of Calcium Carbonate in Deep Sea Sediments General Relations Factors Leading to Variability Near Interfacial Processes Variability of Calcium Carbonate Deposition in Deep Sea Sediments with Time Influence of Glacial Times The Impact of Fossil Fuel CO2 on the Ocean-Carbonate System Concluding Remarks Chapter 5. Composition and Source of Shoal-Water Carbonate Sediments Introduction Shoal-Water Carbonates in Space and Time Carbonate Grains and Skeletal Parts Overview and Examples Sediment Classification Depositional Environments Concluding Statement Biomineralization General Aspects Environmental Controls on Mineralogy Stable Isotopes Coprecipitation Precipitation of Carbonates from Seawater Carbonate Chemistry of Shallow Seawater Abiotic Precipitation of CaCO3 from Seawater Sources of Aragonite Needle Muds Formation of Oöids Concluding Remarks 238 Chapter 6. Early Marine Diagenesis of Shoal-Water Carbonate Sediments Introduction Some Preliminary Thermodynamic and Kinetic Considerations Very Early Diagenesis Major Diagenetic Processes Pore Water Chemistry Precipitation of Early Carbonate Cements Dissolution of Carbonates Concluding Remarks Chapter 7. Early Non-Marine Diagenesis of Sedimentary Carbonates Introduction Plate-Tectonic Controls on Diagenesis General Considerations for Early Non-Marine Diagenesis Major Types of Non-Marine Environments Water Chemistry Reactivity of Sedimentary Carbonates Major Phase Transformations The Transformation of Aragonite to Calcite Dolomite Formation Summary Remarks Mass Transfer During Diagenesis General Considerations Geochemical Constraints on Mass Transfer Beachrock Formation Lithification in the Meteoric Environment Introduction The Meteoric Environment and Cement Precipitates Bermuda: A Case Study of a Meteoric Diagenetic Environment Introduction Geological Framework Limestone Chemistry and Isotopic Composition Water Chemistry Carbonate Mass Transfer A Brief Synthesis of Meteoric Diagenesis Diagenetic Stages Effect of Original Mineralogy Climatic Effects Rock-Water Relationships Mixed Meteoric-Marine Regime Concluding Remarks Chapter 8. Carbonates as Sedimentary Rocks in Subsurface Processes Introduction P,T, and X and Carbonate Mineral Stability Subsurface Water Chemistry in Sedimentary Basins Continuous Processes Pressure Solution Dolomitization Mud to Spar Neomorphism Secondary Porosity Cementation in the Subsurface Examples of "Models" of Long-Term Diagenesis The Present Ocean Setting The Present Continental Setting Concluding Remarks Chapter 9. The Current Carbon Cycle and Human Impact Introduction Modern Biogeochemical Cycle of Carbon A Model for the Cycle of Carbon Methane and Carbon Monoxide Fluxes CO2 Fluxes Human Impact on Carbon Fluxes The Fossil Fuel and Land Use Fluxes Observed Atmospheric CO2 Concentration Increase Future'Atmospheric CO2 Concentration Trends Consequences of Increased Atmospheric CO2 Levels The Oceanic System Sources of Calcium, Magnesium, and Carbon for Modern Oceans Mass Balance of Ca, Mg, and C in Present Oceans Oceanic Mass Balance of Elements Interactive with Ca, Mg, and C Concluding Remarks Chapter 10. Sedimentary Carbonates in the Evolution of Earth's Surface Environment Introduction Sedimentary Rock Mass-Age Distributions Secular Trends in Sedimentary Rock Properties Lithologic Types Chemistry and Mineralogy Carbon Cycling Modeling Introduction and Development of a Global Model Glacial-Interglacial Changes of Carbon Dioxide Long-Term Changes of Atmospheric CO2 Phanerozoic Cycling of Sedimentary Carbonates Synopsis of the Origin and Evolution of the Hydrosphere-Atmosphere-Sedimentary Lithosphere Origin of the Hydrosphere The Early Stages The Transitional Stage Modern Conditions Concluding Remarks Epilogue Introduction The Road Traveled The State of the Art Ever Onward References Index