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  • Other Sources  (8)
  • NASA Technical Reports  (8)
  • 1985-1989  (8)
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  • Other Sources  (8)
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  • NASA Technical Reports  (8)
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  • 1
    Publication Date: 2011-08-19
    Description: Under NASA sponsorship, JPL is developing advanced, high rate Li-SOCl2 cells for future space missions. As part of this effort, Li-SOCl2 cells of various designs were examined for performance and safety. The cells differed from one another in several aspects, such as: nature of carbon cathode, catalysts, cell configuration, case polarity, and safety devices. Performance evaluation included constant-current discharge over a range of currents and temperatures. Abuse-testing consisted of shortcircuiting, charging, and over-discharge. Energy densities greater than 300 Wh/Kg at the C/2 rate were found for some designs. A cell design featuring a high-surface-area carbon cathode was found to deliver nearly 500 Wh/Kg at moderate discharge rates. Temperature influenced the performance significantly.
    Keywords: SPACECRAFT PROPULSION AND POWER
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  • 2
    Publication Date: 2016-06-07
    Description: In the development of high rate Li-SO-Cl2 cells for various applications, the goal is to achieve 300 watt-hours per kilogram at the C/2 (5 amp) rate in a D cell configuration. The JPL role is to develop the understanding of the performance, life, and safety limiting characteristics in the cell and to transfer the technology to a manufacturer to produce a safe, high quality product in a reproducible manner. The approach taken to achieve the goals is divided into four subject areas: cathode processes and characteristics; chemical reactions and safety; cell design and assembly; and performance and abuse testing. The progress made in each of these areas is discussed.
    Keywords: ELECTRONICS AND ELECTRICAL ENGINEERING
    Type: NASA. Goddard Space Flight Center The 1985 Goddard Space Flight Center Battery Workshop (date); p 117 - 130
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  • 3
    Publication Date: 2016-06-07
    Description: A series of experiments was performed on a 1.8-m-diam model rotor in hover for the principal purpose of investigating the lead-lag stability of isolated bearingless rotors. Incidental to those tests, at least three types of pitch-flap flutter were encountered. Type 1 flutter occurred approximately at the second flap-mode frequency on both two-and three-bladed rotors for both small and large pitch angles and appeared to be a classic pitch-flap flutter. Type 2 flutter showed mostly torsional motion and was seen on both two- and three-bladed rotors. Type 3 flutter was a regressing flap flutter that occurred for only the three-bladed rotor configurations and appears to be a wake excited flutter. Although flutter occurred on a number of different configurations, no rotor parameters were identified that were clearly stabilizing or destabilizing.
    Keywords: AIRCRAFT STABILITY AND CONTROL
    Type: NASA. Ames Research Center Rotorcraft Dynamics 1984; p 69-88
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  • 4
    Publication Date: 2013-08-31
    Description: JPL is developing ambient temperature secondary lithium cells for future spacecraft applications. Prior studies on experimental laboratory type Li-TiS2 cells yielded promising results in terms of cycle life and rate capability. To further assess the performance of this cell, 5 Ah engineering model cells were developed. Initially baseline cells were designed and fabricated. Each cell had 15 cathodes and 16 anodes and the ratio of anode to cathode capacity is 6:1. A solution of 1.5 molar LiAsF6 in 2Me-THF was used as the electrolyte. Cells were evaluated for their cycle life at C/1 and C/5 discharge rates and 100 percent depth of discharge. The cells were cycled between voltage limits 1.7 and 2.8 volts. The rate of charge in all cases is C/10. The results obtained indicate that cells can operate at C/10 to C/2 discharge rates and have an initial energy density of 70 Wh/kg. Cells delivered more than 100 cycles at C/2 discharge rate. The details of cell design, the test program, and the results obtained are described.
    Keywords: ENERGY PRODUCTION AND CONVERSION
    Type: NASA-Lewis Research Center, Space Electrochemical Research and Technology (SERT); p 89-95
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  • 5
    Publication Date: 2016-06-07
    Description: The goal of producing spiral wound D cell was met. The cell design and electrodes, particularly the carbon cathodes were produced in-house. Also all parts were assembled, the welding performed, the electrolyte aided and the cells sealed in-house. The lithium capacity (theoretical) was 19.3 Ah and that of the SOCl2 in the 1.8 m LiAlCl4 electrolyte, 16.4 Ah (a greater excess of SOCl2 is necessary for safe high rate operation). The electrode surface area was 452 sq cm. The carbon electrode comprised Shawinigen Black/Teflon -30 (90/10 by weight) mixture 0.020 inches thick on an expanded metal screen prepared in the JPL laboratory. There were two tab connections to the cathode. The 0.0078 inch thick lithium foil was rolled into an expanded nickel screen. The separator was Mead 934-5 fiberglass material.
    Keywords: ELECTRONICS AND ELECTRICAL ENGINEERING
    Type: NASA. Goddard Space Flight Center The 1984 Goddard Space Flight Center Battery Workshop; p 175-182
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  • 6
    Publication Date: 2019-07-12
    Description: JPL is developing ambient temperature secondary lithium cells for future spacecraft applications. Prior studies on experimental laboratory type Li-TiS2 cells yielded promising results in terms of cycle life and rate capability. To further assess the performance of this cell, 5 Ah engineering model cells were developed. Initially baseline cells were designed and fabricated. Each cell had 15 cathodes and 16 anodes and the ratio of anode to cathode capacity is 6:1. A solution of 1.5 molar LiAsF6 in 2Me-THF was used as the electrolyte. Cells were evaluated for their cycle life at C/1 and C/5 discharge rates and 100 percent depth of discharge. The cells were cycled between voltage limits 1.7 and 2.8 volts. The rate of charge in all cases is C/10. The results obtained indicate that cells can operate at C/10 to C/2 discharge rates and have an initial energy density of 70 Wh/kg. Cells delivered more than 100 cycles at C/2 discharge rate. The details of cell design, the test program, and the results obtained are described.
    Keywords: ENERGY PRODUCTION AND CONVERSION
    Type: Journal of Power Sources (ISSN 0378-7753); 22; 269-275
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  • 7
    Publication Date: 2019-07-13
    Description: The use of lithium thionyl chloride cells for low-temperature applications is presently restricted because of their unsafe behavior. An attempt is made in the present investigation to identify the safe/unsafe low temperature operating conditions and to understand the low temperature cell chemistry responsible for the unsafe behavior. Cells subjected to extended reversal at low rate and -40 C were found to explode upon warm-up. Lithium was found to deposit on the carbon cathodes during reversal. Warming up to room temperature may be accelerating the lithium corrosion in the electrolyte. This may be one of the reasons for the cell thermal runaway.
    Keywords: ENERGY PRODUCTION AND CONVERSION
    Type: Symposium on Primary and Secondary Ambient Temperature Lithium Batteries; Oct 18, 1987 - Oct 23, 1987; Honolulu, HI; United States
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  • 8
    Publication Date: 2019-07-13
    Description: The ethylene carbonate/2-methyltetrahydrofuran (EC/2-MeTHF) mixed-solvent electrolyte has been experimentally found to possess many desirable electrolyte characteristics for ambient-temperature secondary Li-TiS2 cell applications. As many as 300 cycles have been demonstrated, and a cycling efficiency figure-of-merit of 38.5 percent, for 10-percent EC/90-percent MeTHF mixed-solvent electrolyte in experimental Li-TiS2 cells. The improved performance of this electrolyte is attributable to the formation of a beneficial passivating film on the Li electrode by interaction with the EC.
    Keywords: INORGANIC AND PHYSICAL CHEMISTRY
    Type: International Power Sources Symposium; Jun 13, 1988 - Jun 16, 1988; Cherry Hill, NJ; United States
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